Structural relaxation and crystallization in supercooled water from 170 to 260 K

The origin of water’s anomalous properties has been debated for decades. Resolution of the problem is hindered by a lack of experimental data in a crucial region of temperatures, T, and pressures where supercooled water rapidly crystallizes—a region often referred to as “no man’s land.” A recently developed technique where water is heated and cooled at rates greater than 109 K/s now enables experiments in this region. Here, it is used to investigate the structural relaxation and crystallization of deeply supercooled water for 170 K < T < 260 K. Water’s relaxation toward a new equilibrium structure depends on its initial structure with hyperquenched glassy water (HQW) typically relaxing more quickly than low-density amorphous solid water (LDA). For HQW and T > 230 K, simple exponential relaxation kinetics is observed. For HQW at lower temperatures, increasingly nonexponential relaxation is observed, which is consistent with the dynamics expected on a rough potential energy landscape. For LDA, approximately exponential relaxation is observed for T > 230 K and T < 200 K, with nonexponential relaxation only at intermediate temperatures. At all temperatures, water’s structure can be reproduced by a linear combination of two, local structural motifs, and we show that a simple model accounts for the complex kinetics within this context. The relaxation time, τrel, is always shorter than the crystallization time, τxtal. For HQW, the ratio, τxtal/τrel, goes through a minimum at ∼198 K where the ratio is about 60.

Landscape-induced spatial oscillations in population dynamics

We study the effect that disturbances in the ecological landscape exert on the spatial distribution of a population that evolves according to the nonlocal FKPP equation. Using both numerical and analytical techniques, we characterize, as a function of the interaction kernel, the three types of stationary profiles that can develop near abrupt spatial variations in the environmental conditions vital for population growth: sustained oscillations, decaying oscillations and exponential relaxation towards a flat profile. Through the mapping between the features of the induced wrinkles and the shape of the interaction kernel, we discuss how heterogeneities can reveal information that would be hidden in a flat landscape.

Analysis of Multicomponent Exponential Magnetic Resonance Relaxation Data: Automatable Parameterization and Interpretable Display Protocols

This report describes and illustrates a set of automatable multicomponent exponential relaxation analysis protocols that are model-agnostic and suited to extracting information under circumstances when little prior knowledge about the underlying system is used. Methods are illustrated and mathematical and physical underpinnings of the methods are provided.

Analysis of Multicomponent Exponential Magnetic Resonance Relaxation Data: Automatable Parameterization and Interpretable Display Protocols

This report describes and illustrates a set of automatable multicomponent exponential relaxation analysis protocols that are model-agnostic and suited to extracting information under circumstances when little prior knowledge about the underlying system is used. Methods are illustrated and mathematical and physical underpinnings of the methods are provided.

Operator thermalisation in d > 2: Huygens or resurgence

Correlation functions of most composite operators decay exponentially with time at non-zero temperature, even in free field theories. This insight was recently codified in an OTH (operator thermalisation hypothesis). We reconsider an early example, with large N free fields subjected to a singlet constraint. This study in dimensions d > 2 motivates technical modifications of the original OTH to allow for generalised free fields. Furthermore, Huygens’ principle, valid for wave equations only in even dimensions, leads to differences in thermalisation. It works straightforwardly when Huygens’ principle applies, but thermalisation is more elusive if it does not apply. Instead, in odd dimensions we find a link to resurgence theory by noting that exponential relaxation is analogous to non- perturbative corrections to an asymptotic perturbation expansion. Without applying the power of resurgence technology we still find support for thermalisation in odd dimensions, although these arguments are incomplete.