Lithium, Oxygen and Magnesium Isotope Systematics of Volcanic Rocks in the Okinawa Trough: Implications for Plate Subduction Studies

Determining the influence of subduction input on back-arc basin magmatism is important for understanding material transfer and circulation in subduction zones. Although the mantle source of Okinawa Trough (OT) magmas is widely accepted to be modified by subducted components, the role of slab-derived fluids is poorly defined. Here, major element, trace element, and Li, O and Mg isotopic compositions of volcanic lavas from the middle OT (MOT) and southern OT (SOT) were analyzed. Compared with the MOT volcanic lavas, the T9-1 basaltic andesite from the SOT exhibited positive Pb anomalies, significantly lower Nd/Pb and Ce/Pb ratios, and higher Ba/La ratios, indicating that subducted sedimentary components affected SOT magma compositions. The δ7Li, δ18O, and δ26Mg values of the SOT basaltic andesite (−5.05‰ to 4.98‰, 4.83‰ to 5.80‰ and −0.16‰ to −0.09‰, respectively) differed from those of MOT volcanic lavas. Hence, the effect of the Philippine Sea Plate subduction component, (low δ7Li and δ18O and high δ26Mg) on magmas in the SOT was clearer than that in the MOT. This contrast likely appears because the amounts of fluids and/or melts derived from altered oceanic crust (AOC, lower δ18O) and/or subducted sediment (lower δ7Li, higher δ18O and δ26Mg) injected into magmas in the SOT are larger than those in the MOT and because the injection ratio between subducted AOC and sediment is always >1 in the OT. The distance between the subducting slab and overlying magma may play a significant role in controlling the differences in subduction components injected into magmas between the MOT and SOT.

Subduction initiation of the western Proto-Tethys Ocean: New evidence from the Cambrian intra-oceanic forearc ophiolitic mélange in the western Kunlun Orogen, NW Tibetan Plateau

The supra-subduction zone ophiolite or ophiolitic mélange formed in the forearc setting is generally considered to be a key geological record for subduction initiation (SI) with petrological characteristics comparable to the SI-related rock sequence from forearc basalt (FAB) to boninite in the Izu-Bonin-Mariana subduction zone. Nevertheless, the standard FAB and boninite are generally difficult to observe in the forearc rocks generated during SI. Yet, a typical rock sequence indicating the SI of the western Proto-Tethys Ocean is reported for the first time in the Qimanyute intra-oceanic forearc system in the western Kunlun Orogen, Northwest Tibetan Plateau. The magmatic compositions, which range from less to more high field strength element (HFSE)-depleted and large ion lithophile element (LILE)-enriched, are changing from oceanic plagiogranites (ca. 494 Ma) to forearc basalt-like gabbros (FAB-Gs, ca. 487 Ma), boninites, and subsequent Nb-enriched gabbros (NEGs, ca. 485 Ma), which are thus consistent with the Izu-Bonin-Mariana forearc rocks as well as the Troodos and Semail supra-subduction zone-type ophiolites. The geochemical data from the chemostratigraphic succession indicate a subduction initiation process from a depleted mid-oceanic-ridge (MORB)-type mantle source with no detectable subduction input to gradual increasing involvement of subduction-derived materials (fluid/melts and sediments). The new petrological, geochemical, and geochronological data, combined with the regional geology, indicate that the well-sustained FAB-like intrusive magmas with associated boninites could provide crucial evidence for SI and further reveal that the SI of the western Proto-Tethys Ocean occurred in the Late Cambrian (494−485 Ma).

Zinc isotope fractionation at destructive plate margins and potential implications for the global recycling signature

<p>Our understanding regarding the behaviour of the fluid mobile element Zn at destructive plate margins is limited. In particular the fractionation mechanisms and input-output mass-balance remains to be investigated due to implications for the spatio-temporal cycling of this vital and socio-economically relevant element. In this study, we investigate the Zn isotope systematics of subduction input provided by IODP samples from the SW Pacific in comparison to lavas from the central Tonga arc, addressed as a worldwide endmember in terms of pre-subduction mantle wedge depletion. With an improved analytical precision, we report subtle, yet resolvable Zn isotope variations between the central Tongan islands, with an overall statistically relevant variation of 0.05‰ (at ±0.014‰ 2SD). The signatures are all > 0.1‰ lighter than the subduction input at this site, suggesting a fractionation process during subduction. After careful extraction of the isotopic effect caused by mantle melting processes (using DMM δ<sup>66/64</sup>Zn <sub>JMC-Lyon </sub>provided by Sossi et al. (2018) and Wang et al. (2017) and melt extraction indices such as Sm/La, Zr/Nb, and Zn/La), a pronounced negative correlation is observed between the Zn isotopic composition of the lavas and key fluid indicators such as Ba/Th and Ce/Pb. Together with predictions from <em>ab initio</em> calculations and mixing models performed between Indian DMM and Rayleigh dehydration of the subducting slab, we attribute the remaining, subtle Zn isotope variations to additions by Cl-rich fluids to the individual mantle wedges. A maximum of 5% chlorine-fluid contribution is suggested for the magmatic source of Tofua, whereas smaller proportions are estimated for Kao, Late and Ata. Overall, this study sheds new light on Zn fractionation mechanisms in sediment-poor subduction zones. Implications for the long-term Zn recycling will be addressed in this presentation.</p><p>References:</p><p>Sossi, P.A., Nebel, O., O’Neill, H.S.C., Moynier, F., 2018. Zinc isotope composition of the Earth and its behaviour during planetary accretion. Chemical Geology 447, 73-84.</p><p>Wang, Z.-Z., Liu, S.-A., Liu, J., Huang, J., Xiao, Y., Chu, Z.-Y., Zhao, X.-M., Tang, L., 2017. Zinc isotope fractionation during mantle melting and constraints on the composition of Earth’s upper mantle. Geochimica et Cosmochimica Acta 198, 151- 167.</p>

Igneous Rock Associations 13. Focusing on the Central American Subduction Zone

Central America has recently been an important focus area for investigations into the complex processes occurring in subduction zones. Here we review some of the new findings concerning subduction input, magma production and evolution, and resultant volcanic output. In the Nicaraguan portion of the subduction zone, subduction input is unusually wet, likely caused by extensive serpentinization of the mantle portion of the incoming plate associated with bending-related faulting seaward of the Middle America trench. The atypical influx of water into the Nicaraguan section of the subduction zone ultimately leads to a regional maximum in the degree of mantle melting. In central Costa Rica, subduction input is also unusual in that it includes oceanic crust flavored by the Galapagos plume. Both of these exotic subduction inputs are recognizable in the compositions of magmas erupted along the volcanic front. In addition, Nicaraguan magmas bear a strong chemical imprint from subducting hemipelagic sediments. The high-field-strength-element depletions of magmas from El Salvador through Costa Rica are related to local variations in the depth to the subducting Cocos plate, and, therefore, to segmentation of the volcanic front. Minor phases, probably amphibole or rutile, control these variable depletions. Silicic magmas erupted along the volcanic front exhibit the same along-arc geochemical variations as their mafic brethren. This and their mantle-like radiogenic isotopic compositions suggest the production of juvenile continental crust all along the Central American subduction zone. Punctuated times of enhanced magmatic input from the mantle may aid in crustal development.SOMMAIREL’Amérique centrale a récemment été le lieu de recherches sur les processus complexes se produisant dans les zones de subduction. Ici nous passons en revue certaines découvertes sur nature des intrants de subduction, la production et l’évolution des magmas, ainsi que les extrants volcaniques résultants. Dans le segment nicaraguayen de la zone de subduction, les intrants de subduction sont exceptionnellement humides, probablement à cause de la serpentinisation généralisée de la portion mantélique de la plaque en subduction, fissurée par flexure dans partie marine de la fosse océanique de l’Amérique centrale. L'afflux atypique en eau dans le segment nicaraguayen de la zone de subduction induit ultimement un maximum régional de la proportion de fusion du manteau. Dans la portion centrale du Costa Rica l’intrant de subduction est lui aussi atypique en ce qu’il comprend une croûte océanique teintée par le panache des Galápagos. Ces deux intrants de subduction atypiques sont répercutés dans la composition des magmas éjectés le long du front volcanique. En outre, les magmas nicaraguayens affichent une forte empreinte chimique héritée des sédiments hémipélagiques en subduction. Les appauvrissements en éléments à fortes liaisons atomiques des magmas, du El Salvador jusqu’au Costa Rica, sont liés à des variations localisées de la profondeur de la plaque en subduction de Cocos, et donc, à la segmentation du front volcanique. Des phases mineures, probablement amphibole et rutile, déterminent ces appauvrissements variables. Les magmas siliceux éjectés le long du même front volcanique montrent les mêmes variations géochimiques le long de l’arc que leur contrepartie mafique. De plus, les compositions radiogéniques de leurs contreparties mantéliques évoquent la production d’une croûte continentale juvénile le long de la zone de subduction de l’Amérique centrale. Des épisodes d’accroissements ponctuels des intrants magmatiques du manteau peuvent contribuer au développement d’une croûte.