Experimental and theoretical study of the characteristics of LSPR peaks for metal NPs produced by controlling Ar ambient gas pressure to enhance the efficiency of solar cells

In this study, silver (Ag) nanoparticle thin films were deposited on microscope slide glass and Si wafer substrates using the pulsed-laser deposition (PLD) technique in Ar ambient gas pressures of 1 × 10−3 and 7.5 × 10−1 mbar. AFM analysis has shown that the number of Ag nanoparticles reaching the substrate decreased with increasing Ar gas pressure. As a result of Ar ambient gas being allowed into the vacuum chamber, it was observed that the size and height of Ag nanoparticles decreased and the interparticle distances decreased. According to the absorption spectra taken by a UV–vis spectrometer, the wavelength where the localised surface plasmon resonance (LSPR) peak appeared was shifted towards the longer wavelength region in the solar spectrum as Ar background gas pressure was decreased. This experiment shows that LSPR wavelength can be tuned by adjusting the size of metal nanoparticles, which can be controlled by changing Ar gas pressure. The obtained extinction cross section spectra for Ag nanoparticle thin film was theoretically analysed and determined by using the metal nanoparticle–boundary element method (MNPBEM) toolbox simulation program. In this study, experimental spectrum and simulation data for metal nanoparticles were acquired, compared, and determined to be in agreement.

Nuclear de-excitation lines as a probe of low-energy cosmic rays

Low-energy cosmic rays (LECRs) contribute substantially to the energy balance of the interstellar medium. They play also significant role in the heating and chemistry of gas, and, consequently, on the star formation process. Because of the slow propagation coupled with enhanced energy losses of subrelativistic particles, LECRs are concentrated around their acceleration sites. LECRs effectively interact with the ambient gas through nuclear reactions. Although these processes are energetically less effective compared to heating and ionization, they are extremely important from the point of view of nuclear de-excitation lines, which carry unique information about LECRs. We present results on production of de-excitation lines combining the numerical treatment of nuclear reactions using the code TALYS, with the propagation and energy losses of LECRs.