Transport of Polymers in Low Permeability Carbonate Rocks

Polymer transport and retention affect oil recovery and economic feasibility of EOR processes. Most studies on polymer transport have focused on sandstones with permeabilities (k) higher than 200 mD. A limited number of studies were conducted in carbonates with k less than 100 mD and very few in the presence of residual oil. In this work, transport of four polymers with different molecular weights (MW) and functional groups are studied in Edwards Yellow outcrop cores (k<50 mD) with and without residual oil saturation (Sor). The retention of polymers was estimated by both the material balance method and the double-bank method. The polymer concentration was measured by both the total organic carbon (TOC) analyzer and the capillary tube rheology. Partially hydrolyzed acrylamide (HPAM) polymers exhibited high retention (> 150 μg/g), inaccessible pore volume (IPV) greater than 7%, and high residual resistance factor (>9). A sulfonated polyacrylamide (AN132), showed low retentions (< 20 μg/g) and low IPV. The residual resistance factor (RRF) of AN132 in the water-saturated rock was less than 2, indicating little blocking of pore throats in these tight rocks. The retention and RRF of the AN132 polymer increased in the presence of residual oil saturation due to partial blocking of the smaller pore throats available for polymer propagation in an oil-wet core.

SENSITIVITY ANALYSIS FOR POLYMER INJECTION TO IMPROVE HEAVY OIL RECOVERY – SMALL-SCALE SIMULATION STUDY

Polymer flooding has been widely used for enhancing oil recovery, due to the growing number of successful applications around the world. The process aims to increase water viscosity and, thus, decrease the water/oil mobility ratio, thereby improving sweep efficiency. The understanding of the physical mechanisms involved in this enhanced oil recovery process allows us to forecast the application potential of polymer flooding. This work aims to assess physical phenomena associated with heavy oil recovery through polymer flooding using 1D small-scale simulation models. We evaluate the influence of different levels of adsorption, accessible pore volume, residual resistance factor, and polymer concentration on the results and compare their magnitude effect on the results. The models used in this study were built using data from previous lab work and literature. For each one of the mentioned parameters, this work compares the histories of water cut, cumulative water-oil ratio, average pressure, and oil recovery factor. Additionally, water saturation, water viscosity, and water mobility profile were determined for specific periods of the flooding process. The sensitivity analyses showed that high levels of adsorption influence the polymer loss of the advance front, delaying oil recovery. Low values of accessible pore volume lead to a slightly faster polymer breakthrough and oil recovery anticipation. A high residual resistance factor increases the average pressure and improves oil recovery. Higher polymer concentration enhances the displacement efficiency and enhances the recovery factor.

Colloidal dispersion gels for in-depth permeability modification

In this study, we describe the synthesis, characterization and evaluation of colloidal dispersion gels (CDGs) to be used as in-situ fluid diversion. The chemical stability of CDGs was improved by modifying the polymer mixture. The CDGs were synthesized by free radical crosslinking polymerization using 2-acrylamido-2-methylpropane sulfonic acid (AMPS), Acrylic acid (AAc), partially hydrolyzed polyacrylamide (HPAM) and chromium triacetate crosslinker. The effect of crosslinker/polymer concentration, salinity, gelation time, rheological behavior, particle size distribution of CDGs, also their thermo-chemical stabilities and resistance/residual resistance factor (RRF) were investigated.

Selective insulation of water flows in a well based on the use of production waste

A method for isolating water inflows into the well by blocking high permeability zones with a gel-forming composition based on sodium silicate, including biologically active additives has been developed. Whey is used as a biologically active supplement. As a result of isolation of the watering intervals by the gel-forming composition, low-permeability oil-saturated areas are involved in the development. The gelation process can be adjusted depending on the concentrations of sodium silicate and whey, as well as the temperature at a certain depth of the reservoir, necessary for isolation. In order to prevent a premature coagulation process when the formation is saturated with hard formation water, fresh or softened water is pumped in front of the gel-forming composition. This technology is used to reach the residual resistance factor to the value 3.88, an increase in oil production will be 18.5%.

An Investigation of CO2-Responsive Preformed Particle Gel for Conformance Control of CO2 Flooding in Reservoirs With Fractures or Fracture-Like Channels

Summary Gel treatment is an important technique to solve early CO2 breakthrough and excess–CO2–production problems, caused by the low viscosity and low density of CO2, as well as the heterogeneity of reservoirs with fractures or fracture–like channels. However, there is no reported work on gel that increases its volume after reacting with CO2 (termed CO2–responsive gel) for the conformance control of CO2 flooding. In this paper, the intrinsic properties of a CO2–responsive preformed particle gel (CR–PPG) were evaluated in a water/supercritical–CO2 (scCO2) environment in high–pressure vessels. Continuous scCO2 injection and CR–PPG treatment were conducted in fractured sandstone cores, to probe their plugging performance to scCO2 flow in a high–permeability–contrast system. The volumetric swelling ratio (VSR) of the CR–PPG increased by approximately two times in the presence of scCO2, compared with a sample under similar conditions in the absence of scCO2. The CR–PPG swelling ratio decreased with increasing NaCl concentration. Under the same conditions, the temperature did not have an apparent effect on the swelling ratio after 31 days of swelling. In coreflooding experiments, the placed CR–PPG resisted a considerable pressure up to 617.0 psi before breakthrough. After a shut–in process, CO2–breakthrough pressure was detected at 437.2 psi. It is observed that the shut–in process improved the plugging performance of CR–PPG to CO2 as revealed by the increase in the residual resistance factor. Controlling the shut–in time was found to be effective in augmenting the increase in the residual resistance factor, by increasing the VSR of placed CR–PPG. Resistance of CR–PPG to some real field challenges, including a high pressure gradient and long–term exposure to CO2, was also reported for field–applicability concerns.

Modeling of Chemical Water Shut off Treatments

Water production is one of the major problems that been encountered in the oil industry, which may cause corrosion of tubular, fine migration and acceleration of well abandonment. More than $40 billion is spent yearly dealing with unwanted water, so a treatment should be implemented to reduce high water production. Many papers investigated and focused their researches on how to reduce water cut percentage. Mechanical and chemical treatments are suggested, chemical treatment represented in polymer-gel with cross linker solution proved optimistic results. Gel can solve many types of water production problems rather than other chemical or other mechanical treatments. In this paper a model was constructed to determine the applicability of gels in reducing water permeability. The model included equations predicted using statistical software (SPSS) that determines the water residual resistance factor (Frrw) and the oil residual resistance factor (Frro) by inserting polymer concentration then determine the optimum concentration which gives the most desired results. A real field data was obtained from Z field (well X, well Y, and Well Z) and gel applicability in permeability reduction had been tested, then an optimistic result obtained. The outcomes of this study investigate that there is a great chance to apply polymer-gel as water shut-off technique. For future work a full core-flooding study must be constructed to obtain more set of data and improvement of the equations accuracy