Geochemical characterization of clastic sediments sheds light on energy sources and on alleged anthropogenic impacts in cave ecosystems

Caves are usually oligotrophic ecosystems, where the organic matter represents a limiting factor to the hypogeal community and sediments are often a significant energy source. With a view to identifying the energy input influencing the ecological processes occurring in caves, as well as the potential alteration sources of the natural equilibriums, geochemical features of several typologies of clastic sediments from the Pertosa-Auletta Cave (Italy) were investigated. The collected sediments, analyzed for a number of chemical (organic matter, Al, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, S, Si, Sr, Ti, V, Zn concentrations) and mineralogical (quartz, calcite, dolomite, clay minerals) characteristics, showed a different composition. Overall, their origin is supposed to be allochthonous, related to the important fluviokarst activities interesting the cave in the past, whereas the abundance of calcitic and dolomitic compounds can be autochthonous, being the carbonate the main host rock. The highest concentrations of organic matter, together with C, Cu, Mo, N, P, Pb, S and Zn, highlighted in one sample composed mainly of bats guano, revealed an important bioavailable energy input as well as a pollutant accumulation, mainly of anthropogenic origin.

Trends and Composition—A Sedimentological-Chemical-Mineralogical Approach to Constrain the Origin of Quaternary Deposits and Landforms—From a Review to a Manual

In this study, six basic Quaternary landform series (LFS) and their sedimentary deposits (LFS1 aeolian, LFS 2.1 to 2.2 mass wasting, LFS 3 cryogenic-glacial, LFS 4.1 to 4.6 fluvial, LFS 5.1 to 5.2 coastal-marine, LFS 6.1 to 6.3 lacustrine) are subdivided into subtypes and examined with regard to their sedimentological parameters and their mineralogical and chemical compositions. Emphasis is placed on the textural (related to transport and deposition), compositional (sediment load/weight, Eh and pH) and geodynamic maturity of the sedimentary deposits which are influenced by the parent lithology and bedrock tectonic and by the climate during the last 2 Ma. To constrain the development of the LFS and their sediments, composite trend-line diagrams are designed combining sedimentological (x-axis) and chemical/mineralogical dataset (y-axis): (1) sorting vs. heavy mineral content; (2) sphericity of grains vs. silica/carbonate contents; and (3) median vs. Ti/Fe ratios. In addition, the x-y plots showing the log SiO2/Al2O3 vs. log Na2O/K2O are amended by a dataset of the three most common clay minerals, i.e., kaolinite-, mica-, and smectite-group clay minerals. Such joint sedimentological-chemical-mineralogical investigations focused on the depositional environment of unconsolidated clastic sediments of Quaternary age can be used to describe the economic geology and environmental geology of mineral deposits in the pre-Quaternary sedimentary series according to the phrase: “The Present is the key to the Past”. Both trend diagrams and compositional x-y plots can contribute to constraining the development of the full transect of landform series from the fluvial incision and slope retreat to reef islands fringing the coastal zone towards the open sea as far as they are built up of clastic sedimentary deposits enriched in siliceous and/or carbonate minerals. Climate zonation and crustal maturity are the exogenous and endogenous “drivers”, as can be deduced from the compositional (mineralogy and chemistry) and physical (transport and deposition) variations observed in the Quaternary sediments. The current study bridges the gap between a review only based on literature and a hybrid manual generated by practical field studies devoted to applied geosciences in economic and environmental geology (“E & E issue”).

Revisiting the phosphorite deposit of Fontanarejo (central Spain): new window into the early Cambrian evolution of sponges and the microbial origin of phosphorites

Fossils within early Cambrian phosphorites worldwide are often well preserved due to early diagenetic permineralization. Here, we examine the fossil record contained within phosphorites of the Lower Cambrian Pusa Formation (late Fortunian to Cambrian Stage 2) in Fontanarejo, central Spain. The sedimentology and age of these phosphorites have been controversial and are here reviewed and discussed, providing also an updated geological map. The Pusa Formation is composed of fine clastic sediments that are partly turbiditic, with channels of quartz-rich conglomerates and abundant phosphorites in the upper part of the succession. The microfacies and mineralogy of these channel deposits are studied here for the first time in detail, showing that they are mainly composed of subspherical apatite clasts, with minor mudstone intraclasts, quartzite and mica grains. Numerous sponge spicules, as well as entirely preserved hexactinellid sponges and demosponges, were collected within these phosphorites and likely represent stem groups. In addition to sponges, other fossils, such as small shelly fossils (SSF) of the mollusc Anabarella sp., were found. The phosphorites exhibit multiple evidence of intense microbial activity, including diverse fabrics (phosphatic oncoidal-like microbialites, thrombolites, stromatolites and cements) and abundant fossils of filamentous microbes that strongly resemble extant sulphur-oxidizing bacteria. Our findings strongly suggest that microbial processes mediated the rapid formation of most of the Fontanarejo apatite, probably accounting for the exceptional preservation of fragile fossils such as sponge skeletons. The apparent presence of taxonomically diverse hexactinellid and demosponge communities at the lowermost Cambrian further corroborates a Precambrian origin of the phylum Porifera.

Fluvial-Tidal to Fluvial-Lacustrine Sedimentation of the Middle Miocene to Pleistocene Mapia Formation, Dogiyai, Papua (Indonesia)

A sedimentological and palynological investigation was carried out on outcropping sedimentary rocks at Dogiyai, Papua, proposed to be named as the Mapia Formation. The age range is from Middle Miocene to Pleistocene. The lower Mapia Formation was deposited at Metroxylon type to Nothofagus emarcida Zone, Middle Miocene to Early Pliocene. It is comprised of three facies associations: tidal channel, tidal point bar, and tidal flat deposits. A tidally dominated fluvially influenced depositional environment is suggested for the deposition of sediments of this unit. The upper Mapia Formation was deposited at Malvacipollis diversus Zone, Garcinia cuspidata type Zone, and Proteacidites sp. Zone, Late Pliocene to Pleistocene. It is comprised of five facies associations: delta front, slump, debrite, turbidite, and lacustrine mud deposits. A non-channelized deep-lacustrine slump and debris-flow dominated depositional environment is suggested for the deposition of sediments of this unit. The lower Mapia Formation was deposited as synorogenic clastic sediments at the beginning of Central Range orogeny event while the upper Mapia Formation was deposited in the piggyback basin at the major uplift event.

Oligomictic alluvial aggregates: petro-mineralogical and geochemical evaluation of sandy gravel formations on the middle course of the Danube (Hungary)

This paper evaluates the applicability of Hungarian oligomictic alluvial gravel formations at two sections of the Danube river for construction use. The classification of these aggregates is more challenging than monomictic rock aggregates due to their heterogeneous nature. Multi-source clastic sediments cannot be characterized by single values of physical properties but only a distribution, and they are generally less predictable than monomictic materials. The possible applications in concrete manufacturing were evaluated by complex macro-microscopic petrographic, heavy mineral and nuclear analytical geochemical investigations. The two regions falling on the middle course of the Danube have similar sandy gravel formations, applicable as aggregates for conventional and unconventional concrete building purposes or road construction. Their utilization in open-air constructions might be problematic due to their probable alkali-silica reactivity.

Biotic and stable-isotope characterization of the Toarcian Ocean Anoxic Event through a carbonate-clastic sequence from Somerset, UK

This study focuses on a condensed sequence of alternating carbonate-clastic sediments of the Barrington Member, Beacon Limestone Formation (latest Pliensbachian to early Toarcian) from Somerset (south west England). Abundant ammonites confirm (apart from the absence of the Clevelandicum and Tenuicostatum ammonite subchronozones) the presence of Hawskerense Subchronozone to Fallaciosum-Bingmanni subchronozones. Well-preserved, sometimes diverse assemblages of ostracods, foraminifera, nannofossils and low diversity dinoflagellate assemblages support the chronostratigraphic framework. Stable-isotope analyses demonstrate the presence of a carbon isotope excursion (CIE), relating to the Toarcian Oceanic Anoxic Event (T-OAE), within the early Toarcian. Faunal, geochemical and sedimentological evidence suggest that deposition largely took place in a relatively deep-water (sub-wave base), mid-outer shelf environment under a well-mixed water column. However, reduced benthic diversity, the presence of weakly-laminated sediments and changes in microplankton assemblage composition within the T-OAE indicates dysoxic, but probably never anoxic, bottom-water conditions during this event. The onset of the CIE coincides with extinction in the nannofossils and benthos, including the disappearance of the ostracod suborder Metacopina. Faunal evidence indicates connectivity with the Mediterranean region, not previously recorded for the United Kingdom during the early Toarcian.Supplementary material at https://doi.org/10.25500/edata.bham.00000574