CHARACTERIZATION OF BIDIRECTIONAL TRANSMISSIVE AND REFLECTIVE PROPERTIES OF BLACK SILICON

This paper describes the initial work of characterizing the transmissive and reflective properties of black silicon diffusers. The diffusers were fabricated from a 100 mm diameter black silicon sample at NASA’s Goddard Space Flight Center (GSFC). The directional hemispherical reflectance from 250 nm to 2500 nm and BRDF/BTDF measurements at 632.8 nm, 1064 nm, and 1550 nm were measured using the GSFC Diffuser Calibration Laboratory’s (DCL) spectrophotometer and optical scatterometer. The diffusers exhibit a low level of specular reflection up to ~1100 nm with no evidence of retroscatter. The measurements are traceable to those made at the National Institute of Standards and Technology (NIST).

Cutting out the middleman: calibrating and validating a dynamic vegetation model (ED2-PROSPECT5) using remotely sensed surface reflectance

Canopy radiative transfer is the primary mechanism by which models relate vegetation composition and state to the surface energy balance, which is important to light- and temperature-sensitive plant processes as well as understanding land–atmosphere feedbacks. In addition, certain parameters (e.g., specific leaf area, SLA) that have an outsized influence on vegetation model behavior can be constrained by observations of shortwave reflectance, thus reducing model predictive uncertainty. Importantly, calibrating against radiative transfer outputs allows models to directly use remote sensing reflectance products without relying on highly derived products (such as MODIS leaf area index) whose assumptions may be incompatible with the target vegetation model and whose uncertainties are usually not well quantified. Here, we created the EDR model by coupling the two-stream representation of canopy radiative transfer in the Ecosystem Demography model version 2 (ED2) with a leaf radiative transfer model (PROSPECT-5) and a simple soil reflectance model to predict full-range, high-spectral-resolution surface reflectance that is dependent on the underlying ED2 model state. We then calibrated this model against estimates of hemispherical reflectance (corrected for directional effects) from the NASA Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and survey data from 54 temperate forest plots in the northeastern United States. The calibration significantly reduced uncertainty in model parameters related to leaf biochemistry and morphology and canopy structure for five plant functional types. Using a single common set of parameters across all sites, the calibrated model was able to accurately reproduce surface reflectance for sites with highly varied forest composition and structure. However, the calibrated model's predictions of leaf area index (LAI) were less robust, capturing only 46 % of the variability in the observations. Comparing the ED2 radiative transfer model with another two-stream soil–leaf–canopy radiative transfer model commonly used in remote sensing studies (PRO4SAIL) illustrated structural errors in the ED2 representation of direct radiation backscatter that resulted in systematic underestimation of reflectance. In addition, we also highlight that, to directly compare with a two-stream radiative transfer model like EDR, we had to perform an additional processing step to convert the directional reflectance estimates of AVIRIS to hemispherical reflectance (also known as “albedo”). In future work, we recommend that vegetation models add the capability to predict directional reflectance, to allow them to more directly assimilate a wide range of airborne and satellite reflectance products. We ultimately conclude that despite these challenges, using dynamic vegetation models to predict surface reflectance is a promising avenue for model calibration and validation using remote sensing data.

Hyperspectral longwave infrared reflectance spectra of naturally dried algae, anthropogenic plastics, sands and shells

Remote sensing of litter is foreseen to become an important source of additional information relevant to scientific awareness about plastic pollution. Here, we document directional hemispherical reflectance measurements of anthropogenic and natural materials gathered along the shorelines of the Chiloé Archipelago, Chile. These spectral observations were completed in a Chilean laboratory using a state-of-the-art hyperspectral HyLogger-3™ thermal infrared (TIR) spectrometer starting from the medium-wave infrared spectrum (6 µm) and going to the longwave infrared (14.5 µm) spectrum at 0.025 µm intervals. The samples we investigated included sands, shells, algae, nautical ropes, Styrofoam®, gunny sacks and several fragments of plastic-based items. The apparent visible colours of these samples included shades of black, blue, brown, green, orange, white and yellow. We grouped the samples using robust statistical approaches (derivatives, peak-seeking technique) and visual analyses of the derived hyperspectral reflectances. In each group we derived an average or TIR end-member signal and determined diagnostic wavebands. Most of the diagnostic wavebands picked were found to be inside the atmospheric window of the TIR spectrum region. Furthermore, this laboratory reference dataset and findings might become useful in related field observations using similar thermal infrared technologies, especially in identifying anomalies resulting from environmental and meteorological perturbations. Validation and verification of proposed diagnostic wavebands would be part of a continuing effort to advance TIR remote sensing knowledge as well as support robust detection algorithm development to potentially distinguish plastics in litter throughout the natural environments. Data are available in open-access form via the online repository PANGAEA, database of the World Data Center for Marine Environmental Sciences: https://doi.org/10.1594/PANGAEA.919536 (Acuña-Ruz and Mattar, 2020).

Redefining the Directional-Hemispherical Reflectance and Transmittance of Needle-Shaped Leaves to Address Issues in Their Existing Measurement Methods

The directional-hemispherical reflectance and transmittance of needle-shaped leaves are redefined in this study. We suggest that the reflected and transmitted radiation of a leaf should be distinguished by the illuminated and shaded leaf surfaces rather than the usual separation of the two hemispheres by a plane perpendicular to the incoming radiation. Through theoretical analysis, we found that needle directional-hemispherical reflectance and transmittance measured by two existing techniques, namely Daughtry's method and Harron's method, could be significantly biased. This finding was proved by ray-tracing simulations intuitively as well as by inversions of the PROSPECT model indirectly. We propose the following requirements for needle spectral measurement in an integrating sphere: needles should be fully exposed to the light source, the interfusion of reflected and transmitted radiation on convex needle surfaces should be avoided, and multiple scattering of radiation among needles should be minimized.

Validation of Space-Based Albedo Products from Upscaled Tower-Based Measurements Over Heterogeneous and Homogeneous Landscapes

Surface albedo is a fundamental radiative parameter as it controls the Earth’s energy budget and directly affects the Earth’s climate. Satellite observations have long been used to capture the temporal and spatial variations of surface albedo because of their continuous global coverage. However, space-based albedo products are often affected by errors in the atmospheric correction, multi-angular bi-directional reflectance distribution function (BRDF) modelling, as well as spectral conversions. To validate space-based albedo products, an in situ tower albedometer is often used to provide continuous “ground truth” measurements of surface albedo over an extended area. Since space-based albedo and tower-measured albedo are produced at different spatial scales, they can be directly compared only for specific homogeneous land surfaces. However, most land surfaces are inherently heterogeneous with surface properties that vary over a wide range of spatial scales. In this work, tower-measured albedo products, including both directional hemispherical reflectance (DHR) and bi-hemispherical reflectance (BHR), are upscaled to coarse satellite spatial resolutions using a new method. This strategy uses high-resolution satellite derived surface albedos to fill the gaps between the albedometer’s field-of-view (FoV) and coarse satellite scales. The high-resolution surface albedo is generated from a combination of surface reflectance retrieved from high-resolution Earth Observation (HR-EO) data and moderate resolution imaging spectroradiometer (MODIS) BRDF climatology over a larger area. We implemented a recently developed atmospheric correction method, the Sensor Invariant Atmospheric Correction (SIAC), to retrieve surface reflectance from HR-EO (e.g., Sentinel-2 and Landsat-8) top-of-atmosphere (TOA) reflectance measurements. This SIAC processing provides an estimated uncertainty for the retrieved surface spectral reflectance at the HR-EO pixel level and shows excellent agreement with the standard Landsat 8 Surface Reflectance Code (LaSRC) in retrieving Landsat-8 surface reflectance. Atmospheric correction of Sentinel-2 data is vastly improved by SIAC when compared against the use of in situ AErosol RObotic NETwork (AERONET) data. Based on this, we can trace the uncertainty of tower-measured albedo during its propagation through high-resolution EO measurements up to coarse satellite scales. These upscaled albedo products can then be compared with space-based albedo products over heterogeneous land surfaces. In this study, both tower-measured albedo and upscaled albedo products are examined at Ground Based Observation for Validation (GbOV) stations (https://land.copernicus.eu/global/gbov/), and used to compare with satellite observations, including Copernicus Global Land Service (CGLS) based on ProbaV and VEGETATION 2 data, MODIS and multi-angle imaging spectroradiometer (MISR).

Design and Fabrication of Dual-Scale Broadband Antireflective Structures on Metal Surfaces by Using Nanosecond and Femtosecond Lasers

Antireflective surfaces, with their great potential applications, have attracted tremendous attention and have been the subject of extensive research in recent years. However, due to the significant optical impedance mismatch between a metal surface and free space, it is still a challenging issue to realize ultralow reflectance on a metal surface. To address this issue, we propose a two-step strategy for constructing antireflective structures on a Ti-6Al-4V (TC4) surface using nanosecond and femtosecond pulsed lasers in combination. By controlling the parameters of the nanosecond laser, microgrooves are first scratched on the TC4 surface to reduce the interface reflection. Then, the femtosecond laser is focused onto the sample surface with orthogonal scanning to induce deep air holes and nanoscale structures, which effectively enhances the broadband absorption. The antireflection mechanism of the dual-scale structures is discussed regarding morphological characterization and hemispherical reflectance measurements. Finally, the modified sample surface covered with micro-nano hybrid structures is characterized by an average reflectance of 3.1% over the wavelengths ranging from 250 nm to 2250 nm.

Intercomparison of Surface Albedo Retrievals from MISR, MODIS, CGLS Using Tower and Upscaled Tower Measurements

Surface albedo is of crucial interest in land–climate interaction studies, since it is a key parameter that affects the Earth’s radiation budget. The temporal and spatial variation of surface albedo can be retrieved from conventional satellite observations after a series of processes, including atmospheric correction to surface spectral bi-directional reflectance factor (BRF), bi-directional reflectance distribution function (BRDF) modelling using these BRFs, and, where required, narrow-to-broadband albedo conversions. This processing chain introduces errors that can be accumulated and then affect the accuracy of the retrieved albedo products. In this study, the albedo products derived from the multi-angle imaging spectroradiometer (MISR), moderate resolution imaging spectroradiometer (MODIS) and the Copernicus Global Land Service (CGLS), based on the VEGETATION and now the PROBA-V sensors, are compared with albedometer and upscaled in situ measurements from 19 tower sites from the FLUXNET network, surface radiation budget network (SURFRAD) and Baseline Surface Radiation Network (BSRN) networks. The MISR sensor onboard the Terra satellite has 9 cameras at different view angles, which allows a near-simultaneous retrieval of surface albedo. Using a 16-day retrieval algorithm, the MODIS generates the daily albedo products (MCD43A) at a 500-m resolution. The CGLS albedo products are derived from the VEGETATION and PROBA-V, and updated every 10 days using a weighted 30-day window. We describe a newly developed method to derive the two types of albedo, which are directional hemispherical reflectance (DHR) and bi-hemispherical reflectance (BHR), directly from three tower-measured variables of shortwave radiation: downwelling, upwelling and diffuse shortwave radiation. In the validation process, the MISR, MODIS and CGLS-derived albedos (DHR and BHR) are first compared with tower measured albedos, using pixel-to-point analysis, between 2012 to 2016. The tower measured point albedos are then upscaled to coarse-resolution albedos, based on atmospherically corrected BRFs from high-resolution Earth observation (HR-EO) data, alongside MODIS BRDF climatology from a larger area. Then a pixel-to-pixel comparison is performed between DHR and BHR retrieved from coarse-resolution satellite observations and DHR and BHR upscaled from accurate tower measurements. The experimental results are presented on exploring the parameter space associated with land cover type, heterogeneous vs. homogeneous and instantaneous vs. time composite retrievals of surface albedo.