Triboluminescence Phenomenon Based on the Metal Complex Compounds—A Short Review

Triboluminescence (TL) is a phenomenon of light emission resulting from the mechanical force applied to a substance. Although TL has been observed for many ages, the radiation mechanism is still under investigation. One of the exemplary compounds which possesses triboluminescent properties are copper(I) thiocyanate bipyridine triphenylphosphine complex [Cu(NCS)(py)2(PPh3)], europium tetrakis dibenzoylmethide triethylammonium EuD4TEA, tris(bipyridine)ruthenium(II) chloride [Ru(bpy)3]Cl2, and bis(triphenylphosphine oxide)manganese(II) bromide Mn(Ph3PO)2Br2. Due to the effortless synthesis route and distinct photo- and triboluminescent properties, these compounds may be useful model substances for the research on the triboluminescence mechanism. The advance of TL studies may lead to the development of a new group of sensors based on force-responsive (mechanical stimuli) materials. This review constitutes a comprehensive theoretical study containing available information about the coordination of metal complex synthesis methodologies with their physical, chemical, and spectroscopic properties.

Ionic liquid immobilized Cu(I)-Hydrazone-Triphenylphosphine Complex: An Easily recyclable Catalytic System for Suzuki and Heck Cross Couplings

A highly efficient, reusable catalytic system towards Heck and Suzuki cross-coupling reactions was observed for an inexpensive copper complex dispersed in ethyl-methyl imidazolium hexafluorophosphate medium, [EMIM] PF6. The reaction conditions were optimized by studying the effects of temperature, catalyst concentration, solvent and time. The method functions for a variety of substrates towards the cross coupling reactions. Most notably, the catalyst-ionic liquid mixture was easily recoverable and reused for six times without much loss in the catalytic activity, causing significantly a very low impact on the environment.

Fluorine-Substituted Arylphosphine for an NHC-Ni(I) System, Air-Stable in a Solid State but Catalytically Active in Solution

Monovalent NHC-nickel complexes bearing triarylphosphine, in which fluorine is incorporated onto the aryl groups, have been synthesized. Tris(3,5-di(trifluoromethyl)-phenyl)phosphine efficiently gave a monovalent nickel bromide complex, whose structure was determined by X-ray diffraction analysis for the first time. In the solid state, the Ni(I) complex was less susceptible to oxidation in air than the triphenylphosphine complex, indicating greatly improved solid-state stability. In contrast, the Ni(I) complex in solution can easily liberate the phosphine, high catalytic activity toward the Kumada–Tamao–Corriu coupling of aryl bromides.