Non-covalently embedded oxytocin in alkanethiol monolayer as Zn2+ selective biosensor

Peptides are commonly used as biosensors for analytes such as metal ions as they have natural binding preferences. In our previous peptide-based impedimetric metal ion biosensors, a monolayer of the peptide was anchored covalently to the electrode. Binding of metal ions resulted in a conformational change of the oxytocin peptide in the monolayer, which was measured using electrochemical impedance spectroscopy. Here, we demonstrate that sensing can be achieved also when the oxytocin is non-covalently integrated into an alkanethiol host monolayer. We show that ion-binding cause morphological changes to the dense host layer, which translates into enhanced impedimetric signals compared to direct covalent assembly strategies. This biosensor proved selective and sensitive for Zn2+ ions in the range of nano- to micro-molar concentrations. This strategy offers an approach to utilize peptide flexibility in monitoring their response to the environment while embedded in a hydrophobic monolayer.

Simulation of three types of nanoparticles on solar cell structure model

In this paper, we systemically and numerically investigate the effects of three types of Nanoparticles on the efficiency of solar cells. Finite Difference Time Domain method has been implemented to compute the absorption spectra in such proposed solar cell structure. High efficiency has been achieved by optimizing the nanoparticles layer by tuning the fraction of nanoparticles on the host layer.

White-light electroluminescence from a layer incorporating a single fully-organic spiro compound with phosphine oxide substituents

We have investigated the potential as an OLED emitter of a spiro compound with phosphine substituents initially designed as a host layer for triplet emitters.

Closed-Form Solutions for Electroacoustic Wave Energy Harvesting in a Coupled Plate-Harvester System

This paper introduces an analytical framework for predicting wave energy harvested by a circular piezoelectric layer from a harmonic point source excitation. The explored acoustic system analyzes a circular piezoelectric disk attached to an infinite host domain. An harmonic point source is located away from the piezoelectric disk on the infinite host layer. The analysis approach decomposes the system into two subdomains, the piezoelectric disk and an infinite plate, which are then separately analyzed. In contrast to traditional analysis methods for such systems (a sandwich of layers with different dimensions), this technique uses internal interaction forces between the different subdomains to find a close-form solution for the vibration of propagating waves over the entire field. In addition, the voltage generated by the harvester is calculated by using coupled electromechanical equations. The analysis is validated by comparing response quantities and frequency response functions at different points on the piezoelectric circular layer and host layers to those predicted using COMSOL simulations, which document good agreement. Analysis of this system is an important stepping stone to the next goal, which is optimization of energy captured from the propagating wave by designing boundary walls (reflector) on the host layer which focus the energy of the wave onto the piezoelectric domain. This focused energy can then be transferred to the electrical power by via a piezoelectric layer through an electrical circuit.