Permeable characteristics of surface film deposited on LiMn2O4 positive electrode revealed by redox-active indicator

Herein, the ferrocene redox indicator-based surface film characteristics of spinel lithium manganese oxide (LMO) were evaluated. The pre-cycling of spinel LMO generated a film on the LMO surface. The surface film deposited on LMO surface suppresses further electrolyte decomposition, while the penetration of approximately 0.7 nm-sized redox indicator is not prevented. The facile self-discharge of LMO and regeneration current from the ferrocenium molecule was observed from the redox indicator in a specifically designed four-electrode cell. From this electrochemical behavior, a small-sized HF molecule attack on the LMO surface through a carbonate-based electrolyte-derived film is defined; hence, the prevention of small-sized molecules into the deposited surface film is crucial for the enhancement of LiMn2O4-based lithium-ion batteries.

Application of stoichiometric hydrogen atoms for balancing organic combustion reactions

Combustion is a common redox reaction, and organic combustion is one of the basic contents in chemistry curriculum. The transferred H-atom is commonly used as a redox indicator in organic chemistry and biochemistry. Nevertheless, the relationship between the number of transferred H-atoms and the number of transferred electrons has not been fully revealed. Oxidation number (ON) is an electron-counting concept. Without knowing the ONs, the number of transferred electrons cannot be counted and therefore, the redox reactions cannot be classified, defined, and balanced. This paper explores the new H-atom method for counting the number of transferred H-atoms. It provides a half-reaction approach to balance the overall organic combustion reactions. Only simple arithmetic procedures are needed to determine the number of transferred H-atoms and consequently the number of transferred electrons. According to this method, the mathematical formulas for assigning the number of transferred H-atoms can be deducted by balancing the general chemical formulas of organic compounds in half and overall organic combustions. Furthermore, the number of transferred electrons and their stoichiometric categories can be determined conveniently by any given organic chemical formula in organic combustion reactions.

Distribution and behavior of fission product 95Nb in FLiBe salt

The 235,238UF4 was irradiated by photo-neutrons, distribution and behavior of the fission product 95Nb from irradiated 235,238UF4 in FLiBe salt were investigated by the measurement of its activity in the salt with the γ-ray spectroscopy. The experiments indicated that a part of 95Nb deposited on the surfaces of graphite and Hastelloy, as the moderator and the structural materials of molten salt reactor (MSR), respectively, and the majority of 95Nb maintained in molten salt. Addition of lithium metal made 95Nb in salt to be reduced and settled, leading to the decrease in its activity. Degree of the decrease was found to be correlated with niobium concentration. The experimental results supported the statement proposed early by ORNL, that 95Nb might be used as a redox indicator for MSR. Finally, the problem met with on-site monitoring for redox potential in MSR was pointed, and a possible protocol to resolve the problem was proposed.

Identification of Clay Mineral Content Using Spectral Gamma Ray on Y1 Well in Karawang Area, West Java, Indonesia.

Northwest Java Basin (NWJB) is one of the proven hydrocarbon basins in Indonesia. The scope of this paper will focus onthe shales and sandstone interval within Y1 well in Karawang area, NWJB, Indonesia.A cored interval from Y1 well was chosen for an investigation of the clay minerology for the gamma-ray activity and with the purpose of determining how the Spectral Natural Gamma (SNG) log could be used as an indicator of source rock and reservoir quality. The Th/U as a redox indicator is used to assert that the shales are of anoxic conditions of shallow marine environments. Despite the relatively high insoluble Th values (60-74.15) ppm, the presence of U in substantial amounts, which only occurs in reducing conditions where it is preserved as a lower insoluble valence (U4+) explains for the low Th/U values ranging between (5.8-7.1) ppm/ppm. The overall Th/U value of the evaluated shales remain less than 25, where Th/U <25 is suggestive of marine sediments, whereas Th/U <4 is indicative of marine black shales of reducing conditions. Although no linear relationship was found between clay content and K, Th, or U, the K content characteristic three discrete reservoir characteristic (RC). The RC-I has predicted a matrix-supported texture with the highest K signal, illite and illitised kaolinite are roughly equal in importance as source of K. The RC-II has predicted a grain-supported texture with intermediate K content. K-feldspar, mica and illite as the main sources. The RC-III has predicted have a low K content with grain-supported texture and most of the K is hosted in feldspar. Overall, the laboratory measurements appear to be applicable to the log data, and, using SEM or XRD, the detail facies subdivision can be extended throughout the source rock and reservoir section based on the SNG log.

Successful introduction of the Colour Test into inexperienced settings

Implementation of non-commercial in-house methods into routine clinical diagnostics becomes more challenging, because these methods are not internationally standardized, most of the research in that field is underfunded and recommendations for their use is lacking. We conducted a study, where all the technicians were previously unfamiliar to the Colour Test (CT), a colorimetric redox indicator and thin-layer agar based Mycobacterium tuberculosis complex diagnosis and direct drug susceptibility testing (DST) method, and tested whether the performance of this in-house method is dependent on experience of the laboratory personnel.After a two-day hands-on training, six panels of 150 M. tuberculosis isolates were cultured onto CT plates prepared in-house by six technicians in two laboratories. Finally, triplicate readings of 900 CT plates resulted 18 DST patterns for each of the initial isolates. The results were compared to each other and the gold standard of BACTEC MGIT 960 DST results.The median time to produce M. tuberculosis CT DST results for three antituberculosis drugs was 13 days. The overall ability to correctly define phenotypic resistance ranged from 94.7% for levofloxacin to 95.8% and 97.3% for isoniazid and rifampicin, respectively. The test specificities were even higher exceeding 97% for all three drugs tested. Interobserver agreement reached 100% in one of the laboratories and exceeded 97% for levofloxacin and 99% for isoniazid and rifampicin in the second laboratory.The implementation of the CT into a new laboratory was straightforward with only minimal guidance. This study proves that the CT is highly reproducible and easily interpreted by previously inexperienced personnel.