Numerical Optimization of WAG Injection in a Sandstone Field using a Coupled Surface and Subsurface Model

Gas injection is one of the most commonly used enhanced oil recovery (EOR) methods. However, there are multiple problems associated with gas injection including gravity override, viscous fingering, and channeling. These problems are due to an adverse mobility ratio and cause early breakthrough of the gas resulting, in poor recovery efficiency. A Water Alternating Gas (WAG) injection process is recommended to resolve these problems through better mobility control of gas, leading to better project economics. However, poor WAG design and lack of understanding of the different factors that control its performance might result in unfavorable oil recovery. Therefore, this study provides more insight into improving WAG oil recovery by optimizing different surface and subsurface WAG parameters using a coupled surface and subsurface simulator. Moreover, the work investigates the effects of hysteresis on WAG performance. This case study investigates a field named Volve, which is a decommissioned sandstone field in the North Sea. Experimental design of factors influencing WAG performance on this base case was studied. Sensitivity analysis was performed on different surface and subsurface WAG parameters including WAG ratio, time to start WAG, total gas slug size, cycle slug size, and tubing diameter. A full two-level factorial design was used for the sensitivity study. The significant parameters of interest were further optimized numerically to maximize oil recovery. The results showed that the total slug size is the most important parameter, followed by time to start WAG, and then cycle slug size. WAG ratio appeared in some of the interaction terms while tubing diameter effect was found to be negligible. The study also showed that phase hysteresis has little to no effect on oil recovery. Based on the optimization, it is recommended to perform waterflooding followed by tertiary WAG injection for maximizing oil recovery from the Volve field. Furthermore, miscible WAG injection resulted in an incremental oil recovery between 5 to 11% OOIP compared to conventional waterflooding. WAG optimization is case-dependent and hence, the findings of this study hold only for the studied case, but the workflow should be applicable to any reservoir. Unlike most previous work, this study investigates WAG optimization considering both surface and subsurface parameters using a coupled model.

Thermal EOR Conformance – A New Frontier for Asset Optimization: Steam Shutoff Pilot in Oman

Over the last 50 years, thermal EOR has been an effective method for reducing the viscosity of and recovering heavy oil from deep reservoirs. In mature thermal EOR projects, conformance is one of the main challenges for maximizing reserves and meeting long-term production expectations. In this paper, Occidental presents a novel pilot to address thermal conformance in the Mukhaizna field in Oman. This is a thermal EOR operation in deep reservoirs (> 2,000 ft) with extremely high viscosity (>10,000 cp) in harsh desert conditions with temperatures exceeding 500°F. The pilot area is a mature thermal area with 15 years of continuous steamflood operations. The novel conformance technique, based on a combination of chemical and zonal mechanical isolation systems, was developed in-house in a low oil price environment. The pilot area consists of multiple reservoir zones that have undergone vertical steam injection since 2005. Thermal conformance has emerged as a challenge because more than 60% of the injected steam has been preferentially entering the high-permeability zones, with only 40% of the steam entering the other zones, which hold a larger amount the remaining oil. The subsurface and well engineering teams collaborated to design a rigless operation using dual coiled tubing units, one for cooling water and one pumping a chemical gelation recipe that gels at a certain trigger gelation temperature at the target zone. Zonal isolation of the reservoir is achieved using a novel inflatable packer triggered mechanically by ball gravitation through coiled tubing at 500°F and retrieved after the temporary zonal isolation. The well and reservoir surveillance included gathering data for injectivity assessment, vertical injection logging, temperature profiles, tracer tests in offset producers, and well testing for determining water cut. The pilot improved vertical conformance, as injection logging showed 40% steam reduction was achieved in the target zone, and more steam was re-allocated to the shallow zones. In addition, there was a water cut reduction of more than 20% in offset producers, and oil production tripled over a period of 3 months, which paid back the cost of the pilot and generated positive cash flow. To our knowledge, based on an SPE literature search, this is the first successful thermal conformance operation conducted with the following combination of technologies: 1) Placing a novel chemical recipe through temporary zonal isolation with an inflatable packer, and 2) Using rigless operation of coiled tubing units at harsh conditions of >500°F and high pressure >1000 psi. The outcomes open a new frontier for thermal EOR development in multi-stack reservoirs, offering better utilization of steam injection and improving mobility control over the field life cycle. The cost of the pilot project was paid off in the first 6 weeks, and all chemicals used were developed in an eco-friendly system.

Supercritical CO2-Foam Screening and Performance Evaluation for CO2 Storage Improvement in Sandstone and Carbonate Formations

Injecting carbon dioxide (CO2) as foam during enhanced oil recovery (EOR) can improve injectate mobility and increase sweep efficiency. Integrating CO2-foam techniques with carbon capture, utilization and storage (CCUS) operations is of recent interest, as the mobility control and sweep efficiency increases seen in EOR could also benefit CO2 storage during CCUS. In this study, a variety of different charge, hydrocarbon chain length, head group surfactants were evaluated by surface tension, bulk and dynamic CO2-foam performance assessments for CCUS. The optimal foam candidate was expected to provide satisfying mobility control effects under reservoir conditions, leading to an improved water displacement efficiency during CO2-foam flooding that favors a more significant CO2 storage potential. All tested surfactants were able to lower their surface tensions against scCO2 by 4-5 times, enlarging the surface area of solution/gas contact; therefore, more CO2 could be trapped in the foam system. A zwitterionic surfactant was found to have slightly higher surface tension against CO2 while exhibiting the highest foaming ability and the most prolonged foam stability with a relatively slower drainage rate among all tested surfactants. The dynamic performance of scCO2-foam stabilized by this zwitterionic surfactant was also evaluated in sandstone and carbonate cores at 13.79 MPa and 90°C. The results show that the mobility control development in carbonate core was relatively slower, suggesting a gradual foam generation process attributed to the higher permeability than the case in sandstone core. A more significant cumulative CO2 storage potential improvement, quantified based on the water production, was recorded in sandstone (53%) over the carbonate (47%). Overall, the selected foam has successfully developed CO2 mobility control and improved water displacement in the occurrence of in-situ foam generation, hence promoting the storage capacity for the injected CO2. This work has optimized the foaming agent selection method at the actual reservoir conditions and evaluated the scCO2-foam performance in establishing high flow resistance and improving the CO2 storage capacity, which benefits integrated CCUS studies or projects utilizing CO2-foam techniques.

Design of an Economical Polymer Flood Pilot Addressing Field Development Uncertainties in the Sabriyah Upper Burgan Reservoir of North Kuwait

The Sabriyah Upper Burgan is a major oil reservoir in North Kuwait with high oil saturation and is currently considered for mobility control via polymer flooding. Although there is high confidence in the selected technology, there are technological and geologic challenges that must be understood to transition towards phased commercial field development. Engineering and geologic screening suggested that chemical flood technologies were superior to either miscible gas or waterflood technologies. Of the chemical flood technologies, mobility control flooding was considered the best choice due to available water ion composition and total dissolved solids (TDS). Evaluation of operational and economic considerations were instrumental in recommending mobility control polymer flooding for pilot testing. Laboratory selected acceptable polymer for use with coreflood incremental oil recovery being up to 9% OOIP. Numerical simulation recommended two commercial size pilots, a 3-pattern and a 5-pattern of irregular five spots, with forecast incremental oil recovery factors of 5.6% OOIP over waterflood. Geologic uncertainty is the greatest challenge in the oil and gas industry, which is exacerbated with any EOR project. Screening of the Upper Burgan reservoirs indicates that UB4 channel sands are the best candidates for EOR technologies. Reservoir quality is excellent and there is sufficient reservoir volume in the northwest quadrant of the field to justify not only a pilot but also future expansion. There is a limited edge water drive of unknown strength that will need to be assessed. The channel facies sandstones have porosities of +25%, permeabilities in the Darcy range, and initial oil saturations of +90%. Pore volume (PV) of the two recommended pilot varies from 29 to 45 million barrels. A total of 0.7 PV of polymer is expected to be injected in 5.6 and 7.9 years for the 3-pattern pilot and the 5-pattern pilot, respectively, with a water drive flush to follow for an additional 5 to 7 years. Incremental cost per incremental barrel of oil of a mobility control polymer flood which includes OPEX and CAPEX costs is $20 (USD). This paper evaluates the (commercial size) pilot design and addresses field development uncertainties.

A nanoscale reciprocating rotary mechanism with coordinated mobility control

Biological molecular motors transform chemical energy into mechanical work by coupling cyclic catalytic reactions to large-scale structural transitions. Mechanical deformation can be surprisingly efficient in realizing such coupling, as demonstrated by the F1FO ATP synthase. Here, we describe a synthetic molecular mechanism that transforms a rotary motion of an asymmetric camshaft into reciprocating large-scale transitions in a surrounding stator orchestrated by mechanical deformation. We design the mechanism using DNA origami, characterize its structure via cryo-electron microscopy, and examine its dynamic behavior using single-particle fluorescence microscopy and molecular dynamics simulations. While the camshaft can rotate inside the stator by diffusion, the stator’s mechanics makes the camshaft pause at preferred orientations. By changing the stator’s mechanical stiffness, we accelerate or suppress the Brownian rotation, demonstrating an allosteric coupling between the camshaft and the stator. Our mechanism provides a framework for manufacturing artificial nanomachines that function because of coordinated movements of their components.

Injectivity and Potential Wettability Alteration of Low-Salinity Polymer in Carbonates: Role of Salinity, Polymer Molecular Weight and Concentration, and Mineral Dissolution

Summary Coupling polymer with low-salinity water (LSW) to promote enhanced oil recovery (EOR) in carbonate reservoirs has attracted significant interest in the petroleum industry. However, low-salinity polymer (LSP) application to improve oil extraction from such rocks remains a challenge because of the complex synergism between these two EOR agents. Thus, this paper highlights the main factors that govern the LSP displacement process in carbonate reservoirs in terms of wettability alteration and mobility control. A series of experiments including contact angle, spontaneous imbibition, injectivity, adsorption, and oil displacement tests were performed. The impact of mineral dissolution on the polymer/brine and polymer/rock surface interactions and its possible connection to the efficiency of the LSP in carbonates was also investigated using ζ potential analysis following an elaborative procedure. All experiments were executed at elevated temperature (75°C) using two polymers (SAV10) of different molecular weights (MWs) prepared at varying concentrations and salinities. Contact angle measurements showed that increasing the polymer concentration and MW and, at the same time, decreasing the solution salinity could effectively rend homogeneous oil-wet calcite surfaces strongly water-wet. Conversely, spontaneous imbibition tests using heterogonous oil-wet Indiana limestone cores showed that the polymer viscosity and its molecular size hinder the performance of the polymer to modify the wettability of the core samples at high concentration and MW because they could limit its penetration into the porous medium. On the other hand, the results obtained from polymer injectivities showed that LSP had better propagation with lower filtration effects in comparison with high-salinity polymer (HSP). However, polymer adsorption and inaccessible pore volume (IPV) increased with the decrease of salinity. Calcite mineral dissolution triggered by LSP, which is associated with an increase in pH and [Ca2+], considerably influenced the polymer viscosity. In addition, ζ potential measurements showed that the LSP altered the rock surface charge from positive toward negative and at the same time, the Ca2+ released due to mineral dissolution could modify the polymer molecule charge toward positive. This confirms that mineral dissolution impressively results in better wettability alteration performance; however, it could lead to undesirable high polymer adsorption at low salinity. These findings provide new insight into the influence of mineral dissolution on polymer performance in carbonates. Finally, forced oil displacement tests revealed that both HSP and LSP extracted approximatively the same amount of oil. The HSP could enhance the oil recovery through mobility control. By contrast, wettability alteration could take part in the improvement of oil recovery at LSP, as proved by spontaneous imbibition tests, along with mobility control. Despite possessing high wettability alteration potential, LSP could not yield very high recovery because of its low accessibility into the porous medium. Shearing of the LSP was found effective in improving oil recovery through enhancing the polymer accessibility. This will lead us to simply say that polymer accessibility into carbonates is crucial for the success of the wettability alteration and mobility control processes, which is remarkably important not only for this specific study but also for other various polymer EOR applications.

Storage of CO2 and Coal Fly Ash using Pickering Foam for Enhanced Oil Recovery

CO2 foams have been used for a long time for enhanced oil recovery (EOR) and carbon capture, utilization, and storage. Note that conventional CO2 foam focuses on mobility control and storage of bare CO2. However, this technology has suffered from low storage efficiency and EOR because of foam instability. In this study, the geological storage of CO2 and coal fly ash (CFA) using Pickering foam for EOR was explored. The aim is to obtain an inexpensive method for EOR and storage of greenhouse gases and atmospheric pollutants. The Pickering foam was prepared using Waring blender method. The experiments were conducted to evaluate CO2/liquid interface enhancement by measuring the interfacial tension and interfacial viscoelastic modulus. As per the heterogeneous sandpack flooding experiments, the profile control capacity and the performance of oil displacement using CO2 foam enhanced by CFA were investigated. The amount of storage from dynamic aspects of CO2 and CFA was measured to demonstrate the storage law. The stability of aqueous foam was improved significantly after the addition of CFA. The half-life time of foam stabilized by CFA particles increased by more than about 11 times than that of foam without CFA particles. The interfacial dilatational viscoelastic modulus of CO2/foaming solution increased with CFA particle concentration increasing, indicating the interface transformed from liquid-like to solid-like. Flooding experiments in heterogeneous porous media showed that more produced fluid was displaced from the relatively low-permeability sandpack after the injection of CO2 foam with CFA. The oil recovery by CFA stabilized foam was improved by ~28.3% than that of foam without CFA particles. And the sequestration of CO2 in heterogeneous porous media was enhanced with the addition of CFA to CO2 foam, and the CFA stabilized foam displayed a strong resistance to water erosion for the storage of CO2 and CFA. This work introduces a win–win method for EOR and storage of CO2 and atmospheric pollutant particles. CFA from coal combustion was used as an enhancer for CO2 foam, which improved the interfacial dilatational viscoelasticity of foam film and the dynamic storage of CO2. Furthermore, the storage of CO2 and CFA contributed to improvement in sweep efficiency, and thus EOR.