Effects of Repeated Heating on Fatty Acid Composition of Plant-Based Cooking Oils

Several polyunsaturated fatty acids are considered to have beneficial health effects, while saturated fatty acids and industrial trans fatty acids (TFAs) are linked to negative health consequences. Given the increased formation of TFAs during heating, many studies already investigated compositional changes in oils after prolonged heating or at extremely high temperatures. In contrast, our aim was to measure changes in fatty acid composition and in some health-related indices in edible oils after short-time heating that resembles the conventional household use. Potatoes were fried in palm, rapeseed, soybean, sunflower and extra virgin olive oils at 180 °C for 5 min, and samples were collected from fresh oils and after 1, 5 and 10 consecutive heating sequences. Regardless of the type of oil, the highest linoleic acid and alpha-linolenic acid values were measured in the fresh samples, whereas significantly lower values were detected in almost all samples following the heating sequences. In contrast, the lowest levels of TFAs were detected in the fresh oils, while their values significantly increased in almost all samples during heating. Indices of atherogenicity and thrombogenicity were also significantly higher in these oils after heating. The present data indicate that prolonged or repeated heating of vegetable oils should be avoided; however, the type of oil has a greater effect on the changes of health-related indices than the number of heating sequences.

Prolonged Thermal Relaxation of the Thermosetting Polymers

The rigidity of structures made of polymer composite materials, operated at elevated temperatures, is mainly determined by the residual rigidity of the polymer binder (which is very sensitive to elevated temperatures); therefore, the study of ways to increase the rigidity of polymer materials under heating (including prolonged heating) is relevant. In the previous research, cured thermosetting polymer structure’s non-stability, especially under heating, is determined by its supra-molecular structure domain’s conglomerate character and the high entropy of such structures. The polymer elasticity modeling proved the significance of the entropy factor and layer (EPL) model application. The prolonged heating makes it possible to release adsorptive inter-layer bonds and volatile groups. As a result, the polymer structure is changing, and inner stress relaxation occurs due to this thermo-process, called thermo-relaxation. The present study suggests researching thermo-relaxation’s influence on polymers’ deformability under load and heating. The research results prove the significant polymer structure modification due to thermo-relaxation, with the polymer entropy parameter decreasing, the glassing onset temperature point (Tg) increasing by 1.3–1.7 times, and the modulus of elasticity under heating increasing by 1.5–2 times.

Identification of Inhomogeneous Temperature on Stainless Steel using Statistical Analysis

Corrosion in stainless steel, abbreviated as SS, is still an exciting topic to study. Even though SS is a corrosion resistance material, this property will be degraded when exposed to high temperatures for a long time because of σ phase, such as a Fe-Cr compound, formation. The presence of this phase can be observed using a special chemical etchant solution that will give five specific colours to this phase: light brown, dark brown, bluish brown, light blue, and dark blue. In this study, the specimen sample is from ASTM A297. Furthermore, the metallography process is carried out to obtain microstructure images that describe the σ phase. Here, two grains were taken as objects to discretize with one of them was around the specimen sample center and the other was close to the boundary with the environment. The discretization resulted in a 2 x 5 frequency table, called contingency table, that is analysed by the independence χ2-test. The contingency table is also represented geometrically in cartesian. The study shows that two grains were not independent. The grain which was around the specimen sample center contained many σ phases dominated by light blue colour (43%). In other words, the prolonged heating did not give homogeneous corrosion level.

Laser-TIG welding of galvanized steel – numerical and experimental assessment of the effect of arc in various setups

The technology of laser-TIG welding utilizes the arc as a secondary heat source during laser welding. In TIG-leading configuration, the low-current arc precedes the beam to preheat the material. The numerical simulations representing various setups combining laser and arc were performed to study the changes of thermal cycles on the interface of thin metal sheets of overlap joint. The relations between the position of the arc towards the beam, additional heat input, and temperature gradients are discussed. The technology of laser-TIG welding of zinc-coated deep-drawing steel was experimentally applied in the same joint configuration. A good agreement between the calculated and experimental welds was achieved. The arc current less than 40 A did not cause the vaporization, neither oxidation of zinc coating on the interface surface of metal sheets. Nevertheless, the quality of laser-TIG welds was better compared to laser welds. The 40A arc current increased the heat input by about 50% and led to an almost 60% decrease in cooling rate compared to autonomous laser welding. Prolonged heating and cooling time are the key factors of improving the weld quality.

Performance enhancement of a baffle-type solar heat collector through CFD simulation study

The application of solar energy conversion has been extensively utilized as an alternative energy source to generate heat. This approach would be a step towards sustainable energy development particularly in the manufacturing industry with energy-intensive process. In this paper, thermal enhancement on the key component of a solar energy device – solar heat collector (SHC), has been evaluated by proposing a baffle-type SHC with various geometric configuration in the air passage namely longitudinal baffle and transversal baffle. The performance of SHC is evaluated in term of efficiency, temperature distribution, airflow pattern and pressure drop across the collector outlet through Computational Fluid Dynamic (CFD) investigation. It was observed that maximum collector efficiency was achieved in the Longitudinal-SHC (L-SHC), with a value of 46.2 % followed by Transversal-SHC (T-SHC) and without baffles. Maximum drying temperature at the collector outlet was 332.43 K for L-SHC, showing temperature rise of 0.35 % and 4.21 % from T-SHC and without baffles, respectively. The velocity vector indicated that turbulence flow was created in the T-SHC which consequently improved the heat transfer. Whereas in L-SHC, enhancement was achieved through the prolonged heating time in the passage. Considering the thermo-hydraulic performance factor evaluated, these enhancement features had diminished the effect of pressure drop.

Features of the synthesis of highly dispersed alumophosphates AlPO4·nH2O

Aluminum orthophosphate of the composition AlPO4·2H2O with a monoclinic structure identical to the structure of the natural mineral metavariscite was obtained by condensation method during hydrothermal treatment of alumophosphate solutions with a concentration (g/l) of Al2O3 90 – 115, P2O5 340 – 440 in the temperature range 95–99 °C. For the first time, the role of aging of the alumophosphate system in shortening of the induction period, simultaneous nucleation of primary particles in the entire volume of the solution and the formation of a pasty product with a predominant particle size of 1–10 μm, in contrast to 30–50 μm, characteristic of a fine-crystalline product obtained without aging of the solution, is established. It is shown that pasty AlPO4·2H2O, in comparison with fine-crystalline, is hardly soluble in HCl even under prolonged heating. The influence of P2O5 content in the alumophosphate solution, the conditions of its aging and the duration of hydrothermal treatment on the particle size distribution for synthesized aluminum orthophosphates have been established. Anhydrous alumophosphate obtained by dehydration of pasty AlPO4·2H2O in the temperature range of 150–200 °C with subsequent heat treatment at 900 °C is readily soluble in acids, and the predominant particle size is 5–13 μm.

Induction Brazing for Rapid Localized Repair of Inconel 718

Vacuum furnace has been used for brazing repair of aerospace components, but it is a slow process which typically takes a few hours. The prolonged heating and cooling cycles could cause some adverse effects on the components such as excessive grain growth. A rapid brazing technique using induction coil was studied to evaluate its suitability for localized repair. Induction brazing of Inconel 718 was carried out using AMS 4777 brazing paste at different temperatures (950 °C, 1050 °C and 1150 °C ) for various durations (2 min, 10 min and 20 min). Microstructure and microhardness were evaluated. The experimental results show that brazing at 1050 °C leads to desirable microstructures in a short period of merely 2 min. The study demonstrates the potential application of induction brazing for rapid localized aerospace repair.

Emulating Full Load Testing of Air-cooled Nanocrystalline IHT at Zero Power

High-power high-frequency air-cooled induction heating transformers, mostly used as current multiplier and isolation purposes, are custom designed. For their reliable performance and long life, the thermal evaluation at rated load is necessary. Creating an equivalent load as test facility for reliability testing of such type of transformer is difficult. Characteristics of such loads drastically change after Curie temperature. Moreover, prolonged heating could increase the nearby ambient temperature and, more importantly, the traditional heat run test wastes large amount of energy. Whenever the coil is energized, windings of transformer draw respective rated current; even at no load condition the copper loss is at rated value. While both windings drawing rated current at desired frequency, using the concept of localized eddy current loss as well as excess eddy current loss, this article proposes a novel method to inject requisite core loss to the magnetic circuit to emulate the characteristics of full load condition but the power drawn from the transformer would be zero. The proposed idea would be validated where only 200 W resonant inverter would be used to inject power loss equivalent to full-load condition of 30 kW transformer to emulate the heat run test.

Thermal stability and diffusion characteristics of ultrathin amorphous carbon films grown on crystalline and nitrogenated silicon substrates by filtered cathodic vacuum arc deposition

Amorphous carbon (a-C) films are widely used as protective overcoats in many technology sectors, principally due to their excellent thermophysical properties and chemical inertness. The growth and thermal stability of sub-5-nm-thick a-C films synthesized by filtered cathodic vacuum arc on pure (crystalline) and nitrogenated (amorphous) silicon substrate surfaces were investigated in this study. Samples of a-C/Si and a-C/SiNx/Si stacks were thermally annealed for various durations and subsequently characterized by high-resolution transmission electron microscopy (TEM) and electron energy loss spectroscopy (EELS). The TEM images confirmed the continuity and uniformity of the a-C films and the 5-nm-thick SiNx underlayer formed by silicon nitrogenation using radio-frequency sputtering. The EELS analysis of cross-sectional samples revealed the thermal stability of the a-C films and the efficacy of the SiNx underlayer to prevent carbon migration into the silicon substrate, even after prolonged heating. The obtained results provide insight into the important attributes of an underlayer in heated multilayered media for preventing elemental intermixing with the substrate, while preserving the structural stability of the a-C film at the stack surface. An important contribution of this investigation is the establishment of an experimental framework for accurately assessing the thermal stability and elemental diffusion in layered microstructures exposed to elevated temperatures.

Phosphorylation of glycoluryl derivatives with phosphorus pentachloride

The paperpresents the research results on the synthesis and study of new organophosphorus derivatives of glycoluril, obtained on the basis of pentavalent phosphorus. New organoelement phosphorus derivatives synthesized on the basis of N-acyl-substituted glycolurilhave been obtained.They are of considerable interest due to the presence of effective reaction centers. Tetraacetyl-substituted glycoluril —2,4,6,8-tetraacetyl-2,4,6,8-tetraazabicyclo[3,3,0]octane-3,7-dione was chosen as theinitial synthon. Theuse of unsubstituted glycoluril in the reaction of direct phosphorylation by the action of phosphorus trichloride or pentachloride is not possible due to the absence of active phosphorylation centers. It was experimentally shown that the reaction proceeds with prolonged heating for at least 48 hours in an argon. Theinitial acyl derivative of glycoluril and phosphorus pentachloride in theratio of 1:6 and leads to the formation of diphosphonic complex of tetraacetylglycoluril —dihexachlorophosphorate 2,6-diacetyl-(4,8-diacetyl-2,4,6,8-tetraaza-bicyclo[3.3.0]octane-3,7-dione)-2,6-di(chloroethenyltrichlorophosphonium). The obtained compoundis a white crystalline substance unstable in air. Decomposition of the diphosphonic complex was carried out using benzaldehyde and proceeds with the formation of the corresponding dichlorophosphate derivative, also unstable in air and rapidly decomposing at room temperature.