The Petrogenesis of Mid-Cretaceous Continental Intraplate Volcanism in Marlborough, New Zealand, during the Break-up of Gondwana

<p>The Lookout Volcanics are the remnants of an extensive sheet of mid-Cretaceous (ca. 96 Ma) continental intraplate volcanic rocks erupted just prior to the rifting of New Zealand from Gondwana. Preserved in a fault angle depression bounded by the Awatere Fault located in Marlborough, South Island, New Zealand, the volcanic rocks cover an area of ca. 50 km2 with exposed thicknesses up to 1000 m. On the basis of stratigraphic evidence the dominantly terrestrial lavas flows are inferred to have erupted from dykes of a coeval radial dyke swarm. A detailed sampling of the lava flows of the Lookout Volcanics has been undertaken with a ca. 700 m composite stratigraphic section being constructed, largely based on a continuous sequence of lava flows outcropping in Middlehurst Stream. New Rb-Sr age constraints for the Lookout Volcanics (97.6 plus or minus 3.4 Ma) and Blue Mountain Igneous Complex (97.1 plus or minus 0.7 Ma) are consistent with previous radiometric dates of plutonic complexes in the Central Marlborough Igneous Complex, and suggest a rapid accumulation of volcanic material from ca. 98-96 Ma during the initial extension of proto-New Zealand. The predominantly mafic and alkaline samples include basalt, picrobasalt, basanite, trachybasalt and basaltic trachyandesite rock types. No samples represent primary magmas with all samples having undergone fractionation (or accumulation) of olivine plus clinopyroxene plus or minus plagioclase plus or minus Fe-Ti oxides. Initial Sr-Nd-Hf-Pb isotopic variations (87Sr/86Sr = 0.7030-0.7039; 143Nd/144Nd = 0.51272-0.51264; 176Hf/177Hf = 0.28283-0.28278; 206Pb/204Pb = 20.32-18.82) reflect mixing between melts of a HIMUlike mantle component with up to 25-30% of an Early Cretaceous upper crustal component. Oxygen isotope ratios determined by laser fluorination analysis from 6 lava flows yielded delta 18O = 4.7-5.0 per thousand for olivine, 4.8-5.4 per thousand in clinopyroxene cores, 3.9-5.5 per thousand in clinopyroxene rims. Average olivine (4.8 per thousand) and clinopyroxene core (5.1 per thousand) values are 0.4-0.5 per thousand lower than those of average mantle peridotite but comparable to those of HIMU OIB, and are consistent with New Zealand intraplate magmas being generated by a low delta 18O mantle. However, oxygen isotopic disequilibrium between clinopyroxene cores and rims (Delta 18O = -1.4 to +0.3) records the overprinting of this signature by crustal processes. Negative disequilibrium between clinopyroxene rims and cores in primitive samples suggests these phenocrysts grew in a shallow crustal magma chamber with an active meteoric water system. The effects of crustal assimilation can also be observed with clinopyroxene phenocrysts from the most evolved sample exhibiting coupled elevated delta 18O and 87Sr/86Sr. Variations in incompatible trace element ratios are consistent with the Lookout Volcanics being the small degree (2-5%) partial melts of an amphibole-bearing garnet pyroxenite. Furthermore, the elevated NiO contents of olivine phenocrysts are consistent with melting of a pyroxenitic mantle source. The presence of residual amphibole constrains melting to the hydrous subcontinental lithospheric mantle. The Lookout Volcanics and coeval plutonic complexes are the oldest occurrences of HIMU magmatism in Zealandia. This source was generated by small degree silicate melts from recycled oceanic lithosphere that metasomatised the base of the subcontinental lithospheric mantle beneath East Gondwana over 200 Ma ago.</p>

The Petrogenesis of Mid-Cretaceous Continental Intraplate Volcanism in Marlborough, New Zealand, during the Break-up of Gondwana

<p>The Lookout Volcanics are the remnants of an extensive sheet of mid-Cretaceous (ca. 96 Ma) continental intraplate volcanic rocks erupted just prior to the rifting of New Zealand from Gondwana. Preserved in a fault angle depression bounded by the Awatere Fault located in Marlborough, South Island, New Zealand, the volcanic rocks cover an area of ca. 50 km2 with exposed thicknesses up to 1000 m. On the basis of stratigraphic evidence the dominantly terrestrial lavas flows are inferred to have erupted from dykes of a coeval radial dyke swarm. A detailed sampling of the lava flows of the Lookout Volcanics has been undertaken with a ca. 700 m composite stratigraphic section being constructed, largely based on a continuous sequence of lava flows outcropping in Middlehurst Stream. New Rb-Sr age constraints for the Lookout Volcanics (97.6 plus or minus 3.4 Ma) and Blue Mountain Igneous Complex (97.1 plus or minus 0.7 Ma) are consistent with previous radiometric dates of plutonic complexes in the Central Marlborough Igneous Complex, and suggest a rapid accumulation of volcanic material from ca. 98-96 Ma during the initial extension of proto-New Zealand. The predominantly mafic and alkaline samples include basalt, picrobasalt, basanite, trachybasalt and basaltic trachyandesite rock types. No samples represent primary magmas with all samples having undergone fractionation (or accumulation) of olivine plus clinopyroxene plus or minus plagioclase plus or minus Fe-Ti oxides. Initial Sr-Nd-Hf-Pb isotopic variations (87Sr/86Sr = 0.7030-0.7039; 143Nd/144Nd = 0.51272-0.51264; 176Hf/177Hf = 0.28283-0.28278; 206Pb/204Pb = 20.32-18.82) reflect mixing between melts of a HIMUlike mantle component with up to 25-30% of an Early Cretaceous upper crustal component. Oxygen isotope ratios determined by laser fluorination analysis from 6 lava flows yielded delta 18O = 4.7-5.0 per thousand for olivine, 4.8-5.4 per thousand in clinopyroxene cores, 3.9-5.5 per thousand in clinopyroxene rims. Average olivine (4.8 per thousand) and clinopyroxene core (5.1 per thousand) values are 0.4-0.5 per thousand lower than those of average mantle peridotite but comparable to those of HIMU OIB, and are consistent with New Zealand intraplate magmas being generated by a low delta 18O mantle. However, oxygen isotopic disequilibrium between clinopyroxene cores and rims (Delta 18O = -1.4 to +0.3) records the overprinting of this signature by crustal processes. Negative disequilibrium between clinopyroxene rims and cores in primitive samples suggests these phenocrysts grew in a shallow crustal magma chamber with an active meteoric water system. The effects of crustal assimilation can also be observed with clinopyroxene phenocrysts from the most evolved sample exhibiting coupled elevated delta 18O and 87Sr/86Sr. Variations in incompatible trace element ratios are consistent with the Lookout Volcanics being the small degree (2-5%) partial melts of an amphibole-bearing garnet pyroxenite. Furthermore, the elevated NiO contents of olivine phenocrysts are consistent with melting of a pyroxenitic mantle source. The presence of residual amphibole constrains melting to the hydrous subcontinental lithospheric mantle. The Lookout Volcanics and coeval plutonic complexes are the oldest occurrences of HIMU magmatism in Zealandia. This source was generated by small degree silicate melts from recycled oceanic lithosphere that metasomatised the base of the subcontinental lithospheric mantle beneath East Gondwana over 200 Ma ago.</p>

Origin of Fe-Ni-Cu (Co) sulfide and Fe-Ti oxide minerals in the c. 1.77 Ga dolerite dyke, Singhbhum Craton (eastern India)

Dolerite dyke swarms are widespread within the Singhbhum Craton (eastern India) that emplaced from the Neoarchean to Paleoproterozoic era just after the stabilization of crust before c. 3 Ga. These dyke swarms are oriented in NE - SW to NNE - SSW, NW - SE to WNW - ESE, E - W, and N - S directions. The WNW - ESE trending c. 1.77 Ga Pipilia dyke swarm is sampled from the Satkosia area of the Orissa state. The dyke shows a noticeable disparity in terms of the modal proportion and grain size of pyroxenes, plagioclase, Fe-Ti-oxide minerals and texture across the trend. At places the primary silicates are altered to secondary hydrated mineral assemblages of amphibole, chlorite and sericite. Primary silicates are clinopyroxene (augite: Mg# = 65.7 - 82.6; En37-48Fs11-17Wo36-41), orthopyroxene (clinoenstatite: Mg# = 68.5 − 78; En63-70Fs20-29Wo4-5), plagioclase (An11-39Ab44-82Or1-7) and Fe-Ti oxides are titanomagnetite (FeO = 34.38 − 39.50 wt%, Fe2O3 = 48.26 − 56.21 wt%, TiO2 = 5.05 − 9.60 wt%) and ilmenite (FeO = 40.75 − 43.79 wt%, Fe2O3 = 3.54 − 10.03 wt%, TiO2 = 47.82 − 50.87 wt%). Application of two-pyroxene thermometry yields an equilibration temperature range of 1065oC to 978oC, and coexisting titanomagnetite-ilmenite pairs reveal 731.39oC to 573.37oC at the oxygen fugacity (fO2) condition NNO+0.3 to FMQ-1.03. The dyke contains disseminated sulfides at the interstices of Fe-Ti-oxides, and silicates. Major sulfide minerals are pyrite, chalcopyrite, and vaesite; Pyrite-vaesite assemblages occur in association with secondary silicate minerals. Pyrite grains contain variable concentration of Co = 0.01 − 5.70 wt% and Ni = 0.02 − 1.95 wt%. Coexisting vaesite contains Co = 2.42 − 10.44 wt%, Ni = 26.40 − 47.88 wt%, and Fe = 7.32 − 26.55 wt%. Texture, sulfide-silicate assemblage, and presence of low metal/S sulfides such as the pyrite-vaesite assemblage indicate primary Fe-Ni- sulfides (pyrrhotite-pentlandite) that segregated from immiscible sulfide liquid at high temperature is modified by late magmatic/hydrothermal fluid activities. Numerous sulfide-bearing deposits hosted in ultramafic-mafic intrusions of Paleoproterozoic age have been recorded globally and the occurrence of Fe-Ni-sulfides in the c. 1.77 Ga Pipilia dyke swarm in the Singhbhum Craton enhances the exploration potential of this craton in eastern India.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5643989

Lamprophyre as the Source of Zircon in the Veneto Region, Italy

Discrete zircons, up to 9 mm in length, occur in alluvial deposits from the Veneto area. They are likely derived from the disaggregation of lamprophyric rocks belonging to a regional, pervasive dyke-swarm. Zircon and REE phases occur in both alkaline lamprophyres and connate calcite-bearing felsic lithics and their debris in lamprophyre breccia. We present 36 new complete U–Pb and trace element analyses of zircons and associated inclusions. We used a statistical approach on a larger dataset using new and literature data to evaluate the confidence figure to give an estimation of age of zircons. Inclusions suggest a genetic link with an S–CO2–ZrO–BaO–SrO–CaO-rich fluid/melt possibly associated with carbonate-rich alkaline parental magma and a metasomatised mantle source. This paper confirms the importance of calcite–syenite and lamprophyre genetic link and zircon magmatic origin, in contrast with hydrothermal and metamorphic zircons. U–Pb dating by LA-ICP-MS provides time constrains (40.5–48.4 Ma, Lutetian), consistent with the age of the alkaline magmatic event. Trace element data indicate a link to anorogenic magmatism associated with mantle upwelling. Complex zoning is highlighted by cathodoluminescence images. The Veneto zircons are helpful for regional geological information and may have commercial potential as a critical resource for green technologies.

Highly magmatic breakup LIP centers – a revisit to the East Greenland VRM

Decompressional release of magma at continental triple rift breakup LIP centers, above mantle plume stems, result in highly magmatic settings. As a particularly well exposed example, it is proposed that the East Greenland coastal dyke swarm preserves a structural record of how dyke dilations versus tectonic extension increased upon approaching its Kangerlussuaq triple rift center. Such more magmatic breakup is reflected by how abruptly its volcanic rifted margin transitions into 100% dykes, and in this case up to 100 km farther inland than its geophysically determined continent-ocean boundary. Correspondingly high magma flux through an igneous Kap Edward Holm center sustained the lateral injection of up to 150 km-long dykes, evidenced by increased cut-off dyke thicknesses - below which there is an anomalously low abundance of thinner dykes - that conform to the cube root of their thermal arrest distance. Only the thickest and thereby longest dyke injections linked up with a more southerly located igneous Imilik center of an en echelon offset dyke swarm, the complex transition into which is also addressed. This highly magmatic central plumbing system is further compared to similar volcanic zones across Iceland and other post-Paleozoic breakup LIPs, in order to contextualize its importance.

Evolution of ultrapotassic volcanism on the Kaapvaal craton: deepening the orangeite versus lamproite debate

Orangeites are a significant source of diamonds, yet ambiguity surrounds their status among groups of mantle-derived potassic rocks. This study reports mineralogical and geochemical data for a ca. 140 Ma orangeite dyke swarm that intersects the Bushveld Complex on the Kaapvaal craton in South Africa. The dykes comprise distinctive petrographic varieties that are linked principally by olivine fractionation, with the most evolved members containing minor amounts of primary carbonate, sanidine and andradite garnet in the groundmass. Although abundant groundmass phlogopite and clinopyroxene have compositions that are similar to those of cratonic lamproites, these phases show notable Ti-depletion, which we consider a hallmark feature of type orangeites from the Kaapvaal craton. Ti-depletion is also characteristic for the bulk rock compositions and is associated with strongly depleted Th-U-Nb-Ta contents at high Cs-Rb-Ba-K concentrations. The resultant high LILE/HFSE ratios of orangeites suggest that mantle source enrichment occurred by metasomatic processes in the proximity of ancient subduction zones.The Bushveld-intersecting orangeite dykes have strongly enriched Sr-Nd-Hf isotopic compositions (initial 87Sr/86Sr = 0.70701-0.70741; εNd = −10.6 to −5.8; εHf = −14.4 to −2.5), similar to those of other orangeites from across South Africa. Combined with the strong Ti-Nb-Ta depletion, this ubiquitous isotopic feature points to the involvement of ancient metasomatized mantle lithosphere in the origin of Kaapvaal craton orangeites, where K-rich metasomes imparted a ‘fossil’ subduction geochemical signature. Previous geochronology studies identified ancient K-enrichment events within the Kaapvaal cratonic mantle lithosphere, possibly associated with collisional tectonics during the 1.2-1.1 Ga Namaqua-Natal orogeny of the Rodinia supercontinent cycle. It therefore seems permissible that the cratonic mantle root was preconditioned for ultrapotassic magma production by tectonomagmatic events that occurred along convergent plate margins during the Proterozoic. However, reactivation of the K-rich metasomes had to await establishment of an extensional tectonic regime, such as that during the Mesozoic breakup of Gondwana, which was accompanied by widespread (1000 × 750 km) small-volume orangeite volcanism between 200 and 110 Ma.Although similarities exist between orangeites and lamproites, these and other potassic rocks are sufficiently distinct in their compositions such that different magma formation processes must be considered. In addition to new investigations of the geodynamic triggers of K-rich ultramafic magmatism, future research should more stringently evaluate the relative roles of redox effects and volatile components such as H2O-CO2-F in the petrogeneses of these potentially diamondiferous alkaline rocks.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5440652