Performance of TiB2 Wettable Cathode Coating

A TiB2 wettable cathode coating was deposited on a graphite carbon cathode material via atmospheric plasma spraying (APS). The microstructure and phase composition of the TiB2 coating were analyzed via scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDS). The wettability and corrosion resistance of the coating were studied in a molten-aluminum electrolytic system. The results showed that the surface of the TiB2 coating prepared via plasma spraying was flat and that the main phase of the coating was TiB2. The wettability between the TiB2 coating and liquid aluminum was better than that between graphite cathode carbon block and liquid aluminum. The abilities of the TiB2 coating and graphite cathode carbon block to resist sodium (Na) penetration and prevent molten salt corrosion were compared through a corrosion test. The TiB2 coating was found to have better resistance to Na penetration and better refractory cryolite corrosion resistance than graphite cathode carbon block.

Effect of TiB2 Content on Properties of Nickel-Coated Graphite Self-Lubricating Coating Prepared by Laser Cladding

To improve the anti-wear and friction-reducing properties of self-lubricating coatings, Ni60/Nickel-coated graphite/TiB2 composite coatings with different contents were prepared by laser cladding. The coating properties were characterized by X-ray diffractometer (XRD), scanning electron microscope (SEM), energy spectrometer (EDS), electrochemical workstation, micro-Vickers hardness tester, and friction and wear tester. The results showed that with the increase in TiB2 content, the graphite morphology changed from spherical at 0 wt.% TiB2 content to a little black graphite alone at 14 wt.% TiB2 to irregular agglomerates at 22 wt.% TiB2. Furthermore, the hardness of the coatings increased with increasing TiB2 content, and the 63% Ni60 + 15% nickel-coated graphite + 22% TiB2 coating had the highest hardness. TiC and Cr7C3 were generated in the coatings with the addition of nickel-coated graphite, creating a dispersion reinforcement effect, so that the hardness of these coatings was higher than that of the 86% Ni60 + 0% nickel-coated graphite + 14% TiB2 coating without the addition of nickel-coated graphite. In addition, the 71% Ni60 + 15% Ni-coated graphite + 14% TiB2 coating had the lowest friction coefficient, wear loss, and wear volume, thus exhibiting excellent friction reduction and anti-wear properties. The 71% Ni60 + 15% nickel-coated graphite + 14% TiB2 coating had excellent corrosion resistance.

The Analysis of Resistance to Brittle Cracking of Tungsten Doped TiB2 Coatings Obtained by Magnetron Sputtering

In this work, the authors present the possibility of characterization of the fracture toughness in mode I (KIC) for TiB2 and TiB2 coatings doped with different concentration of W (3%, 6% and 10%). The Young’s modulus, hardness and fracture toughness of this coatings are extracted from nanoindentation experiments. The fracture toughness was evaluated using calculation of crack length measurement. An important observation is that increasing tungsten concentration in the range 0–10% changes the microstructure of the investigated coatings: from columnar structure for TiB2 coating to nano-composite structure for Ti-B-W (10%) coating. It can be concluded that doping with concentration 10 at.% W causes an increase of the fracture toughness for the tested coatings.

STUDY OF MACHINING OF THERMAL RECTIFICATED Corymbia citriodora AND Pinus elliottii

ABSTRACT This study evaluated the influence of thermal rectification in machining Corymbia citriodora and Pinus elliottii. The heat treatment was carried out for 6 hours at temperatures of 100°C, 140°C, 160°C, 180°C and 200°C and evaluated the performance of machining in three different material cutting tools, polished and hard metal carbide with TiB2 coating. The cutting power and roughness Ra and Rt of the machined surfaces with three different tools were evaluated. The power has proven lower for Pinus elliottii species. The roughness was lower for Corymbia citriodora wood. The roughness Ra and Rt were lower for heat treatment temperature of 180°C.