Characteristics Evolution of Multiscale Structures in Deep Coal under Liquid Nitrogen Freeze-Thaw Cycles

Liquid nitrogen freeze-thaw fracturing has attracted more and more attention in improving the coal reservoir permeability. In order to reveal the impact of liquid nitrogen freeze-thaw on the multiscale structure of deep coal, the multiscale structure evolution law of deep and shallow coal samples from the same seam in the Qinshui coalfield during the liquid nitrogen freeze-thaw cycling was investigated using NMR T 2 spectrum, NMRI, and SEM. The connectivity between mesopores and macropores in deep and shallow coal is improved after liquid nitrogen freeze-thaw cycles. The influence of liquid nitrogen freeze-thaw cycles on the structure evolution of deep and shallow coal is the formation and expansion of microscopic fractures. The initial NMR porosity of deep coal is lower than that of shallow coal from the same coalfield and coal seam. The NMR porosity of both the deep and shallow coal samples increases with the increase of the number of freeze-thaw cycles, and the NMR porosity growth rate of the deep sample is lower than that of the shallow sample.

Exploring the hidden depth by confocal Raman experiments with variable objective aperture and magnification

The article analyzes experimentally and theoretically the influence of microscope parameters on the pinhole-assisted Raman depth profiles in uniform and composite refractive media. The main objective is the reliable mapping of deep sample regions. The easiest to interpret results are found with low magnification, low aperture, and small pinholes. Here, the intensities and shapes of the Raman signals are independent of the location of the emitter relative to the sample surface. Theoretically, the results can be well described with a simple analytical equation containing the axial depth resolution of the microscope and the position of the emitter. The lower determinable object size is limited to 2–4 μm. If sub-micrometer resolution is desired, high magnification, mostly combined with high aperture, becomes necessary. The signal intensities and shapes depend now in refractive media on the position relative to the sample surface. This aspect is investigated on a number of uniform and stacked polymer layers, 2–160 μm thick, with the best available transparency. The experimental depth profiles are numerically fitted with excellent accuracy by inserting a Gaussian excitation beam of variable waist and fill fraction through the focusing lens area, and by treating the Raman emission with geometric optics as spontaneous isotropic process through the lens and the variable pinhole, respectively. The intersectional area of these two solid angles yields the leading factor in understanding confocal (pinhole-assisted) Raman depth profiles. Graphical abstract

Asymbiotic nitrogen fixation is greater in soils under long-term no-till versus conventional tillage

A series of N-rate experiments was previously conducted in spring wheat, corn and sunflower in North Dakota indicated that less N was required when fields were in 6-years or more continuous no-till compared to conventional till. The objective of this study was to determine whether part of the reason for the decreased requirement for N was the greater activity of asymbiotic N-fixing organisms. Twelve paired-samplings were conducted in 2018. A surface 0-5cm deep sample was obtained in a long-term no-till field directly across the fence/road from a similar soil in conventional till. Samples were incubated in an acetylene-reduction procedure to estimate N fixation rate. Ten of twelve paired samplings had greater asymbiotic N fixation compared to the conventional till counterpart. This indicates that long-term no-till soils support greater N production from soil microorganisms than conventional till soils, which would result in lower input costs to no-till farmers.

Host galaxy properties of radio selected AGN

With the goal of investigating the link between black hole (BH) and star formation (SF) activity, we study a deep sample of radio selected star forming galaxies (SFGs) and active galactic nuclei (AGNs). Using a multi-wavelength approach we characterize their host galaxies properties (stellar masses, optical colors, and morphology). Moreover, comparing the star formation rate derived from the radio and far-infrared luminosity, we found evidences that the main contribution to the radio emission in the radio-quiet AGNs is star-formation activity in their host galaxy.

The build-up of mass in UV-selected sub-L* Galaxies at z~2

Broadband spectral energy distribution (SED) fitting is used to study a deep sample of UV-selected sub-L* galaxies at z~2. They are found to be less dusty than L* galaxies, and to contribute more mass to the cosmic mass budget at this epoch than is inferred from shallower high-z surveys. Additionally, SFRs are found to be proportional to stellar masses over three orders of magnitude in mass; this phenomenon can be explained by assuming that new stars form out of gas that co-accretes along with dark matter onto the galaxies' dark matter halos, a scenario that naturally leads to SFRs that gradually increase with time.