Chapter 5.5 Gaussberg: volcanology and petrology

Gaussberg is a nunatak composed of lamproite pillow lava situated on the coast of East Antarctica. It is the most isolated Quaternary volcanic centre in Antarctica but it is important palaeoenvironmentally and petrologically out of all proportion to its small size. The edifice has a likely low, shield-like, morphology c. 1200 m high and possibly up to 10 km wide, which is unusually large for a lamproite construct. Gaussberg was erupted subglacially at 56 ± 5 ka, which places it late in the last glacial, close to the peak of marine isotope stage 3. The coeval ice sheet was c. 1300 m thick, and c. 420 m has been removed from the ice surface since Gaussberg erupted. Lamproite is a rare ultrapotassic mantle-derived magma, and Gaussberg is one of two type examples worldwide. Although traditionally considered as related in some way to the Kerguelen plume, it is more likely that the Gaussberg magma is a product of a separate magmatic event. It is ascribed to the storage and long-term (Gy) isolation of sediment emplaced by subduction in the Transition Zone of the deep mantle, followed by entrainment and subsequent melting in a plume.

Forsterite reprecipitation and carbon dioxide entrapment in the lithospheric mantle during its interaction with carbonatitic melt: a case study from the Sung Valley ultramafic–alkaline–carbonatite complex, Meghalaya, NE India

Carbonatite melts derived from the mantle are enriched in CO2- and H2O-bearing fluids. This melt can metasomatize the peridotitic lithosphere and liberate a considerable amount of CO2. Experimental studies have also shown that a CO2–H2O-rich fluid can form Fe- and Mg-rich carbonate by reacting with olivine. The Sung Valley carbonatite of NE India is related to the Kerguelen plume and is characterized by rare occurrences of olivine. Our study shows that this olivine is resorbed forsterite of xenocrystic nature. This olivine bears inclusions of Fe-rich magnesite. Accessory apatite in the host carbonatite contains CO2–H2O fluid inclusions. Carbon and oxygen isotopic analyses indicate that the carbonatites are primary igneous carbonatites and are devoid of any alteration or fractionation. We envisage that the forsterite is a part of the lithospheric mantle that was reprecipitated in a carbonatite reservoir through dissolution–precipitation. Carbonation of this forsterite, during interaction between the lithospheric mantle and carbonatite melt, formed Fe-rich magnesite. CO2–H2O-rich fluid derived from the carbonatite magma and detected within accessory apatite caused this carbonation. Our study suggests that a significant amount of CO2 degassed from the mantle by carbonatitic magma can become entrapped in the lithosphere by forming Fe- and Mg-rich carbonates.