This chapter introduces an improved proportional-integral-derivative (PID) adjusting method by applying a simulated annealing algorithm (SAA) and the cosine, tangent, exponential measures of single-valued neutrosophic sets (SvNSs). For the approach, characteristic values of the unit step response (rise time, peak time, settling time, undershoot ratio, overshoot ratio, and steady-state error) in the control system should be neutrosophicated by the neutrosophic membership functions. Next, one of cosine, tangent, and exponential measures is used to obtain the similarity measure of the ideal SvNS and the response SvNS to assess the control performance of the PID controller by the optimization values of the PID parameters Kp, Ki, and Kd searched by SAA. The results of the illustrative example obtained by these measures and SAA are better than the existing ones and indicate better PID controller performance. Comparative results can demonstrate the rationality and superiority of the improved PID adjusting method.