The relationship of destinezite to the acid sulfate alteration at the El Laco magnetite deposit, Chile

Destinezite, ideally Fe23+(PO4)(SO4)(OH)·6(H2O), is found as nodular lumps in hematite-rich epiclastic sediments accumulated in small crater lakes on the slopes of El Laco volcano. These lumps are almost entirely dominated by fine-grained destinezite replacing earlier lipscombite, and associated with gray hematite. The crystal structure of destinezite has been re-examined to test for possible differences with respect to the earthy and poorly crystalline destinezite that forms by weathering in cave soils and mine waste dumps. The structural refinements confirm that the differences are minor. The El Laco destinezite was refined in space group P1 with a = 9.5828(2), b = 9.7440(3), c = 7.3302(3) Å, and α = 98.796(3)°, β = 107.985(3)°, γ = 63.898(2)°, V = 584.50(4) Å3, and Z = 1. We measured by calorimetry the enthalpy and derived the entropy and the Gibbs free energy of formation of destine-zite (–4051.7 ± 4.3, –1518.5 ± 20.0, and –3598.9 ± 7.1 kJ/mol, respectively). This has allowed us to estimate the equilibrium constant in the temperature range 0–300 °C (log K = –27.97 ± 1.1). We can predict that destinezite coexists with hematite over the range of conditions that typically encompass the steam-heated hydrothermal environments recognized at El Laco. The presence of destinezite along with hematite and the occurrence of alunite, jarosite, and variscite in the system provide evidence of intense hydrothermal alteration during the extrusion of Fe-rich melts at El Laco volcano. The mineral assemblage and the available geochemical data suggest that destinezite formed in hydrothermal conditions by “maturation” of an immiscible Fe–P-rich melt. An unknown Fe–P–O phase produced by this melt was first replaced by lipscombite and later, owing to intense sulfidation, by destinezite. This replacement took place in the vadose zone above the paleowater table by relatively cool (<150 °C) groundwaters acidified by oxidation of magmatic SO2 to aqueous sulfate in a steam-heated system. Our model precludes other modes of formation, such as devitrification of hypothetical Fe–P–S–O-rich melts ejected from the volcano and supergene crystallization.

The conservation status of the Galapagos Martin Progne modesta: Assessment of historical records and results of recent surveys

Summary The endemic Galapagos Martin Progne modesta is a rare species. Population sizes in the past are unknown, but the few reports available suggest that it has become rarer in some sites. To obtain a better understanding of its population status, a simultaneous survey was conducted in 2017 around the coastline of 14 islands and 23 islets resulting in sightings of only 26 individuals. A simultaneous survey on Sierra Negra volcano on Isabela Island added five more individuals. However, observations from early expeditions and expeditions since 2015 have shown that the volcanoes of Isabela Island are important feeding areas and probable breeding areas for the Galapagos Martin, but these were largely excluded from the survey in 2017 due to logistical reasons. Historical and recent nesting sites include Tagus Cove on Isabela Island and Daphne Major Island. During our 2017 count, three possible new nesting sites were discovered: Daphne Minor, Santiago and a small crater on Punta Cristóbal on southwestern Isabela Island. From 2015 to 2018, 15 nests were also observed on the cliff in Tagus Cove. Two accessible nests were collected and revealed the first records of Philornis downsi in Galapagos Martin nests. The impact of parasitism by P. downsi is unknown but potentially severe. Given the lack of general knowledge about the biology of this species and its apparent low population sizes, further studies are urgently needed.

Cratering and age of the small Saturnian satellites

Context. The small (≤135 km mean radius) satellites of Saturn are closely related to its rings and together they constitute a complex dynamical system where formation and destruction mechanisms compete against each other. The Cassini-Huygens mission provided high-resolution images of the surfaces of these satellites and therefore allowed for the calculation of observational crater counts. Aims. We model the cratering process by Centaur objects on the small Saturnian satellites, and compare our results with the observational crater counts obtained from the Voyager and Cassini missions. Methods. Using a theoretical model previously developed we calculate the crater production on these satellites considering two slopes of the size-frequency distribution (SFD) for the smaller objects of the Centaur population and compare our results with the available observations. In addition, we consider the case of catastrophic collisions between these satellites and Centaur objects and calculate the age of formation of those satellites that suffer one or more disruptions. Results. In general we find that the observed crater distributions are best modeled by the crater size distribution corresponding to the s2 = 3.5 index of the SFD of impactors with diameters smaller than 60 km. However, for crater diameters D ≲ 3–8 km (which correspond to impactor diameters d ~ 0.04–0.15 km), the observed distributions become flatter and deviate from our results, which may evidence processes of erosion and/or crater saturation at small crater sizes or a possible break in the SFD of impactors at d ~ 0.04–0.15 km to a much shallower differential slope of approximately − 1.5. Our results suggest that Pan, Daphnis, Atlas, Aegaeon, Methone, Anthe, Pallene, Calypso, and Polydeuces suffered one or more catastrophic collisions over the age of the solar system, the younger being associated to arcs with ages of ~108 yr. We have also calculated surface ages for the satellites, which indicate ongoing resurfacing processes.

Psoralea forbesiae (Psoraleeae, Fabaceae), a new species from the Swartberg Mountains of South Africa

Psoraleaforbesiae C.H.Stirt., A.Bello & Muasya is a new species of Psoraleeae, Fabaceae. Psoraleaforbesiae is endemic to the Swartberg Mountains and is a tall densely branched re-sprouting shrub up to 2.5 m, with bluish-green stems and with most parts covered in small crater-like glands, leaves pinnately 3-foliolate, linear-oblong, pale bluish-green, semi-conduplicate, somewhat succulent, glabrous, crowded at the end of bare branches on older stems or distributed along short branches on young shoots, petiolate. A description of P.forbesiae, together with photographs and a distribution map are presented.

AUTOMATION OF MORPHOMETRIC MEASUREMENTS FOR PLANETARY SURFACE ANALYSIS AND CARTOGRAPHY

For automation of measurements of morphometric parameters of surface relief various tools were developed and integrated into GIS. We have created a tool, which calculates statistical characteristics of the surface: interquartile range of heights, and slopes, as well as second derivatives of height fields as measures of topographic roughness. Other tools were created for morphological studies of craters. One of them allows automatic placing of topographic profiles through the geometric center of a crater. Another tool was developed for calculation of small crater depths and shape estimation, using C++ programming language. Additionally, we have prepared tool for calculating volumes of relief features from DTM rasters. The created software modules and models will be available in a new developed web-GIS system, operating in distributed cloud environment.

AUTOMATION OF MORPHOMETRIC MEASUREMENTS FOR PLANETARY SURFACE ANALYSIS AND CARTOGRAPHY

For automation of measurements of morphometric parameters of surface relief various tools were developed and integrated into GIS. We have created a tool, which calculates statistical characteristics of the surface: interquartile range of heights, and slopes, as well as second derivatives of height fields as measures of topographic roughness. Other tools were created for morphological studies of craters. One of them allows automatic placing of topographic profiles through the geometric center of a crater. Another tool was developed for calculation of small crater depths and shape estimation, using C++ programming language. Additionally, we have prepared tool for calculating volumes of relief features from DTM rasters. The created software modules and models will be available in a new developed web-GIS system, operating in distributed cloud environment.