Molecular chirality detection using plasmonic and dielectric nanoparticles

Nanoscale particles and structures hold promise in circular dichroism (CD) spectroscopy for overcoming the weakness of molecular CD signals. Significant effort have been made to characterize nanophotonic CD enhancement and find efficient ways to boost molecular chirality, but the best solution is yet to be found. In this paper, we present a rigorous analytic study of the nanophotonic CD enhancement of typical nanoparticles. We consider metallic and dielectric nanoparticles capped with chiral molecules and analyze the effect of multipolar nanoparticles on the molecular CD. We identify the spectral features of the molecular CD resulting from the electric and magnetic resonances of nanoparticles and suggest better ways to boost molecular chirality. We also clarify the contribution of particle scattering and absorption to the molecular CD and the dependence on particle size. Our work provides an exact analytic approach to nanophotonic CD enhancement and offers a rule for selecting the most efficient particle for sensitive molecular chirality detection.

The action-sentence compatibility effect (ACE) a benchmark finding for embodiment - A meta-analysis

The embodied account of language comprehension has been one of the most influentialtheoretical developments in the recent decades addressing the question how humanscomprehend and represent language. To examine its assumptions, many studies havemade use of behavioral paradigms involving basic compatibility effects. Theaction–sentence compatibility effect (ACE) is one of the most influential of thesecompatibility effects and is the most widely cited evidence for the assumptions of theembodied account of language comprehension. However, recently there have beendifficulties to extend or even to reliably replicate the ACE. The conflicting findingsconcerning the ACE and its extensions lead to the discussion whether the ACE isindeed a reliable effect or whether it might be the product of publication bias or otherdistorting research practices. In a first step we conducted a meta-analysis using arandom-effects model. This analysis revealed a small but significant effect size of theACE (d = .129, p = .007). A second meta-analytic approach supports these findings ofthe existence of an ACE (Fisher’s method: χ2 = 124.379, p < .001). Furthermore, thetask-parameter Delay occurred as a factor of interest in whether the ACE appears withpositive or negative effect direction. This meta-analysis further assessed for potentialpublication bias and suggests that there is bias in the ACE literature.

Dispute over Grammatical Boundaries

This research studies the dispute among grammarians over some of the boundaries of grammatical categories by following the inductive-analytic approach. The selection of dispute issues is based on the objection by one of the dissenters with the linguistic inheritance. The disputes are classified in two sections, each of which embodies references you consult, and weighting what has been proven correct.