Enhancing the Interlaminar Fracture Toughness and AO Resistance of CFRPs by Using Phosphorus-Containing Polymer/PEC-K Bifunctional Film

A new attempt to use a bifunctional interleaf for developing a novel structure–function-integrated composite with simultaneously improved interlaminar fracture toughness and atomic oxygen resistance was studied. The toughening mechanism and the atomic oxygen erosion property of the delaminated surfaces of the composites were examined. The bifunctional interleaf was prepared by blending a phosphorus-containing polymer and a thermoplastic polymer. After being interleaved, the mode I and mode II fracture toughness increased by 8.2% and 23.7% compared to the control sample, respectively. The toughness gains are much smaller than that of the only thermoplastic film-toughened composite because of the relative brittleness of the blend film. The atomic oxygen erosion rates of the mode I and mode II delamination surfaces decreased by 45.3% and 31.3% compared with the control, respectively. The carbon fibers on the irradiation surfaces are protected by a layer of phosphine oxide to prevent further erosion, and they were much less eroded, particularly for the mode I surface. In comparison, the erosion rates of the mode I and mode II surfaces of the toughened-only composite significantly increased by 83.6% and 107.2%, respectively, and the carbon fibers are seriously eroded.

Influence of the Composition of the Hybrid Filler on the Atomic Oxygen Erosion Resistance of Polyimide Nanocomposites

The structure and properties of nanocomposites based on organosoluble polyimide (PI) and branched functional metallosiloxane oligomers with different types of central metal atoms (Al, Cr, Fe, Zr, Hf and Nb) were investigated. Under the same weight content of the filler, the geometric parameters of the nanoparticles and thermal properties of the nanocomposites did not exhibit a direct relationship with the ability of the materials to withstand the incident flow of oxygen plasma. The atomic oxygenerosion resistance of the filled PI films was influenced by the composition of the hybrid fillerand the type of metal atom in the hybrid filler in the base metallosiloxane oligomer. To determine the effectiveness of the nanoparticles as protective elements of the polymer surface, the nanocomposite erosion yields pertaining to the concentration of the crosslinked organo–inorganic polymer forming the dispersed phase were determined and expressed in mmol per gram PI. The filler concentration in the polymer, expressed in these units, allows for comparison of the efficiency of different nanosize fillers for use in fabricating space survivable coatings. This can be important in the pursuit of new precursors, fillers for fabricating space survivable polymer composites.

Improved atomic oxygen erosion resistance of the carbon fibre–epoxy interface with polyhedral oligomeric silsesquioxane

Polyhedral oligomeric silsesquioxane (POSS) was grafted onto the surface of carbon fibres (CFs) to fabricate carbon fibre/epoxy (CF/EP) composites with improved interlaminar shear strength (ILSS) and atomic oxygen (AO) erosion resistance. POSS-CF was prepared by reacting amine groups on the pretreated CF surface with the POSS to form a continuous uniform layer of siloxane oligomers. X-Ray photoelectron spectroscopy, scanning electron microscopy and Fourier transform infrared spectroscopy demonstrated that POSS was successfully grafted onto the CF surface. The ILSS and AO erosion resistance of the POSS-treated CFs and CF-EP interface were improved because a SiO2 passivation layer formed with AO exposure, especially with POSS-EP0409. This is an effective solution for enhancing the interfacial bonding force and interfacial AO erosion resistance for the low-Earth orbit environment.