Abstract
The effect of photoelectron processes in n-Si and p-Si on the glucose sensitivity of a capacitive field-effect biosensor based on electrolyte/oxide/semiconductor structure was investigated. We obtained that illumination of n-Si/SiO2/PEI structure during the GOx adsorption increases the glucose sensitivity by three times compare to GOx adsorption in the dark. In contrast, p-Si illumination during the GOx adsorption led to a decrease in sensor sensitivity from 2.9 mV/mM to 2.2 mV/mM. The result is explained by a change in the density of immobilized GOx molecules due to a change in the electrostatic forces of attraction under illumination and stabilization of the photo-generated charge on the surface electronic states of the Si/SiO2 and SiO2/PEI interfaces after illumination.