Klisura/Rozino granite, Central Sredna Gora: a part of the story of late Permian–Early Triassic extensional magmatic event

Тhe late- to post-Variscan magmatic activity in the South Black See region took plaсe during a considerably long period of ca. 80 from Late Carboniferous up to Early–Mid Triassic as two episodes are distinguished. The obtained age of 253.6±1.6 Ma for the Klisura/Rozino granite gives further evidence of the contemporaneous intrusive and extrusive magmatism during late Permian and Early Triassic in the Sredna Gora and Balkan zones.

Variscan intracrustal recycling by melting of Carboniferous arc-like igneous protoliths (Évora Massif, Iberian Variscan belt)

Bulk rock geochemistry and sensitive high-resolution ion microprobe zircon geochronology of igneous and metaigneous rocks of the Évora gneiss dome, located to the north of the reworked Rheic Ocean suture zone in the southwest Iberian Variscan belt, reveal a succession of magmatic and melting events lasting ∼30 m.y. between ca. 341−314 Ma. The study of detailed field relationships of orthomigmatites (i.e., migmatites from igneous protoliths) and host granitic rocks proved to be crucial to reconstruct the complex sequence of tectono-thermal events of the Évora gneiss dome. The older igneous protoliths, with marked geochemical arc-like signatures, are represented by 338 ± 3 Ma tonalites and 336 ± 3 Ma diorites. These tonalites and diorites appear as mesosomes of igneous orthomigmatites containing new melts (leucosomes) of monzogranite composition and silica-poor trondhjemites formed in a melting episode at 329 ± 4/6 to 327 ± 3 Ma. The absence of peritectic phases (e.g., pyroxene), together with shearing associated with migmatization, imply the existence of water-rich fluids during melting of the older igneous rocks of the Évora gneiss dome. This melting event is coeval with the second magmatic event of the Évora gneiss dome represented by the neighboring Pavia pluton. A porphyritic monzogranite dated at 314 ± 4 Ma defines a later magmatic event. The porphyritic monzogranite encloses large blocks of the orthomigmatites and contains magmatic mafic enclaves (autoliths) dated at 337 ± 4 Ma that are ∼23 m.y. older than the host rock. All studied rocks of the Évora gneiss dome show arc-like, calc-alkaline geochemical signatures. Our results support recycling of intermediate-mafic plutonic rocks, representing the root of an early magmatic arc that formed at the time of Gondwana-Laurussia convergence (after the closure of the Rheic Ocean) and coeval subduction of the Paleotethys. A geodynamic model involving ridge subduction is proposed to explain the Early Carboniferous intra-orogenic crustal extension, dome formation, exhumation of high-grade rocks, compositional variations of magmatism and formation of new granitic magmatism in which, arc-like signatures were inherited from the crustal source.

Large Igneous Provinces of the Amazonian Craton and their Metallogenic Potential in Proterozoic Times

This paper overviews the Proterozoic Large Igneous Provinces of the Amazonian Craton, characterized by large volumes of extrusive and intrusive magmatic rocks. We reassess the geologic, geochronologic and geochemical information to stablish three intracontinental felsic volcanic-plutonic igneous belts (i.e., SLIPs), namely: Orocaima (1.98-1.96 Ga), Uatumã (1.88-1.87 Ga) and Alta Floresta (1.80-1.79 Ga). The Avanavero LIP (1.79-1.78 Ga), as well as the Rincón del Tigre-Huanchaca LIP (1.11 Ga) are also revisited. The relationships of these events with intraplate settings through time and space are apparent. We examine the main characteristics of each magmatic event in light of the U-Pb zircon and baddeleyite ages and coupled isotopic-geochemical constraints, the geodynamic significance, and metallogenetic potential. The Uatumã and Alta Floresta SLIPs host the most important mineral resources within the Amazonian Craton. Global barcode matches of the Proterozoic SLIPS/LIP events of Amazonia are also addressed, as well as their possible links with geologic time-scale periods: the Orosirian, Statherian and Stenian boundaries. We also evaluate the available paleomagnetic data to address issues related to the barcode match of such SLIP/LIP events in the context of supercontinent cycles.

Uraninite from the Guangshigou Pegmatite-Type Uranium Deposit in the North Qinling Orogen, Central China: Its Occurrence, Alteration and Implications for Post-Caledonian Uranium Circulation

The Guangshigou deposit is the largest pegmatite-type uranium deposit in the Shangdan domain of the North Qinling Orogenic Belt, which is characterized by the enrichment of uraninite hosted in biotite granitic pegmatites. At Guangshigou, uraninite commonly occurs as mineral inclusions in quartz, K-feldspar and biotite or in interstices of these rock-forming minerals with magmatic characteristics (e.g., U/Th < 100, high ThO2, Y2O3 and REE2O3 contents and low concentrations of CaO, FeO and SiO2). It crystallized at 407.6 ± 2.9 Ma from fractionated calc-alkaline high-K pegmatitic melts under conditions of 470–700 °C and 2.4–3.4 kbar as deduced by the compositions of coexisting peritectic biotite. The primary uranium mineralization took place during the Late Caledonian post-collisional extension in the North Qinling Orogen. After this magmatic event, uraninite has experienced multiple episodes of fluid-assisted metasomatism, which generated an alteration halo of mineral assemblages. The alteration halo (or radiohalo) was the result of the combined effects of metamictization and metasomatism characterized by an assemblage of goethite, coffinite and an unidentified aluminosilicate (probably clay minerals) around altered uraninite. This fluid-assisted alteration was concomitant with the albitization of K-feldspar subsequently followed by the coffinitization of uraninite during the major period of 84.9–143.6 Ma, as determined by U-Th-Pb chemical ages. Further investigations revealed that the metasomatic overprinting on uraninite initially and preferentially took place along microcracks or cavities induced by metamictization and promoted their amorphization, followed by the release of U and Pb from structure and the incorporation of K, Ca and Si from the fluids, finally resulting in various degrees of uraninite coffinitization. The released U and Pb were transported by alkali-rich, relatively oxidizing fluids and then re-precipitated locally as coffinite and an amorphous U-Pb-rich silicate under low to moderate temperature conditions (85–174 °C). The compositional changes in primary uraninite, its structure amorphization together with the paragenetic sequence of secondary phases, therefore, corroborate a combined result of intense metamictization of uraninite and an influx of alkali–metasomatic fluids during the Late Mesozoic Yanshanian magmatic event in the region. Hence, the remobilization and circulation of uranium in the North Qinling Orogen was most likely driven by post-Caledonian magmatism and hydrothermal activities related to large-scale tectonic events. In this regards, Paleozoic pegmatite-type uranium mineralization may represent a significant uranium source for Mesozoic hydrothermal mineralization identified in the Qinling Orogenic Belt.

Radiogenic heat production in granitoids from the Sierras de Córdoba, Argentina

One of the most important processes of heat generation from the Earth's interior is the radioactive decay of isotopes. The main hosts of the major radiogenic elements U, Th and K in the crust are granitoids. The Sierras de Córdoba are formed of dissimilar granitic intrusions emplaced by a series of magmatic events that occurred during the Paleozoic. The different granitoids are classified as A-type, I-type, and S-type, and there is also a magmatic expression corresponding to the Famatinian period which exhibits TTG-type characteristics. In this work, the geochemical concentrations of the radiogenic elements of the granitic intrusions making up the Sierras de Córdoba were compiled in a single database. The radiogenic heat production of the Sierras de Córdoba granitoids was evaluated, making this the first study of radiogenic heat generation in the area. The radiogenic heat production showed variability for the different events, with the highest values found in Achalian magmatism and early Carboniferous magmatism, which are represented by A-type granitoids. The Capilla del Monte pluton has the highest heat production rate, with a value of 4.54 ± 1.38 µW/m3. The lowest values were found in the TTG-type granitoids and in the S-type granitoids, all of which belong to the Famatinian magmatic event. The range of values for this magmatic event goes from 0.26 ± 0.05 µW/m3 for the San Agustin pluton to 1.19 ± 0.50 µW/m3 for the La Playa pluton. An empirical ternary model is presented for the Sierras de Córdoba that involves the concentrations of the elements U, Th and K, and the radiogenic heat production, with a distinction for the petrogenetic types according to the S-I-A-M classification. The thermal manifestations located on the Capilla del Monte pluton could be related to the radioactive heat generation of the intrusion, involving both the neotectonic activity of the area and the radiogenic heat production. The results provide new opportunities for studying temperature variation within some of these intrusions and to evaluate the geothermal potential of the granitoids of Córdoba.

Eruption risks from covert silicic magma bodies

Unintentional encounters with silicic magma at ~2–2.5 km depth have recently occurred during drilling at three volcanoes: Kilauea (Hawaii), Menengai (Kenya), and Krafla (Iceland). Geophysical surveys had failed to warn about shallow magma before each encounter, and subsequent surveys at Krafla have been unable to resolve the size or architecture of its silicic magma body. This presents a conundrum for volcano monitoring: Do such shallow “covert” magma bodies pose an eruption risk? Here, we show that Krafla’s most recent explosive eruption, a mixed hydrothermal-magmatic event in 1724 C.E. that formed the Víti maar, involved rhyolite essentially indistinguishable in composition from magma encountered during drilling in 2009. Streaks of quenched basalt in some Víti pumices provide direct evidence for interaction between co-erupted rhyolitic and basaltic magmas, but crystals in these pumices show no evidence for late-stage heating or re-equilibration with more mafic melt, implying mixing time scales of at most several hours. Covert silicic magma thus presents an eruption risk at Krafla and may be mobilized with little warning. Difficulties in resolving magma bodies smaller than ~1 km3 with geophysical surveys mean that covert silicic magma may exist at many other volcanoes and should be considered in hazard and risk assessments.

Chapter 5.5 Gaussberg: volcanology and petrology

Gaussberg is a nunatak composed of lamproite pillow lava situated on the coast of East Antarctica. It is the most isolated Quaternary volcanic centre in Antarctica but it is important palaeoenvironmentally and petrologically out of all proportion to its small size. The edifice has a likely low, shield-like, morphology c. 1200 m high and possibly up to 10 km wide, which is unusually large for a lamproite construct. Gaussberg was erupted subglacially at 56 ± 5 ka, which places it late in the last glacial, close to the peak of marine isotope stage 3. The coeval ice sheet was c. 1300 m thick, and c. 420 m has been removed from the ice surface since Gaussberg erupted. Lamproite is a rare ultrapotassic mantle-derived magma, and Gaussberg is one of two type examples worldwide. Although traditionally considered as related in some way to the Kerguelen plume, it is more likely that the Gaussberg magma is a product of a separate magmatic event. It is ascribed to the storage and long-term (Gy) isolation of sediment emplaced by subduction in the Transition Zone of the deep mantle, followed by entrainment and subsequent melting in a plume.

The igneous plumbing system of the Early Permian Bolzano/Bozen supervolcano (North-eastern Italy)

&lt;p&gt;Early Permian Post-Variscan magmatism is widespread throughout the Alps and consists mainly of felsic to mafic plutonic and volcanic bodies emplaced between ca. 285 and 275 Ma. This study focuses on the acidic to intermediate intrusions in the areas of Trento and Bolzano/Bozen (North-eastern Italy) like the Cima d&amp;#8217;Asta gabbrodiorite/granite, the Pergine granodiorite, the Monte Sabion and the Bressanone (Brixen) granites. New U-Pb zircon data along with ages for the Ivigna (Ifinger) and Monte Croce (Kreuzberg) granites and the Bressanone (Brixen) gabbro constrain the age of the Permian intrusions and Hf isotopic data highlight the interaction between mantle-derived melts and crustal rocks during ascent of the former through the crust. Moreover, the studied intrusions represent the shallow crustal plumbing system of the coeval widespread volcanics of the Athesian Volcanic Group and the mega-caldera of the Bolzano/Bozen supervolcano. This acid intrusive-extrusive magmatism, which identified an elliptic structure of more than 4200 square kilometers, represents the biggest magmatic event outcropping in the Southern Alps and likely influenced the ecosystems of the Athesian Volcanic District and of the dolomitic area l.s. during the Permian.&lt;/p&gt;

Syndepositional hydrothermalism selectively preserves records of one of the earliest benthic ecosystems, Moodies Group (3.22 Ga), Barberton Greenstone Belt, South Africa

The ~3.22 Ga Moodies Group, Barberton Greenstone Belt (BGB), South Africa, provides a unique window into Archaean sedimentary, magmatic and ecological processes. In the central BGB, a regional mafic complex, consisting of a genetically related major mafic sill, a peperitic dyke stockwork, and extensive basaltic lava flows affected thick quartzose sandstones of the Moodies Group. We argue that epithermal hydrothermalism associated with this magmatic event occurred, at least in part, syndepositionally and in places destroyed, in other places preserved the abundant benthic microbial mats in terrestrial- and coastal-facies sandstone of this unit. We differentiate four principal types of hydrothermal alteration: (1) Sericitization resulted from ubiquitous feldspar breakdown; (2) iron-oxide alteration replaced the original matrix by fine-grained iron oxide; (3) silicification replaced matrix and most non-silica grains by microcrystalline silica and locally preserved kerogenous microbial mats; and (4) hydraulic fracturing at shallow depth brecciated consolidated Moodies Group sandstone and created closely spaced, randomly oriented fractures and quartz-filled veins. Because stockwork intrusion locally interacted with unconsolidated water-saturated sediment and because the dykes connect the sill with the mafic lava but also follow zones of structural weakness, we suggest that hydrothermalism associated with this magmatic event occurred syndepositionally but was also – within the resolution of radiometric age data – contemporaneous with tight regional folding. We conclude that microbial organisms in Paleoarchaean coastal (tidal, estuarine) environments may have been formerly widespread, possibly even abundant, but are nearly nowhere preserved because they were easily degradable. Preservation of Early Archaean microbial mats in a thermal aureole in the central BGB was controlled by the “just right” degree of heating and very early hydrothermal silicification.