Potentially Toxic Element Contaminations and Lead Isotopic Fingerprinting in Soils and Sediments from a Historical Gold Mining Site

Lead (Pb) isotopes have been widely used to identify and quantify Pb contamination in the environment. Here, the Pb isotopes, as well as the current contamination levels of Cu, Pb, Zn, Cr, Ni, Cd, As, and Hg, were investigated in soil and sediment from the historical gold mining area upstream of Miyun Reservoir, Beijing, China. The sediment had higher 206Pb/207Pb ratios (1.137 ± 0.0111) than unpolluted soil did (1.167 ± 0.0029), while the soil samples inside the mining area were much more variable (1.121 ± 0.0175). The mean concentrations (soil/sediment in mg·kg−1) of Pb (2470/42.5), Zn (181/113), Cu (199/36.7), Cr (117/68.8), Ni (40.4/28.9), Cd (0.791/0.336), As (8.52/5.10), and Hg (0.168/0.000343) characterized the soil/sediment of the studied area with mean Igeo values of the potentially toxic element (PTE) ranging from −4.71 to 9.59 for soil and from −3.39 to 2.43 for sediment. Meanwhile, principal component analysis (PCA) and hierarchical cluster analysis (HCA) coupled with Pearson’s correlation coefficient among PTEs indicated that the major source of the Cu, Zn, Pb, and Cd contamination was likely the mining activities. Evidence from Pb isotopic fingerprinting and a binary mixing model further confirmed that Pb contamination in soil and sediment came from mixed sources that are dominated by mining activity. These results highlight the persistence of PTE contamination in the historical mining site and the usefulness of Pb isotopes combined with multivariate statistical analysis to quantify contamination from mining activities.

About this title - Pannotia to Pangaea: Neoproterozoic and Paleozoic Orogenic Cycles in the Circum-Atlantic Region

Special Publication 503 celebrates the career of R. Damian Nance. It features 27 articles, with more than 110 authors based in 18 different countries. These articles include contributions on the processes responsible for the formation and breakup of supercontinents, the controversies concerning the status of Pannotia as a supercontinent, the generation and destruction of Paleozoic oceans, and the development of the Appalachian-Ouachitan- Caledonide-Variscan orogens. In addition to field work, the approaches to gain that understanding include examining the relationships between stratigraphy and structural geology, precise geochronology, geochemical and isotopic fingerprinting, geodynamic modelling, regional syntheses, palaeogeographic modelling, and good old-fashioned arm-waving!The wide range of topics mirrors the breadth and depth of Damian's contributions, interests and expertise. Like Damian's papers, the contributions range from the predominantly conceptual to detailed field work, but all are targeted at understanding important tectonic processes. Their scope not only varies in scale from global to regional to local, but also in the range of approaches required to gain that understanding.