Влияние ионной подсистемы на термоэлектрический эффект в коллоидных растворах

The thermoelectric effect is investigated in mixtures of colloidal solutions with ionic electrolytes in the initial state, when the formation of concentration gradients under the influence of an inhomogeneous temperature field can be neglected. Based on experimental measurements in mixtures with different concentrations of colloidal particles and ions, the conditions under with the coefficient of thermoelectric EMF is determined by the ion subsystem and under which the main contribution to the value of the thermoelectric force is made by colloidal particles are determined.

Development of unsteady boundary layers on the generatrices of a vertical silicon rod heated by electric current in the mode of conjugate radiation-convective heat transfer

The nonstationary conjugate radiation-convective heat transfer of a single silicon rod heated by an electric current with the surrounding gas medium is studied numerically in the axisymmetric formulation by the finite element method. The calculations were carried out at the Prandtl number Pr = 0.68, and the range of the Grashof number, determined by the temperature difference and the radius of the rod 9 703 ≤ Gr ≤ 261 977. It is shown that after a short incubation period, a circulation flow is formed. As a result, a significantly inhomogeneous temperature field in the longitudinal direction is formed in a silicon rod heated by an electric current. As the Grashof number increases, the inhomogeneity of the longitudinal distribution of the temperature field increases.

Stability of a nonlinear thermoelastic plate

The problem of loss of stability of a circular plate under lateral compression in an inhomogeneous temperature field is considered. The theory of superposition of a small deformation on a finite one is used. A similar approach to the study of the equilibrium bifurcation of nonlinear thermoelastic bodies was used in the following works.

Identification of Inhomogeneous Temperature on Stainless Steel using Statistical Analysis

Corrosion in stainless steel, abbreviated as SS, is still an exciting topic to study. Even though SS is a corrosion resistance material, this property will be degraded when exposed to high temperatures for a long time because of σ phase, such as a Fe-Cr compound, formation. The presence of this phase can be observed using a special chemical etchant solution that will give five specific colours to this phase: light brown, dark brown, bluish brown, light blue, and dark blue. In this study, the specimen sample is from ASTM A297. Furthermore, the metallography process is carried out to obtain microstructure images that describe the σ phase. Here, two grains were taken as objects to discretize with one of them was around the specimen sample center and the other was close to the boundary with the environment. The discretization resulted in a 2 x 5 frequency table, called contingency table, that is analysed by the independence χ2-test. The contingency table is also represented geometrically in cartesian. The study shows that two grains were not independent. The grain which was around the specimen sample center contained many σ phases dominated by light blue colour (43%). In other words, the prolonged heating did not give homogeneous corrosion level.

Towards Measuring the Maxwell–Boltzmann Distribution of a Single Heated Particle

The Maxwell–Boltzmann distribution is a hallmark of statistical physics in thermodynamic equilibrium linking the probability density of a particle’s kinetic energies to the temperature of the system that also determines its configurational fluctuations. This unique relation is lost for Hot Brownian Motion, e.g., when the Brownian particle is constantly heated to create an inhomogeneous temperature in the surrounding liquid. While the fluctuations of the particle in this case can be described with an effective temperature, it is not unique for all degrees of freedom and suggested to be different at different timescales. In this work, we report on our progress to measure the effective temperature of Hot Brownian Motion in the ballistic regime. We have constructed an optical setup to measure the displacement of a heated Brownian particle with a temporal resolution of 10 ns giving a corresponding spatial resolution of about 23 pm for a 0.92 μm PMMA particle in water. Using a gold-coated polystyrene (AuPS) particle of 2.15 μm diameter we determine the mean squared displacement of the particle over more than six orders of magnitude in time. Our data recovers the trends for the effective temperature at long timescales, yet shows also clear effects in the region of hydrodynamic long time tails.

STABILITY OF A VISCOUS INCOMPRESSIBLE CONDUCTING LIQUID LAYER OF A CYLINDRICAL SHAPE IN AN INHOMOGENEOUS TEMPERATURE FIELD AND A MAGNETIC FIELD OF A VACUUM ARC CURRENT THROUGH IT

Convective mass transfer in a cylindrical viscous incompressible conductive fluid layer in an inhomogeneous temperature field and in the external magnetic field of the vacuum arc current through it is theoretically investigated in this work. For a horizontal layer of a viscous, incompressible, conducting liquid of a cylindrical shape, located in a temperature field inhomogeneous in height and in an external magnetic field of a vacuum arc current flowing through it, the original equations are written. These equations consist of linearized equations for small velocity perturbations, small deviations from the equilibrium values of temperature, pressure, and magnetic field strength. The considered boundary value problem is solved for the case of free boundaries. Comparison of the experimental data with theoretical calculations made it possible to determine the rotation velocity of the steel melt during vacuum arc melting.

Influence of packing density and fillers on thermal conductivity of polymer powders for additive manufacturing

Additive manufacturing of polymer powders is nowadays an industrial production technology. Complex thermal phenomena occur during processing, mainly related to the interaction dynamics among laser, powder, and heating system, and also to the subsequent cool-down phase from the melt to the parts. Thermal conductivity of the powder is a key property for material processing, since an inhomogeneous temperature field in the powder cake leads to uneven part properties and can strongly limit productivity because only a smaller portion of the build chamber can be used. Nevertheless, little is known about the relationship between thermal conductivity, packing density, and presence of fillers, which are used to enhance specific properties such as high temperature resistance or stiffness. The development and consequent validation of a device capable of measuring thermal conductivity as a function of powder packing density are then extremely important, providing an additional tool to characterize powders during the development process of new materials for PBF of polymers. The results showed a positive correlation between packing density and thermal conductivity for some commercially available materials, with an increase of the latter of about 10 to 40% with an increase of the packing density from 0 to 100%. Problems arose in trying to replicate the compaction state of the powder, since the same amount of taps led to a different packing density, but this is a known problem of measuring free-flowing powders such as the ones used for additive manufacturing. Regarding fillers, an increase of about 40 to 70% of thermal conductivity when inorganic fillers such as carbon fibers are added to the neat polymer was observed, and the expected behavior following the rule of mixture was only partially observed.

Influence of conformations of flexible-chain polymers on changes in polarization in an inhomogeneous temperature field

Due to the widespread use of polyethylene oxide (PEO) in modern technologies, studies of the relationship between its supramolecular structure and properties by means of modeling methods have recently intensified, but usually the conformational features of the structure of polymers are not taken into account in modeling. Using the example of PEO, the article substantiates a method for calculating the influence of the conformations of a polymer molecule on the temperature dependence of the averaged square of the dipole moment of its molecules.