Strength of Chemically Stabilized Sewage Sludge—Some Inferences from Recent Studies

Although there has been a substantial body of research on the chemical stabilization of sewage sludge, most of these results are project-specific and relate mainly to the use of new binders and sewage sludge from specific sources. In this sense, much of the work to date is context-specific. At present, there is still no general framework for estimating the strength of the chemically treated sludge. This paper proposes one such general framework, based on data from some recent studies. An in-depth re-interpretation of the data is first conducted, leading to the observation that sludge, which has coarse, hard particulate inclusions, such as sand, premixed into it, gives significantly higher strength. This was attributed to the hard coarse particles that lower the void ratio of treated soil, are much less susceptible to volume collapse under pressure, and contribute to the strength through frictional contacts and interlocking. This motivates the postulation of a general framework, based on the premise that coarse, hard particulate inclusions in the sludge which do not react with the binders can nonetheless contribute to the strength of the treated soil. The overall void ratio, defined as the volume of voids in the cementitious matrix normalised by the overall volume, is proposed as a parameter for quantifying the combined effect of the coarse particulate inclusions and the cementitious matrix. The binder-sludge ratio is another parameter which quantifies the strength of the cementitious matrix, excluding the hard particulate inclusions. Back-analysis of the data suggests that the significance of the binder-sludge ratio may diminish as the content of hard particulate inclusions increases.

Nanobelts-constructed Porous TiO2-B@SnS2 Heterostructure Hybrids for Enhance Lithium Storage Performance

Alloy-type anodes materials possess broad prospects for excellent electrochemical property lithium-ion batteries owing to its high theoretical capacity and excellent electronic conductivity. However, this type electrode materials experience poor kinetics and tremendous volume collapse during the repeated lithiation-delithiation process. Herein, an efficient method to provide a fast transmission channel and suppress the volume collapse during the discharge/charge process by constructing the heterostructure between porous TiO2-B nanoblets and few-layer SnS2 nanosheets interface, which provides high-active sites for the nucleation and growth of SnS2 nanosheets, and inhibits the agglomeration of SnS2 nanosheets. Both experimental results and theoretical calculations definite that porous TiO2 nanobelts provides more chemical active sites for the adsorption and transmission of lithium ion and then effectively improve the stability the electrode structure. As a result, TiO2-B@SnS2 hybrid exhibits excellent rate and cycle performance. This work paves a way to design and construction of high performance alloy-type anode materials.

Phase transitions in ε-FeOOH at high pressure and ambient temperature

Constraining the accommodation, distribution, and circulation of hydrogen in the Earth's interior is vital to our broader understanding of the deep Earth due to the significant influence of hydrogen on the material and rheological properties of minerals. Recently, a great deal of attention has been paid to the high-pressure polymorphs of FeOOH (space groups P21nm and Pnnm). These structures potentially form a hydrogen-bearing solid solution with AlOOH and phase H (MgSiO4H2) that may transport water (OH–) deep into the Earth's lower mantle. Additionally, the pyrite-type polymorph (space group Pa3 of FeOOH), and its potential dehydration have been linked to phenomena as diverse as the introduction of hydrogen into the outer core (Nishi et al. 2017), the formation of ultralow-velocity zones (ULVZs) (Liu et al. 2017), and the Great Oxidation Event (Hu et al. 2016). In this study, the high-pressure evolution of FeOOH was re-evaluated up to ~75 GPa using a combination of synchrotron-based X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and optical absorption spectroscopy. Based on these measurements, we report three principal findings: (1) pressure-induced changes in hydrogen bonding (proton disordering or hydrogen bond symmetrization) occur at substantially lower pressures in ε-FeOOH than previously reported and are unlikely to be linked to the high-spin to low-spin transition; (2) ε-FeOOH undergoes a 10% volume collapse coincident with an isostructural Pnnm → Pnnm transition at approximately 45 GPa; and (3) a pressure-induced band gap reduction is observed in FeOOH at pressures consistent with the previously reported spin transition (40 to 50 GPa).

On the Integrated Surface Uplift for Dip‐Slip Faults

Interferometric Synthetic Aperture Radar observations often provide maps of vertical displacement that can be integrated to estimate an uplift volume. Relating this measure to source processes requires a model of the deformation. Bignami et al. (2019) argue that the negative uplift volume associated with the 2016 Amatrice–Norcia, central Italy, earthquake sequence requires a coseismic volume collapse of the hanging wall. Using results for dip‐slip dislocations in an elastic half‐space we show that Vuplift=(P/4)(1−2ν)sin(2δ), in which P is the seismic potency, ν is the Poisson’s ratio, and δ is the fault dip, consistent with an earlier result of Ward (1986). For reasonable estimates of net potency for the 2016 Amatrice–Norcia sequence, this simple formula yields uplift volume estimates close to that observed. We conclude that the data are completely consistent with elastic dislocation theory and do not require a volume collapse at depth.

Compressional behavior and spin state of δ-(Al,Fe)OOH at high pressures

Hydrogen transport from the surface to the deep interior and distribution in the mantle are important in the evolution and dynamics of the Earth. An aluminum oxy-hydroxide, δ-AlOOH, might influence hydrogen transport in the deep mantle because of its high stability extending to lower mantle conditions. The compressional behavior and spin states of δ-(Al,Fe3+)OOH phases were investigated with synchrotron X-ray diffraction and Mössbauer spectroscopy under high pressure and room temperature. Pressure-volume (P-V) profiles of the δ-(Al0.908(9)57Fe0.045(1))OOH1.14(3) [Fe/(Al+Fe) = 0.047(10), δ-Fe5] and the δ-(Al0.832(5)57Fe0.117(1))OOH1.15(3) [Fe/(Al+Fe) = 0.123(2), δ-Fe12] show that these hydrous phases undergo two distinct structural transitions involving changes in hydrogen bonding environments and a high- to low-spin crossover in Fe3+. A change of axial compressibility accompanied by a transition from an ordered (P21nm) to disordered hydrogen bond (Pnnm) occurs near 10 GPa for both δ-Fe5 and δ-Fe12 samples. Through this transition, the crystallographic a and b axes become stiffer, whereas the c axis does not show such a change, as observed in pure δ-AlOOH. A volume collapse due to a transition from high- to low-spin states in the Fe3+ ions is complete below 32–40 GPa in δ-Fe5 and δ-Fe12, which i ~10 GPa lower than that reported for pure ε-FeOOH. Evaluation of the Mössbauer spectra of δ-(Al0.824(10)57Fe0.126(4))OOH1.15(4) [Fe/(Al+Fe) = 0.133(3), δ-Fe13] also indicate a spin transition between 32–45 GPa. Phases in the δ-(Al,Fe)OOH solid solution with similar iron concentrations as those studied here could cause an anomalously high ρ/νΦ ratio (bulk sound velocity, defined as K/ρ at depths corresponding to the spin crossover region (~900 to ~1000 km depth), whereas outside the spin crossover region a low ρ/νΦ anomaly would be expected. These results suggest that the δ-(Al,Fe)OOH solid solution may play an important role in understanding the heterogeneous structure of the deep Earth.