Variations of Source Composition and Melting Degrees of Olivine-Phyric Rocks from Kamchatsky Mys: Results of Geochemical Modeling of Trace Element Contents in Melts

We conducted the geochemical modeling of trace element contents for primary melts of olivine-phyric rocks from Kamchatsky Mys. This modeling reveals substantial chemical heterogeneity of their source while the average source composition is close to the enriched DMM (E-DMM). The average estimation of the melting degree is in the range from 9.1 ± 3.8% for the model of modal batch melting to 15.4 ± 5.2% for the model of accumulated fractional melting, which is slightly higher than the estimation for primitive mid-ocean ridge basalt (MORB) glasses (7.4 ± 2.2% and 12.5 ± 3.8% respectively). It is in a good agreement with high melting degrees estimated earlier for other rocks of the Kamchatsky Mys ophiolites. Low pressure of mantle melting caused by the elevated speed of decompression relative to the average MORB could explain elevated melting degrees estimated for Kamhcatsky Mys ophiolites as well as their characteristic Sr-anomalies and sulfide saturation on the earliest stages of magmatic evolution.

Petrogenesis of the post-collisional porphyritic granitoids from Jhalida, Chhotanagpur Gneissic Complex, eastern India

The Jhalida porphyritic granitoid pluton is exposed in a regional shear zone belonging to the Chhotanagpur Gneissic Complex of the Satpura Orogen (c. 1.0 Ga), regarded as the collisional suture between the South and North Indian blocks. The pluton intruded the migmatitic gneisses, metapelites, calc-silicate rocks and amphibolites belonging to the amphibolite facies. The mineral assemblage indicates the calc-alkaline nature of the granitoids. Mafic (Pl–Qz–Bt±Hbl) schists occur as xenoliths within the pluton. The granitoids are classified as alkali-calcic to alkalic, dominantly magnesian grading to ferroan, metaluminous to slightly peraluminous, and shoshonitic to ultrapotassic. Geochemically, the granitoids are enriched in large-ion lithophile elements (LILE), particularly K, and light rare earth elements (LREE), but are comparatively depleted in Nb, Ta, and heavy rare earth elements (HREE). The strong negative correlation between SiO2 and P2O5, metaluminous to weakly peraluminous character, high liquidus temperature (798–891°C) and high fO2 (ΔQFM +0.8 to +1.6) of the melt suggest their I-type nature. Field relations and tectonic discrimination diagrams imply their post-collisional emplacement. Low Nb/U (average 8.5), Ce/Pb (average 9.0), and Al2O3/(Al2O3 + FeO(t) + MgO + TiO2) ratios and relatively low Mg number (average 0.15) of these granitoids indicate a crustal mafic source. Batch melting (at 825–950°C) of 10–20% of an old, incompatible elements-rich high-K high-alumina hornblende granulite can generate the porphyritic granite melt. The heat source for melting was an upwelling of the asthenospheric mantle in the post-collisional set-up. Textural and chemical characteristics of the mafic xenoliths show that invading porphyritic granitoid magma metasomatized the amphibolite protoliths.

THE ROLE OF MAGMATIC HEAT SOURCES IN THE FORMATION OF REGIONAL AND CONTACT METAMORPHIC AREAS IN WEST SANGILEN (TUVA, RUSSIA)

The tectonomagmatic evolution of the Sangilen massif has been described in detail in numerous publications, but little attention was given to heat sources related to the HT/LP metamorphism. Modeling of the magma transport to the upper‐crust levels in West Sangilen shows that the NT/LP metamorphism is related to gabbromonodiorite intrusions. This article is focused on the thermo‐mechanical modeling of melting and lifting of melts in the crust, taking into account the density interfaces. The model of the Erzin granitoid massif shows that in case of fractional melting, the magma ascent mechanism is fundamentally different, as opposed to diapir upwelling – percolation take place along a magmatic channel or a system of channels. An estimated rate of diapiric rise in the crust amounts to 0.8 cm/yr, which is more than an order of magnitude lower than the rate of melt migration in case of fractional melting (25 cm/yr). In our models, a metamorphic thermal ‘anticline’ develops in stages that differ, probably, due to the modes of crust melting: batch melting occurs at the first stage, and fractional melting takes place at the second stage. It is probable that the change of melting modes from melting conditions in a ‘closed’ system to fractional melting conditions in ‘open’ systems is determined by tectonic factors. For the Sangilen massif, we have estimated the degrees of melting in the granulite, granite, and sedimentary‐metamorphic layers of the crust (6, 15, and 5 vol. %, respectively).

Effect of Mechanical Activation on the Heat of Fusion of a Conventional Batch Used for the Manufacture of Float Glass

ABSTRACTAn initial mixture of raw materials (batch) typically used for the manufacture of conventional soda-lime float glass was subjected to a mechanical activation process for 30 or 60 minutes in a planetary ball mill. An intensification of the chemical reactivity of the batch, which was directly related with the increase in the milling time, was observed. This accelerated the chemical reactions that took place during the batch melting process between sodium, calcium and magnesium carbonates and other components of the mixture, which happened at significantly lower temperatures with respect to the batch without mechanical activation. The heat of fusion of the batch, estimated using a methodology previously reported in the literature, indicated that the mechanical activation given to the initial mixture of raw materials decreased the energy consumed during the batch melting. This was also evidenced by a decrease in the temperature at which the release of CO2 ended, which was considerably larger than that previously reported in the literature based solely on the decrease in the particle size of a batch of similar composition achieved by dry sieving.