scholarly journals Trends and Composition—A Sedimentological-Chemical-Mineralogical Approach to Constrain the Origin of Quaternary Deposits and Landforms—From a Review to a Manual

Geosciences ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 24
Author(s):  
Harald G. Dill
Keyword(s):  
Clay Minerals ◽  
Field Studies ◽  
Environmental Geology ◽  
Chemical Compositions ◽  
Sedimentary Deposits ◽  
Coastal Marine ◽  
Clastic Sediments ◽  
Open Sea ◽  
Reef Islands ◽  
Clastic Sedimentary

In this study, six basic Quaternary landform series (LFS) and their sedimentary deposits (LFS1 aeolian, LFS 2.1 to 2.2 mass wasting, LFS 3 cryogenic-glacial, LFS 4.1 to 4.6 fluvial, LFS 5.1 to 5.2 coastal-marine, LFS 6.1 to 6.3 lacustrine) are subdivided into subtypes and examined with regard to their sedimentological parameters and their mineralogical and chemical compositions. Emphasis is placed on the textural (related to transport and deposition), compositional (sediment load/weight, Eh and pH) and geodynamic maturity of the sedimentary deposits which are influenced by the parent lithology and bedrock tectonic and by the climate during the last 2 Ma. To constrain the development of the LFS and their sediments, composite trend-line diagrams are designed combining sedimentological (x-axis) and chemical/mineralogical dataset (y-axis): (1) sorting vs. heavy mineral content; (2) sphericity of grains vs. silica/carbonate contents; and (3) median vs. Ti/Fe ratios. In addition, the x-y plots showing the log SiO2/Al2O3 vs. log Na2O/K2O are amended by a dataset of the three most common clay minerals, i.e., kaolinite-, mica-, and smectite-group clay minerals. Such joint sedimentological-chemical-mineralogical investigations focused on the depositional environment of unconsolidated clastic sediments of Quaternary age can be used to describe the economic geology and environmental geology of mineral deposits in the pre-Quaternary sedimentary series according to the phrase: “The Present is the key to the Past”. Both trend diagrams and compositional x-y plots can contribute to constraining the development of the full transect of landform series from the fluvial incision and slope retreat to reef islands fringing the coastal zone towards the open sea as far as they are built up of clastic sedimentary deposits enriched in siliceous and/or carbonate minerals. Climate zonation and crustal maturity are the exogenous and endogenous “drivers”, as can be deduced from the compositional (mineralogy and chemistry) and physical (transport and deposition) variations observed in the Quaternary sediments. The current study bridges the gap between a review only based on literature and a hybrid manual generated by practical field studies devoted to applied geosciences in economic and environmental geology (“E & E issue”).

Synthesis of nontronite and other Fe-rich smectites: a critical review

Clay Minerals ◽  
2017 ◽  
Vol 52 (4) ◽  
pp. 469-483 ◽  
Author(s):  
S. Petit ◽  
F. Baron ◽  
A. Decarreau
Keyword(s):  
Clay Minerals ◽  
Critical Review ◽  
Present Review ◽  
Chemical Compositions ◽  
Natural Environments ◽  
The Past

AbstractThe synthesis of clay minerals has been studied for decades in an attempt to better understand their formation in natural environments and more recently to obtain clay minerals with controlled compositions and properties. Even though nontronite has been synthesized successfully since 1935, the process is not a straightforward and has been poorly documented. In the present review concerning the synthesis of nontronite and other Fe-rich smectites, the experiments attempted in the past are discussed critically in light of the most recent data. Most notably, the application of relationships established recently, thanks to synthetic smectitic series, have allowed us to refine the chemical compositions of some nontronites synthesized previously.

scholarly journals Field test of available methods to measure remotely SO<sub>x</sub> and NO<sub>x</sub> emissions from ships

2014 ◽  
Vol 7 (8) ◽  
pp. 2597-2613 ◽  
Author(s):  
J. M. Balzani Lööv ◽  
B. Alfoldy ◽  
L. F. L. Gast ◽  
J. Hjorth ◽  
F. Lagler ◽  
...  
Keyword(s):  
Field Studies ◽  
Emission Factors ◽  
Sulphur Content ◽  
Nox Emission ◽  
Optical Methods ◽  
Optical Absorption Spectroscopy ◽  
Open Sea ◽  
Remote Measurements ◽  
Convenient Technique

Abstract. Methods for the determination of ship fuel sulphur content and NOx emission factors based on remote measurements have been compared in the harbour of Rotterdam and compared to direct stack emission measurements on the ferry Stena Hollandica. The methods were selected based on a review of the available literature on ship emission measurements. They were either optical (LIDAR, Differential Optical Absorption Spectroscopy (DOAS), UV camera), combined with model-based estimates of fuel consumption, or based on the so called "sniffer" principle, where SO2 or NOx emission factors are determined from simultaneous measurement of the increase of CO2 and SO2 or NOx concentrations in the plume of the ship compared to the background. The measurements were performed from stations at land, from a boat and from a helicopter. Mobile measurement platforms were found to have important advantages compared to the land-based ones because they allow optimizing the sampling conditions and sampling from ships on the open sea. Although optical methods can provide reliable results it was found that at the state of the art level, the "sniffer" approach is the most convenient technique for determining both SO2 and NOx emission factors remotely. The average random error on the determination of SO2 emission factors comparing two identical instrumental set-ups was 6%. However, it was found that apparently minor differences in the instrumental characteristics, such as response time, could cause significant differences between the emission factors determined. Direct stack measurements showed that about 14% of the fuel sulphur content was not emitted as SO2. This was supported by the remote measurements and is in agreement with the results of other field studies.

Rifting in SW China: structural and sedimentary investigation of the initial crustal response to emplacement of the Permian Emeishan LIP

2018 ◽  
Vol 156 (4) ◽  
pp. 745-758 ◽  
Author(s):  
YU WANG ◽  
INGRID UKSTINS PEATE ◽  
ZHAOHUA LUO ◽  
SHUZHI WANG ◽  
LILU CHENG ◽  
...  
Keyword(s):  
Near Field ◽  
Flood Basalt ◽  
Large Igneous Province ◽  
Normal Faults ◽  
Rift System ◽  
Main Stage ◽  
Plate Motions ◽  
Sedimentary Deposits ◽  
Icp Ms ◽  
Clastic Sedimentary

AbstractDetailed structural, volcanic, and sedimentary investigations of the crustal response to the emplacement of the Middle–Late Permian Emeishan large igneous province show that a rifting system developed prior to the main stage of flood basalt eruptions, in the form of sedimentary breccias, clastic sedimentary deposits and mafic hydromagmatic units. Detrital zircon grains from sandstones yield ~750–800 Ma LA-ICP-MS 206Pb/238U age clusters, showing that material was sourced from the Yangtze crystalline basement. Gabbros and pegmatites intruded along the normal faults of the rift system yield zircon ages of 264–260 Ma, and thus constrain the timing of rifting. N–S-trending rift zones developed along the western flank of the Pan-Xi palaeo-uplift, with NE–SW- and NNE–SSW-trending rifts on the eastern side and along the western and eastern margins of the Yangtze Block. The rifting progressed in pulses, with an initial phase of normal faulting followed by rapid deposition of breccias. Later there was lower-energy deposition of sandstone, with accompanying rhyolitic eruptions. This was followed by low-energy sedimentation of mudstones and dolomites, with accompanying hydromagmatic deposits. Rift system formation was constrained by a combination of far- and near-field tectonic stresses due to plate motions and lithospheric interaction with initial Emeishan volcanism.

scholarly journals Identification of interstratified mica and pyrophyllite monolayers within chlorite using advanced scanning/transmission electron microscopy

2019 ◽  
Vol 104 (10) ◽  
pp. 1436-1443
Author(s):  
Guanyu Wang ◽  
Hejing Wang ◽  
Jianguo Wen
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Electron Beam ◽  
Clay Minerals ◽  
Scanning Transmission Electron Microscopy ◽  
Dark Field ◽  
Chemical Compositions ◽  
Scanning Transmission Electron ◽  
Transmission Electron ◽  
Scanning Transmission

Abstract Interstratified clay minerals reflect the weathering degree and record climatic conditions and the pedogenic processes in the soil. It is hard to distinguish a few layers of interstratified clay minerals from the chlorite matrix, due to their similar two-dimensional tetrahedral-octahedral-tetrahedral (TOT) structure and electron-beam sensitive nature during transmission electron microscopy (TEM) imaging. Here, we used multiple advanced TEM techniques including low-dose high-resolution TEM (HRTEM), high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) imaging combined with energy-dispersive spectroscopic (EDS) mapping to study interstratified layers in a chlo-rite sample from Changping, Beijing, China. We demonstrated an interstratified mica or pyrophyllite monolayer could be well distinguished from the chlorite matrix by projected atomic structures, lattice spacings, and chemical compositions with advanced TEM techniques. Further investigation showed two different transformation mechanisms from mica or pyrophyllite to chlorite: either a 4 Å increase or decrease in the lattice spacing. This characterization approach can be extended to the studies of other electron-beam sensitive minerals.

Clay minerals in hydrothermally altered basalts from Middle Atlas, Morocco

Clay Minerals ◽  
2005 ◽  
Vol 40 (1) ◽  
pp. 67-77 ◽  
Author(s):  
A. Dekayir ◽  
M. Amouric ◽  
J. Olives
Keyword(s):  
Electron Microscopy ◽  
Clay Minerals ◽  
Crystallization Process ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
Equilibrium Conditions ◽  
Transmission Electron ◽  
Middle Atlas ◽  
Higher Temperature ◽  
Main Components

AbstractClay minerals occur as replacements of olivine, pyroxenes, plagioclase and interstitial materials, and as vesicle fillings, in altered basalts from the Middle Atlas (Morocco). Phyllosilicates are the main components of this alteration process. They have been characterized here by optical microscopy, X-ray diffraction, scanning electron microscopy and high-resolution transmission electron microscopy as saponite, talc, corrensite and chlorite. The homogeneity of the chemical compositions of these phyllosilicates, in different alteration environments, probably means that they are controlled by the composition of the hydrothermal fluid. Talc-saponite-corrensite (with dominant saponite) is the clay mineral association most frequently observed (corrensite being more abundant in the vesicular levels of the basalts). Such an association, with no evidence of albite and zeolite, suggests that these basalts have suffered minimal alteration at relatively low temperatures. Another association, chlorite-corrensite, was detected in a deeper (vesicular) sample, probably resulting from a slightly higher temperature. Lastly, only discrete phyllosilicates (i.e. no random mixed-layer minerals) were observed. This suggests that near-equilibrium conditions prevailed during this alteration stage and that a dissolution-crystallization process was the main mechanism of transformation.

scholarly journals The first X-ray diffraction measurements on Mars

IUCrJ ◽  
2014 ◽  
Vol 1 (6) ◽  
pp. 514-522 ◽  
Author(s):  
David Bish ◽  
David Blake ◽  
David Vaniman ◽  
Philippe Sarrazin ◽  
Thomas Bristow ◽  
...  
Keyword(s):  
Field Studies ◽  
Central Peak ◽  
Chemical Compositions ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cell Parameters ◽  
Gale Crater ◽  
Quantitative Mineralogy ◽  
Transmission Geometry ◽  
Two Samples

The Mars Science Laboratory landed in Gale crater on Mars in August 2012, and the Curiosity rover then began field studies on its drive toward Mount Sharp, a central peak made of ancient sediments. CheMin is one of ten instruments on or inside the rover, all designed to provide detailed information on the rocks, soils and atmosphere in this region. CheMin is a miniaturized X-ray diffraction/X-ray fluorescence (XRD/XRF) instrument that uses transmission geometry with an energy-discriminating CCD detector. CheMin uses onboard standards for XRD and XRF calibration, and beryl:quartz mixtures constitute the primary XRD standards. Four samples have been analysed by CheMin, namely a soil sample, two samples drilled from mudstones and a sample drilled from a sandstone. Rietveld and full-pattern analysis of the XRD data reveal a complex mineralogy, with contributions from parent igneous rocks, amorphous components and several minerals relating to aqueous alteration. In particular, the mudstone samples all contain one or more phyllosilicates consistent with alteration in liquid water. In addition to quantitative mineralogy, Rietveld refinements also provide unit-cell parameters for the major phases, which can be used to infer the chemical compositions of individual minerals and, by difference, the composition of the amorphous component.

scholarly journals Map of fossil resins of Ukraine

2020 ◽  
pp. 13-17
Author(s):  
U. Z. Naumenko ◽  
V. M. Matsui
Keyword(s):  
Marine Environment ◽  
Deep Water ◽  
Raw Materials ◽  
Middle Eocene ◽  
Scientific Research ◽  
Ukrainian Shield ◽  
Sedimentary Deposits ◽  
Coastal Marine ◽  
Geological Past ◽  
Fossil Resins

Finding out the conditions of the geological past under which tar secretions were fossilised and primary bio-sedimentary deposits of protoamber were accumulated and amber-succinite placers formed in the marine environment is an important link in scientific research. Insufficient study of amber-succinite as an organic formation, which has gone through a difficult path of transition from wildlife to minerals, leads to irrational use and search for such valuable raw materials and its extraction is much less beneficial than planned. The authors have carried out a comprehensive systematization of accumulated knowledge on amber-succinite and other mineral types of mineral resins in Ukraine and the entire Baltic-Dnipro amber province. The article discusses the creation of a new map of mineral fossil resins in Ukraine. In addition to the known amber-bearing zones, deposits and occurrences of amber, the map carriespaleogeological and predicted loads, is closely related to the formation of both secondary placers of amber-succinite and primary biogenic-sedimentary deposits – resin bodies, transitional composition in the first half of the Middle Eocene (Buchakian time). In order to develop a reasonable forecast of the deposits, the authors identified the root source of amber-succinite placers, which is represented by biogenic-sedimentary deposits of resin bodies.  These deposits were formed in the Lower Middle Eocene during the Buchakian time on land of the Ukrainian Shield, most often within swampy accumulative depressions associated with ancient faults and structural tectonic traps. The conditions of the geological past, under which tar secretions were fossilized and primary biogenic-sedimentary deposits of the protoamber were accumulated, as well as the formation of amber-succinite placers, the first intermediate collectors in the coastal-marine, liman delta and deep-water parts of the paleoshelf, have been clarified. The work carried out by the authors resulted in predicted conclusions about the possibility of finding new areas promising for the discovery of industrial deposits of the most valuable type of fossil resins – amber succinite.

scholarly journals GEOLOGICAL AND GEOGRAPHICAL FEATURES OF FORMATION, SEARCH AND PROGNOSIS OF UKRAINIAN AMBER-SUCCINITE

2020 ◽  
pp. 03-10
Author(s):  
V.M. Matsui ◽  
◽  
U.Z. Naumenko ◽  
Keyword(s):  
Late Eocene ◽  
Late Oligocene ◽  
Negative Consequences ◽  
Living Matter ◽  
Sedimentary Deposits ◽  
Early Oligocene ◽  
Geological Processes ◽  
Coastal Marine ◽  
The Baltic ◽  
Vegetation Characteristic

The purpose of this study is to determine the geological and geographical features of the transformation of resin secretions of conifers during the transition from living matter to inanimate (mineral) in the process of several stages of fossilization; formation of succinite-amber placers, as well as substantiation of prognosis assessment of prospects for discovery of new deposits and amber manifestations in the context of their ecologically safe and ecologically expedient extraction. The natural-geographical paleocomplexes of the south-eastern part of the Baltic-Dnieper amber-bearing province in the Eocene-Oligocene are characterized, which caused the accumulation of primary biogenic-sedimentary deposits of resin secretions (proto-amber) and conditions of formation of weeds of different ages. These placers are divided by genesis into indigenous, coastal, marine and estuarine delta and delta of the first intermediate reservoirs, formed in the post-Buchach period - late Middle - Late Eocene and early Oligocene and continental polygenetic placers due to in the late Oligocene, Neogene and Anthropogenic. It has been established that the root source of succinite amber in Ukraine was biogenic sedimentary deposits of resin secretions of vegetation characteristic of the central part of modern Ukraine, while in foreign literature it is believed that the main source of Ukrainian amber is its transfer from Scandinavia by coastal banks or river streams and glaciers from the Baltics. The substantiation of the prognosis of new industrial deposits of amber-succinite discovery in Ukraine is stated. Attention is paid to the problem of development of valuable gem deposits - illegal amber mining, the negative consequences of which are considered as manifestations of natural geological processes.

scholarly journals Oregano (Origanum vulgar subsp. viride) Essential Oil: Extraction, Preparation, Characterization, and Encapsulation by Chitosan-Carbomer Nanoparticles for Biomedical Application

2021 ◽  
Vol In Press (In Press) ◽  
Author(s):  
Mona Sharififard ◽  
Maryam Kouchak ◽  
Ismaeil Alizadeh ◽  
Elham Jahanifard
Keyword(s):  
Biomedical Application ◽  
Chitosan Nanoparticles ◽  
Field Studies ◽  
Gas Chromatography Mass Spectrometry ◽  
Chemical Compositions ◽  
Ionic Gelation ◽  
Plant Essential Oils ◽  
Natural Agents ◽  
The Stability ◽  
Average Size

Background: Plant essential oils (EOs) as natural agents have broad activity, including antibacterial, antifungal, antiviral, insecticidal, and repellency activities because of their chemical compositions. Objectives: The objective of this study was to increase the stability of Origanum vulgar subsp. viride EOs by encapsulation in chitosan-carbomer nanoparticles by ionic gelation method. Methods: The EOs from dried leaves of O. vulgar subsp. Viride were extracted by hydro-distillation method, and EO components were determined by gas chromatography-mass spectrometry (GC-MS). Besides, OEO-loaded chitosan (CS) nano-capsules were prepared using the ionic gelation method. The molecular structure and morphology of nanoparticles were characterized by Fourier Transform-Infrared (FTIR) and scanning electron microscopy (SEM), respectively. The encapsulation efficiency (EE), loading capacity (LC) of the OEO-loaded CS nanoparticles, and their release profiles were determined using UV/Vis spectrophotometry. Results: The major components of OEO were thymol (20.53%), 4-terpinenol (20.28%), and γ-terpinene (12.22%). The percentages of EE and LC of OEO ranged from 99.25 ± 0.74 to 93.84 ± 0.71 and 38.02 ± 0.18 to 66.73 ± 0.51, respectively, with increasing the OEO to chitosan ratio from 1:0.0.01 to 1:0.0.04 W/V. The nanoparticles were regular, uniform, and spherical in shape with an average size of 134 to 181 nm, which were dispersed throughout the solution. The zeta potential values for blank chitosan nanoparticles (CSNPs) and OEO-loaded CSNPs were +23.4 and +38.5 mV, respectively. Conclusions: The results confirmed the suitability of the CS-carbomer complex for OEO- CSNPs formation. It is recommended to evaluate the antimicrobial activity of developed OEO nanoparticles in laboratory and field studies.

scholarly journals Mineralogy and deformation structures in components of clastic sediments from the Morasko meteorite lake (Poland)

2018 ◽  
Vol 15 (1) ◽  
pp. 91-100 ◽  
Author(s):  
Agata Duczmal-Czernikiewicz ◽  
Adam Choiński ◽  
Mariusz Ptak ◽  
Andrzej Muszyński
Keyword(s):  
Clay Minerals ◽  
Nature Reserve ◽  
Fine Fraction ◽  
Dynamic Factor ◽  
Mineralogical Analysis ◽  
Soft Sediments ◽  
Deformation Structures ◽  
Clastic Sediments ◽  
Main Components ◽  
The Impact

Abstract The paper presents a mineralogical analysis of sediments of the biggest lake in the Morasko Meteorite Reserve (Poland). The lake is filled by phytogenic sediments at the top, while at the bottom there are Neogene clays. The main components are: clay minerals in fine fraction and quartz and feldspars in coarse sandy fractions. The presence of disturbed ferrous zones suggests the existence of a dynamic factor that caused deformations in the sediments. Cavities, crevices, cracks, and traces of parching or fragmentation of mineral material can be interpreted as deformations related to the impact of meteorite fragments in non-consolidated soft sediments in the Morasko meteorite nature reserve. Meteorite fragments that left numerous deformed structures were most probably consituted meteorite debris that originated from the fragmentation of the meteorite before its impact.

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