Excited states of isolated fermions in the Higgs phase of gauge Higgs theories

We present evidence that seemingly elementary and non-composite objects, namely isolated static fermions in certain gauge Higgs theories, have a mass spectrum corresponding to localized excitations of the surrounding gauge and Higgs fields.

Optical Activity of Metal Nanoclusters Deposited on Regular and Doped Oxide Supports from First-Principles Simulations

We report a computational study and analysis of the optical absorption processes of Ag20 and Au20 clusters deposited on the magnesium oxide (100) facet, both regular and including point defects. Ag20 and Au20 are taken as models of metal nanoparticles and their plasmonic response, MgO as a model of a simple oxide support. We consider oxide defects both on the oxygen anion framework (i.e., a neutral oxygen vacancy) and in the magnesium cation framework (i.e., replacing Mg++ with a transition metal: Cu++ or Co++). We relax the clusters’ geometries via Density-Functional Theory (DFT) and calculate the photo-absorption spectra via Time-Dependent DFT (TDDFT) simulations on the relaxed geometries. We find that the substrate/cluster interaction induces a broadening and a red-shift of the excited states of the clusters, phenomena that are enhanced by the presence of an oxygen vacancy and its localized excitations. The presence of a transition-metal dopant does not qualitatively affect the spectral profile. However, when it lies next to an oxygen vacancy for Ag20, it can strongly enhance the component of the cluster excitations perpendicular to the surface, thus favoring charge injection.

Novel Soliton Molecules and Wave Interactions for A (3+1)-Dimensional Nonlinear Evolutionary Equation

New wave excitations are revealed for a (3+1)-dimensional nonlinear evolution equation to enrich nonlinear wave patterns in nonlinear systems. Based on a new variable separation solution with two arbitrary variable separated functions obtained by means of the multilinear variable separation approach, localized excitations of N dromions, N x M lump lattice and N x M ring soliton lattice are explored. Interestingly, it is observed that soliton molecules can be composed of diverse "atoms" such as the dromions, lumps and ring solitons, respectively. Elastic interactions between solitons and soliton molecules are graphically demonstrated.

Vibrational resonant inelastic X-ray scattering in liquid acetic acid: a ruler for molecular chain lengths

Quenching of vibrational excitations in resonant inelastic X-ray scattering (RIXS) spectra of liquid acetic acid is observed. At the oxygen core resonance associated with localized excitations at the O–H bond, the spectra lack the typical progression of vibrational excitations observed in RIXS spectra of comparable systems. We interpret this phenomenon as due to strong rehybridization of the unoccupied molecular orbitals as a result of hydrogen bonding, which however cannot be observed in x-ray absorption but only by means of RIXS. This allows us to address the molecular structure of the liquid, and to determine a lower limit for the average molecular chain length.

Painlevé Analysis, Soliton Molecule, and Lump Solution of the Higher-Order Boussinesq Equation

The Painlevé integrability of the higher-order Boussinesq equation is proved by using the standard Weiss-Tabor-Carnevale (WTC) method. The multisoliton solutions of the higher-order Boussinesq equation are obtained by introducing dependent variable transformation. The soliton molecule and asymmetric soliton of the higher-order Boussinesq equation can be constructed by the velocity resonance mechanism. Lump solution can be derived by solving the bilinear form of the higher-order Boussinesq equation. By some detailed calculations, the lump wave of the higher-order Boussinesq equation is just the bright form. These types of the localized excitations are exhibited by selecting suitable parameters.

Vibrational Resonant Inelastic X-Ray Scattering Inliquid Acetic Acid: A Ruler for Molecular Chain Lengths

Quenching of vibrational excitations in resonant inelastic X-ray scattering (RIXS) spectra of liquid acetic acid is observed. At the oxygen core resonance associated with localized excitations at the O-H bond, the spectra lack the typical progressionof vibrational excitations observed in RIXS spectra of comparable systems. We interpret this phenomenon as due to strong rehybridization of the unoccupied molecular orbitals as a result of hydrogen bonding. This allows us to address the molecular structure of the liquid, and to determine a lower limit for the average molecular chain length.