Experimental Investigation on the Effects of Ethanol-Enhanced Steam Injection Remediation in Nitrobenzene-Contaminated Heterogeneous Aquifers

Steam injection is an effective technique for the remediation of aquifers polluted with volatile organic compounds. However, the application of steam injection technology requires a judicious selection of stratum media because the remediation effect of hot steam in heterogeneous layers with low permeability is not suitable. In this study, the removal effect of nitrobenzene in an aquifer was investigated through a series of two-dimensional sandbox experiments with different stratigraphic structures. Four types of alcohols were used during steam injection remediation to enhance the removal effect of nitrobenzene (NB)-contaminated heterogeneous aquifers. The principle of the removal mechanism of alcohol-enhanced organic compounds is that alcohols can reduce the surface tension of the contaminated water, resulting in Marangoni convection, thereby enhancing mass and heat transfer. The addition of alcohol may also reduce the azeotropic temperature of the system and enhance the volatility of organic compounds. The study revealed that all four alcohol types could reduce the surface tension from 72 mN/m to <30 mN/m. However, among these, only ethanol reduced the azeotropic temperature of NB by 15 °C, thereby reducing energy consumption and remediation costs. Therefore, ethanol was selected as an enhancing agent to reduce both surface tension and azeotropic temperature during steam injection. In the 2-D simulation tank, the interface between the low-and high-permeability strata in the layered heterogeneous aquifer had a blocking effect on steam transportation, which in turn caused a poor remediation effect in the upper low-permeability stratum. In the lens heterogeneous aquifer, steam flows around the lens, thereby weakening the remediation effect. After adding ethanol to the low-permeability zone, Marangoni convection was enhanced, which further enhanced the mass and heat transfer. In the layered and lens heterogeneous aquifers, the area affected by steam increased by 13% and 14%, respectively. Moreover, the average concentration of NB was reduced by 51% in layered heterogeneous aquifers and by 58% in low-permeability lenses by ethanol addition. These findings enhance the remediation effect of steam injection in heterogeneous porous media and contribute to improve the remediation efficiency of heterogeneous aquifers by steam injection.

Effects of passive storage on modelling hydrological function and isotope dynamics in a karst flow system in southwest China

Representing passive storage in coupled flow-isotope models can facilitate simulation of mixing and retardation effects on tracer transport in many natural systems, such as catchments or rivers. However, the effectiveness of incorporating passive storages in models of complex karst flow systems remains poorly understood. In this study, we developed a coupled flow-isotope model that conceptually represents both “fast” and “slow” flow processes in heterogeneous aquifers to represent hydrological connections between hillslopes and low-lying depression units in cockpit karst landscapes. As this model originally included a varying number of passive storages at different positions of the flow system (e.g. fast/slow flow reservoirs combined with different hillslope/depression units), the model structure and relevant parameters were optimized using a multi-objective optimization algorithm. This was used to match detailed observational data of hydrological processes and isotope concentration in the Chenqi catchment in southwest China. Results show that the optimal structure for a coupled flow-isotope model incorporated only two passive storages in fast flow and slow flow paths of the hillslope unit. Using fewer or greater numbers of passive stores in the model could lead to under- or over-mixing of isotope signatures. This optimized model structure could effectively improve simulation accuracies for outlet discharge and isotope signatures, with > 0.65 of the modified Kling-Gupta efficiency. Additionally, the optimal tracer-aided model yields reasonable parameter values and estimations of hydrological components (e.g. more than 80 % of fast flow in the total discharge). Furthermore, results imply that the solute transport is primarily controlled by advection and hydrodynamic dispersion in steep hillslope unit, which is a remarkable phenomenon in the karst flow system. The study resulted in new insights, more realistic catchment conceptualizations and improved model formulation.

Imaging the Structure and the Saltwater Intrusion Extent of the Luy River Coastal Aquifer (Binh Thuan, Vietnam) Using Electrical Resistivity Tomography

With the growing population and the adverse effects of climate change, the pressure on coastal aquifers is increasing, leading to a larger risk of saltwater intrusion (SI). SI is often complex and difficult to characterize from well data only. In this context, electrical resistivity tomography (ERT) can provide high-resolution qualitative information on the lateral and vertical distribution of salinity. However, the quantitative interpretation of ERT remains difficult because of the uncertainty of petrophysical relationships, the limitations of inversion, and the heterogeneity of aquifers. In this contribution, we propose a methodology for the semiquantitative interpretation of ERT when colocated well data are not available. We first use existing wells to identify freshwater zones and characterize the resistivity response of clayey deposits. Then, we approximate the formation factor from water samples collected in the vicinity of ERT data to derive a resistivity threshold to interpret the saline boundary. We applied the methodology in the shallow aquifers of the Luy River in the Binh Thuan province, Vietnam, where water resources are under pressure due to agricultural, aquacultural, and industrial production. Twenty-one ERT profiles were collected and revealed a much larger intrusion zone, compared to the previous study. Saltwater is present in lowland areas of the left bank over almost the whole thickness of the aquifer, while the right bank is constituted of sand dunes that are filled with freshwater. At a larger distance from the sea, a complex distribution between fresh and saltwater is observed. Our methodology could be applied to other heterogeneous aquifers in the absence of a dense monitoring network.

Evaluation of Groundwater Potential and Safe Yield of Heterogeneous Unconsolidated Aquifers in Chiang Mai Basin, Northern Thailand

Chiang Mai basin has an escalating population growth resulting in high demand for water consumption. Lack of surface water supply in most parts of the basin gives rise to the increasing use of groundwater which leads to a continuous decline in groundwater level in the past decades. This study is the first long-term groundwater monitoring and modeling study that aims at developing a transient, regional groundwater flow model of heterogeneous unconsolidated aquifers based on the MODFLOW program. Long-term groundwater monitoring data from 49 piezometers were used in model calibration and validation. The pilot points technique was used to account for the spatial variability of hydrogeologic parameters of heterogeneous aquifers. The simulation results and statistics showed that most sensitive and significant model parameters were spatially variable hydraulic conductivities and recharge rates. The Chiang Mai basin’s unconsolidated aquifers do not have high potential. The water table and/or potentiometric surface in the southeast and southwest areas of Chiang Mai city were continuously decreasing with no sign of recovery indicating critical groundwater condition and careful management must be considered. Safe yield calculation, based on a 2-m average drawdown threshold, suggested that unconsolidated aquifers of the Chiang Mai basin can sustain overall abstraction rates up to 51.2 Mm3/y or approximately 214% of the current extraction rates.