Anodic Activity of Hydrated and Anhydrous Iron (II) Oxalate in Li-Ion Batteries

We discuss the applicability of the naturally occurring compound Ferrous Oxalate Dihydrate (FOD) (FeC2O4·2H2O) as an anode material in Li-ion batteries. Using first-principles modeling, we evaluate the electrochemical activity of FOD and demonstrate how its structural water content affects the intercalation reaction and contributes to its performance. We show that both Li0 and Li+ intercalation in FOD yields similar results. Our analysis indicates that fully dehydrated ferrous oxalate is a more promising anodic material with higher electrochemical stability: it carries 20% higher theoretical Li storage capacity and a lower voltage (0.68 V at the PBE/cc-pVDZ level), compared to its hydrated (2.29 V) or partially hydrated (1.43 V) counterparts.

Rapid AC Electrokinetic Micromixer with Electrically Conductive Sidewalls

We report a quasi T-channel electrokinetics-based micromixer with electrically conductive sidewalls, where the electric field is in the transverse direction of the flow and parallel to the conductivity gradient at the interface between two fluids to be mixed. Mixing results are first compared with another widely studied micromixer configuration, where electrodes are located at the inlet and outlet of the channel with electric field parallel to bulk flow direction but orthogonal to the conductivity gradient at the interface between the two fluids to be mixed. Faster mixing is achieved in the micromixer with conductive sidewalls. Effects of Re numbers, applied AC voltage and frequency, and conductivity ratio of the two fluids to be mixed on mixing results were investigated. The results reveal that the mixing length becomes shorter with low Re number and mixing with increased voltage and decreased frequency. Higher conductivity ratio leads to stronger mixing result. It was also found that, under low conductivity ratio, compared with the case where electrodes are located at the end of the channel, the conductive sidewalls can generate fast mixing at much lower voltage, higher frequency, and lower conductivity ratio. The study of this micromixer could broaden our understanding of electrokinetic phenomena and provide new tools for sample preparation in applications such as organ-on-a-chip where fast mixing is required.

Improvements on High Temperature Lithium Oxyhalide Primary Battery for Downhole Tools Power Applications

Commercial lithium oxyhalide batteries have a very flat voltage curve. It is challenging to determine a battery's remaining capacity during and after powering downhole drilling tools. It is wasteful and environmentally hazardous to dispose of lightly used battery packs. Through innovations in battery cell design and electrolyte formulation, laboratory cells showed multiple voltage plateaus allowing easy estimation of remaining capacity at room temperature. Prototyped DD-size batteries validated the unique feature at high temperatures. If the batteries are used in downhole drilling and measurement tools, non-productive time may be shortened, and costs reduced over time. Small coin cells were assembled in an inert argon gas filled glovebox. The assembled coin cell, lithium metal foil disk, carbon electrode, and other cell components were weighted to determine electrolyte weight accurately. Carbon black electrodes were prepared by coating carbon black paste on nickel foam substrate. After overnight air drying, coated nickel foam was hot pressed to 1 mm thickness at 230 °C. DD-size cells were prototyped at a battery vendor with selected cell configurations. Performance of coin cells and prototyped DD-size cells were measured during constant current discharge tests. Discharge voltage curves of baseline coin cells mimicking commercial battery products were flat at 3.4 until sudden voltage crash at the end of discharge. Coin cells OP-33 and OP-36, with the improved design and electrolyte formula, showed two main voltage plateaus. The higher voltage plateau was around 3.85-3.60 V, and the lower voltage plateau was around 3.50-3.40 V. The sharp voltage transition from 3.60 V to 3.50 V was easy for a user or a battery management system to detect. Capacity percentage in the higher voltage plateau and the lower voltage plateau depends on the energy active chemical compositions of electrolyte. A cell design and electrolyte formulation were selected to prototype scaled-up DD-size cells. Three repeating DD-size cells were discharged at 150 °C. The overall sloping voltage curves and the obvious voltage transition between two discharge stages around 3.5 V can greatly facilitate battery capacity estimation. As of today, there is no commercial high temperature lithium oxyhalide primary battery with such a unique feature of staged and sloping battery voltage shape for capacity estimation. Compared to capacity estimation by charge counting method utilized in some battery monitoring chips, capacity estimation based on voltage change is much simpler, more accurate, and consumes less battery energy without needs of frequent current measurement and charge calculation. Any previously lightly discharged battery pack can be easily determined whether further usage is possible for the next downhole tools power application, which saves cost and reduces battery waste.

Improved Cascaded H-Bridge Multilevel Inverters with Voltage-Boosting Capability

This paper proposes two improved cascaded H-bridge (ICHB) multilevel inverters that feature voltage-boosting capability. The conventional H-bridge with a front-end dc–dc boost converter was restructured for single-stage operation. The developed three-level topology not only saves one power switch but also exhibits lower voltage stress across its capacitor. Extension to five-level generation was also introduced by merely adding two power switches and one capacitor. The final five-level topology outperforms the classical cascaded H-bridge (CHB) multilevel inverter with a significant reduction in the power switch count, with a 42% and 50% reduction in both the isolated dc source and inductor counts. The power efficiency was also improved without compromising the modularity feature of the classical CHB multilevel inverter. The operation and theoretical analysis of the proposed topologies were validated via simulations and experimental tests.

Recent Progress on Electroactive Polymers: Synthesis, Properties and Applications

Electroactive polymers (EAPs) are an advanced family of polymers that change their shape through electric stimulation and have been a point of interest since their inception. This unique functionality has helped EAPs to contribute to versatile fields, such as electrical, biomedical, and robotics, to name a few. Ionic EAPs have a significant advantage over electronic EAPs. For example, Ionic EAPs require a lower voltage to activate than electronic EAPs. On the other hand, electronic EAPs could generate a relatively larger actuation force. Therefore, efforts have been focused on improving both kinds to achieve superior properties. In this review, the synthesis routes of different EAP-based actuators and their properties are discussed. Moreover, their mechanical interactions have been investigated from a tribological perspective as all these EAPs undergo surface interactions. Such interactions could reduce their useful life and need significant research attention for enhancing their life. Recent advancements and numerous applications of EAPs in various sectors are also discussed in this review.

Impact of Changes in a Distribution Network Nature on the Capacitive Reactive Power Flow into the Transmission Network in Slovakia

The main emphasis in the operation of an electricity system is placed on its safe and reliable operation. The flow of reactive power in a network can affect voltage conditions in individual nodes of the transmission system. In recent years, there have been changes in the network that have resulted in increased capacitive reactive power flows from lower voltage levels to higher ones. These flows can cause the voltage to rise above the limit. This paper examines recent changes in the reactive power transmission in the network, especially at lower voltage levels. The possible impact of these changes on the flow of capacitive reactive power at higher voltage levels is analyzed. This paper also presents a description and the simulated impact of power lines at different voltage levels on reactive power flows. Real measurements of different types of consumers at the low-voltage (LV) level are analyzed. Finally, a simulation model was created to simulate the impact of a customer’s power contribution to the reactive power flows from the point of view of a 110 kV voltage node. This node is characterized as a supply point.