Second-order nonlinear polarizability of ferrocene–BODIPY donor–acceptor adducts. Quantifying charge redistribution in the excited state

Ferrocene–BODIPY based donor–acceptor systems linked either directly or through an N-phenylmethanimine or ethynylbenzene linker with improved second-order nonlinear polarizability.

Multifunctional geometrical isomers of ferrocene-benzo[1,2-b:4,5-b′]difuran-2,6-(3H,7H)-dione adducts: second-order nonlinear optical behaviour and charge transport in thin film OFET devices

New ferrocene based donor–acceptor chromophores depict structure-dependent second-order nonlinear polarizability and charge transport in thin film OFET devices.

TUNABLE GRID GATED DOUBLE-QUANTUM-WELL FET TERAHERTZ DETECTOR

Several aspects of the theory of plasmon resonant DC photoconduction are discussed here, in connection with recent observations involving a THz-irradiated grid-gated double-quantum-well FET.1 In this, we construct a classical model of nonlinear polarizability to second order in the THz field using a “hydrodynamic” type formulation including the roles of a stress-tensor and friction/viscosity. The resulting second order polarizability exhibits resonant behavior when the THz frequency matches plasmon frequencies of the system, sharply reducing the effectiveness of screened impurity scattering potentials which can admit resonant DC photoconduction. Furthermore, we also show that an asymmetric double-quantum-well system with lateral periodicity can mix optical and acoustic plasmons, giving rise to an interlayer THz field which becomes very strong when tuned by gate voltage into the “mode-mode-repulsion” regime wherein the optical and acoustic modes equally share amplitude. This can enhance interlayer electron tunneling and may contribute to photoconductivity.