Uranium and Vanadium Resources of Utah: An Update in the Era of Critical Minerals and Carbon Neutrality

Utah is the second largest vanadium producing state and the third largest uranium producing state in the United States. Carnotite, a primary ore mineral for both vanadium and uranium, was first discovered and used by Native Americans as a source of pigment in the Colorado Plateau hysiographic province of eastern Utah. Radioactive deposits have been ommercially mined in Utah since about 1900, starting with radium, followed by vanadium, and thenuranium. In 1952, the discovery of the Mi Vida mine in Utah’s Lisbon Valley mining district in San Juan County kicked off a uranium exploration rush across the Colorado Plateau. As a result, the United States dominated the global uranium market from the early 1950s to late 1970s. In the modern mining era, Utah is an important contributor to the domestic uranium and vanadium markets with the only operating conventional uranium-vanadium mill in the country, multiple uranium-vanadium mines on standby, and active uranium-vanadium exploration. Overall, Utah has produced an estimated 122 million lbs U3O8 and 136 million lbs V2O5 since 1904. Most of this production has been from the sandstone-hosted deposits of the Paradox Basin, with minor production from volcanogenic deposits and as byproducts from other operations across the state

Seaborgite, LiNa6K2(UO2)(SO4)5(SO3OH)(H2O), the First Uranyl Mineral Containing Lithium

Seaborgite (IMA2019-087), LiNa6K2(UO2)(SO4)5(SO3OH)(H2O), is a new mineral species from the Blue Lizard mine, Red Canyon, San Juan County, Utah, U.S.A. It is a secondary phase found on gypsum in association with copiapite, ferrinatrite, ivsite, metavoltine, and römerite. Seaborgite occurs in sprays of light-yellow, long flattened prisms or blades, up to about 0.2 mm in length. Crystals are elongated on [100], flattened on {010}, and exhibit the forms {100}, {010}, {001}, and {101}. The mineral is transparent with vitreous luster and very pale-yellow streak. It exhibits bright lime-green fluorescence under a 405 nm laser. The Mohs hardness is ~2½. The mineral has brittle tenacity, curved or conchoidal fracture, and one good cleavage on {100}. The measured density is 2.97(2) g/cm3. The mineral is immediately soluble in H2O at room temperature. The mineral is optically biaxial (–), α = 1.505(2), β = 1.522(2), γ = 1.536(2) (white light); 2Vmeas = 85(1)°; moderate r < ν dispersion; orientation X ^ a ≈ 10°; pleochroic X colorless, Y and Z light green-yellow; X < Y ≈ Z. EPMA and LA-ICP-MS analyses of seaborgite undermeasured its Li, K, and Na. The empirical formula using Li, Na, and K based on the structure refinement is Li1.00Na5.81K2.19(UO2)(SO4)5(SO3OH)(H2O). Seaborgite is triclinic, P1, a = 5.4511(4), b = 14.4870(12), c = 15.8735(15) Å, α = 76.295(5), β = 81.439(6), γ = 85.511(6)°, V = 1203.07(18) Å3, and Z = 2. The structure (R1 = 0.0377 for 1935 I = 2σI) contains [(UO2)2(SO4)8]4– uranyl-sulfate clusters that are linked into a band by bridging LiO4 tetrahedra. The bands are linked through peripheral SO4 tetrahedra forming a thick heteropolyhedral layer. Channels within the layers contain a K site, while an additional K site, six Na sites, and an SO3OH group occupy the space between the heteropolyhedral layers.

Natromarkeyite and pseudomarkeyite, two new calcium uranyl carbonate minerals from the Markey mine, San Juan County, Utah, USA

The new minerals natromarkeyite, Na2Ca8(UO2)4(CO3)13(H2O)24⋅3H2O (IMA2018-152) and pseudomarkeyite, Ca8(UO2)4(CO3)12(H2O)18⋅3H2O (IMA2018-114) were found in the Markey mine, San Juan County, Utah, USA, where they occur as secondary phases on asphaltum. Natromarkeyite properties are: untwinned blades and tablets to 0.2 mm, pale yellow green colour; transparent; white streak; bright bluish white fluorescence (405 nm laser); vitreous to pearly lustre; brittle; Mohs hardness 1½ to 2; irregular fracture; three cleavages ({001} perfect, {100} and {010} good); density = 2.70(2) g cm–3; biaxial (–) with α = 1.528(2), β = 1.532(2) and γ = 1.533(2); and pleochroism is X = pale green yellow, Y ≈ Z = light green yellow. Pseudomarkeyite properties are: twinned tapering blades and tablets to 1 mm; pale green yellow colour; transparent; white streak; bright bluish white fluorescence (405 nm laser); vitreous to pearly lustre; brittle; Mohs hardness ≈ 1; stepped fracture; three cleavages ({10$\bar{1}$} very easy, {010} good, {100} fair); density = 2.88(2) g cm–3; biaxial (–) with α = 1.549(2), β = 1.553(2) and γ = 1.557(2); and it is nonpleochroic. The Raman spectra of markeyite, natromarkeyite and pseudomarkeyite are very similar and exhibit bands consistent with UO22+, CO32– and O–H. Electron microprobe analyses provided the empirical formula Na2.01Ca7.97Mg0.03Cu2+0.05(UO2)4(CO3)13(H2O)24⋅3H2O (–0.11 H) for natromarkeyite and Ca7.95(UO2)4(CO3)12(H2O)18⋅3H2O (+0.10 H) for pseudomarkeyite. Natromarkeyite is orthorhombic, Pmmn, a = 17.8820(13), b = 18.3030(4), c = 10.2249(3) Å, V = 3336.6(3) Å3 and Z = 2. Pseudomarkeyite is monoclinic, P21/m, a = 17.531(3), b = 18.555(3), c = 9.130(3) Å, β = 103.95(3)°, V = 2882.3(13) Å3 and Z = 2. The structures of natromarkeyite (R1 = 0.0202 for 2898 I > 2σI) and pseudomarkeyite (R1 = 0.0787 for 2106 I > 2σI) contain uranyl tricarbonate clusters that are linked by (Ca/Na)–O polyhedra forming thick corrugated heteropolyhedral layers. Natromarkeyite is isostructural with markeyite; pseudomarkeyite has a very similar structure.

The Morrison Formation and its bounding strata on the western side of the Blanding basin, San Juan County, Utah

In 2016 and 2017, the Utah Geological Survey partnered with the U.S. Bureau of Land Management to conduct a paleontological inventory of the Morrison Formation south and west of Blanding, Utah, along the eastern margin of the Bears Ears National Monument. The Morrison in this region is critical to understanding Upper Jurassic stratigraphy across the Colorado Plateau because it is the type area for the Bluff Sandstone, Recapture, Westwater Canyon, and Brushy Basin Members of the Morrison Formation, which are the basis for nomenclature in New Mexico and Arizona as well. Researchers have disagreed about nomenclature and correlation of these units, which transition northward in the study area into the Tidwell, Salt Wash, and Brushy Basin Members. Numerous vertebrate localities make inclusion of the Bluff Sandstone and Recapture Members in the Middle Jurassic San Rafael Group, as suggested by some previous workers, unlikely. The Salt Wash Member does not separate the Bluff Sandstone and Recapture Members at Recapture Wash, but sandstone lenses of Salt Wash facies occur higher in northern Recapture exposures. Northward, along the outcrop belt east of Comb Ridge, the Bluff-Recapture interval thins, interlenses, and pinches out into the Tidwell and lower Salt Wash, with the main lower sandstone interval of the Westwater Canyon merging northward into the upper Salt Wash Member. The partly covered, 1938 type section of the Brushy Basin Member is identified along Elk Mountain Road at the southern end of Brushy Basin. We describe a detailed, accessible Morrison Formation reference section about 11.2 km (7 mi) to the south along Butler Wash. There, 81.68 m (268 ft) of Brushy Basin Member is well exposed along a road between the top of the Westwater Canyon Member and the base of the Lower Cretaceous Burro Canyon Formation. We informally call the upper sandstone bed(s) of the Westwater Canyon Member that cap mesas and benches in the region “No-Mans Island beds.” Smectitic mudstones between the No-Mans Island beds and the main sandstone body of the Westwater Canyon suggest that the Salt Wash-Brushy Basin contact to the north may be somewhat older than the base of the Brushy Basin Member as originally defined in its type area. Determining whether the No-Mans Island beds pinch out to the north or are removed by erosion below the regional basal Brushy Basin paleosol requires further research. Several significant fossil vertebrate and plant sites have been documented in the Brushy Basin type area. Newly identified volcanic ashes provided zircons for U-Pb ages of 150.67 ± 0.32 Ma from near the top of the Brushy Basin Member and of 153.7 ± 2.1 Ma and 153.8 ± 2.2 Ma for two zircons in lower part of Recapture Member. At the top of the Brushy Basin Member, ferruginous paleosols commonly overlying conglomeratic sandstone are speculated to be of Early Cretaceous age (detrital zircon age pending) and are assigned herein to the Yellow Cat Member of the Burro Canyon Formation. These iron-rich paleosols suggest wetter climatic conditions during the Jurassic-Cretaceous transition in the Blanding basin.

Pseudomeisserite-(NH4), a new mineral with a novel uranyl-sulfate linkage from the Blue Lizard mine, San Juan County, Utah, USA

The new mineral pseudomeisserite-(NH4) (IMA2018-166), (NH4,K)2Na4[(UO2)2(SO4)5]⋅4H2O, was found in the Blue Lizard mine, San Juan County, Utah, USA, where it occurs as light yellow prisms in a secondary assemblage with belakovskiite, blödite, changoite, ferrinatrite, gypsum, ivsite, metavoltine and tamarugite. The streak is very pale yellow and the fluorescence is bright lime green under 405 nm ultraviolet light. Crystals are transparent with vitreous lustre. The tenacity is brittle, the Mohs hardness is 2½, the fracture is curved or conchoidal and there is one perfect cleavage on {100}. The mineral is easily soluble in H2O and has a measured density of 3.22(2) g⋅cm–3. Pseudomeisserite-(NH4) is optically biaxial (–) with α = 1.536(2), β = 1.559(2) and γ = 1.565(2) (white light); 2Vmeas. = 53(1)°; dispersion is r > v, distinct; pleochroism: X colourless, Y light yellow and Z pale yellow (X < Z < Y); optical orientation: Z = b, Y ∧ c = 33° in obtuse β). Electron microprobe analyses (WDS mode) provided (NH4)1.49K0.60Na3.87U2.00S5.04O28H7.78. The five strongest X-ray powder diffraction lines are [dobs, Å(I)(hkl)]: 12.69(76)(100), 6.83(84)(012,102), 6.01(100)($\bar{2}$02), 3.959(67)($\bar{2}$21,$\bar{2}$14,$\bar{1}$23) and 3.135(76)($\bar{2}$06,223,$\bar{1}$16). Pseudomeisserite-(NH4) is monoclinic, P21/c, a = 13.1010(3), b = 10.0948(2), c = 19.4945(14) Å, β = 104.285(7)°, V = 2498.5(2) Å3 and Z = 4. The structural unit in the structure (R1 = 0.0254 for 3837 I > 2σI reflections) is a novel [(UO2)2(SO4)5]6– uranyl-sulfate band.