Boosting the resolution of multidimensional NMR spectra by complete removal of proton spin multiplicities

Over decades multidimensional NMR spectroscopy has become an indispensable tool for structure elucidation of natural products, peptides and medium sized to large proteins. Heteronuclear single quantum coherence (HSQC) spectroscopy is one of the work horses in that field often used to map structural connectivity between protons and carbons or other hetero nuclei. In overcrowded HSQC spectra, proton multiplet structures of cross peaks set a limit to the power of resolution and make a straightforward assignment difficult. In this work, we provide a solution to improve these penalties by completely removing the proton spin multiplet structure of HSQC cross peaks. Previously reported sideband artefacts are diminished leading to HSQC spectra with singlet responses for all types of proton multiplicities. For sideband suppression, the idea of restricted random delay (RRD) in chunk interrupted data acquisition is introduced and exemplified. The problem of irreducible residual doublet splitting of diastereotopic CH2 groups is simply solved by using a phase sensitive JRES approach in conjunction with echo processing and real time broadband homodecoupling (BBHD) HSQC, applied as a 3D experiment. Advantages and limitations of the method is presented and discussed.

Magnetic Domain-Wall Induced Electric Polarization in NdCrO3 Polycrystalline Ceramic

We reported the magnetic, dielectric and magnetoelectric properties of NdCrO3 polycrystalline ceramics. Magnetization curves revealed two magnetic transitions at 227 K and 38 K, which corresponded to Cr3+ canted antiferromagnetic ordering and Cr3+ spin reorientation phase transition, respectively. At 11.5 K, a Schottky-type anomaly was observed, caused by Nd3+ ground doublet Zeeman splitting. High-temperature dielectric relaxation exhibited a type of thermally activated relaxation process, which mainly resulted from the Maxwell–Wagner effect. The spin-reorientation of Cr3+ ions and the Nd3+ ground doublet splitting were observed to be accompanied by an electric polarization. The polarization could be induced by the presence of the antiferromagnetic-type domain walls, which led to spatial inversion symmetry breaking.

Energy spectra in $p$-shell $\Lambda$ hypernuclei and $^{19}_{\Lambda}\textrm{F}$ and spin-dependent $\Lambda N$ interactions

Energy spectra of $0s$-orbit $\Lambda$ states in $p$-shell $\Lambda$ hypernuclei ($^{A}_\Lambda Z$) and those in $^{19}_{\Lambda}\textrm{F}$ are studied with the microscopic cluster model and antisymmetrized molecular dynamics using the $G$-matrix effective $\Lambda N$ ($\Lambda NG$) interactions. Spin-dependent terms of the ESC08a version of the $\Lambda NG$ interactions are tested and phenomenologically tuned to reproduce observed energy spectra in $p$-shell $^{A}_\Lambda Z$. Spin-dependent contributions of the $\Lambda N$ interactions to spin-doublet splitting and excitation energies are discussed. Energy spectra for unobserved excited states in $p$-shell $^{A}_\Lambda Z$ and $^{19}_{\Lambda}\textrm{F}$ are predicted with the modified $\Lambda NG$ interactions.

COULOMB INTERACTION OF TRIANGULAR QUANTUM DOTS IN A SMALL RING INTERFEROMETER

Doublet splitting of single-electron peaks has been observed in the conductance of a small high-resistance ring interferometer. Realistic modeling of the device shows that the electron system of interferometer divides into two triangular quantum dots connected by single-mode channels to each other and to reservoirs. We explain the splitting of conductance peaks by charge interaction of the dots.