Reflux Reaction Behavior of Phosphorus Under Nonequilibrium Condition of Casting Ladle Between Slag and Hot Metal

2016 ◽  
pp. 699-705
Author(s):  
MA Jinfang ◽  
Zhang Jianliang ◽  
Wang Zhenyang ◽  
Xing Xiangdong
Keyword(s):  
Nonequilibrium Condition ◽  
Hot Metal ◽  
Reaction Behavior ◽  
Casting Ladle

HREM observations of internetallic alloy formation in Pt-Sn thin films

1992 ◽  
Vol 50 (1) ◽  
pp. 52-53
Author(s):  
D.C. Dufner
Keyword(s):  
Thin Films ◽  
Cross Sections ◽  
Carbon Films ◽  
Solid State Reactions ◽  
Alloy Formation ◽  
Reaction Behavior ◽  
Interdiffusion Process ◽  
Compositional Changes ◽  
General Goal ◽  
Film Method

The general goal of this research is to clarify mechanisms of solid state reactions at the atomic level as a step in the rationalization of macroscopic reaction behavior in solids. A study of intermetallic alloy formation resulting from interdiffusion of metals in thin films can be made by HREM. In this work, reactions between Pt and Sn in thin films are studied to elucidate mechanisms for structural and compositional changes during the interdiffusion process.Thin films of Pt and Sn used in this study were prepared by the two-film method introduced by Shiojiri. Few hundred angstroms of Pt were vacuum-deposited onto holey carbon films mounted on TEM grids. Sn films with an average thickness of 200Å were created by evaporation at rates of 15-30 Å/sec onto air-cleaved KBr substrates. The Sn films were wet-stripped and collected on the holey Pt grids. Figure 1 shows a cross-section schematic of a Pt-Sn couple. While this two-film arrangement did not allow observations of the actual reaction interface, microtomy was used to produce cross-sections.

Increase of desulphurization potential of technological systems of hot metal injection desulphurization by various reagents

2019 ◽  
Vol 75 (11) ◽  
pp. 1237-1243
Author(s):  
A. F. Shevchenko ◽  
I. A. Manachin ◽  
B. V. Dvoskin ◽  
A. S. Vergun ◽  
S. A. Shevchenko ◽  
...  
Keyword(s):  
Technological Systems ◽  
Hot Metal

Review of methods of slag removal from melt surface in hot metal and steel ladles

2020 ◽  
Vol 76 (12) ◽  
pp. 1243-1252
Author(s):  
B. A. Sivak ◽  
A. V. Protasov ◽  
L. A. Smirnov
Keyword(s):  
Settling Tank ◽  
Necessary Condition ◽  
Hot Metal ◽  
Slag Removal ◽  
Production Scale ◽  
Technical Parameters ◽  
Ecological Requirements ◽  
The Usa ◽  
Work Done ◽  
Technological Methods

The removal of slag from melt surface of hot metal and steel ladles is a necessary condition to provide a deep desulphurization and dephosphorization of hot metal and steel in the process of their processing. A review of methods of slag skimming presented, mainly based on slag mechanical shoveling and its removal out of ladles by vacuum sucking. It was shown, that manipulators design for the slag skimming working instrument moving depends on the production scale, mass of the processed heats, amount and properties of the slag to be removed, production process intensity and ecological requirements. Peculiarities of designs and technical parameters of machines for slag skimming presented, designed by Irkutsk plant of heavy machinery, Scientific and Production Enterprise n.a. M.I. Platov, VNIIMETMASH, Kuznetsk and Novolipetsk steel plants. Technological methods of control of slag composition and physical properties considered, first of all of viscosity and fluidity, which have significant effect on selection of a method of slag skimming. Advantages and drawbacks of actions, aimed at more complete slag removal from metal surface by a scraper noted including bath blowing off by an inert gas, liquid slag tapping into am intermediate settling tank following its removal into a slag bowl. In case of satisfactory fluidity it is possible to slag removal by vacuum sucking, which at the same time promoted the melt degassing. Work done in this area abroad noted. Methods of vacuum slag removal developed in the USA and Japan described.

Prediction of Mass Transfer in Hot Metal Reactors

2019 ◽  
Author(s):  
L. Oliveira Campos ◽  
P. Gardin ◽  
S. Vincent
Keyword(s):  
Mass Transfer ◽  
Hot Metal

CYW CHOICE

Alloy Digest ◽  
1956 ◽  
Vol 5 (2) ◽  
Keyword(s):  
Tensile Properties ◽  
Tool Steel ◽  
Heat Treating ◽  
Hot Metal ◽  
Hot Work Steel ◽  
Class Iv

Abstract C. Y. W. CHOICE steel is a chromium hot work steel developed for applications where dies or tools are subjected to heavy pressure or impact while in contact with hot metal. It is an ASM Class IV A-2 tool steel. This datasheet provides information on composition, hardness, elasticity, and tensile properties. It also includes information on forming, heat treating, and machining. Filing Code: TS-43. Producer or source: Firth Sterling Corporation.

scholarly journals Carbothermic Reduction and Nitridation Mechanism of Vanadium-Bearing Titanomagnetite Concentrate

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 730
Author(s):  
Wen Yu ◽  
Xiaojin Wen ◽  
Wei Liu ◽  
Jiangan Chen
Keyword(s):  
Phase Transformation ◽  
Carbothermic Reduction ◽  
Titanium Oxides ◽  
Distribution Characteristic ◽  
Reaction Behavior ◽  
Microstructure Transformation ◽  
Rate Limiting Step ◽  
Limiting Step ◽  
Roasting Process ◽  
Rate Limiting

In this study, the carbothermic reduction and nitridation mechanism of vanadium-bearing titanomagnetite concentrate are investigated in terms of phase transformation, microstructure transformation, and thermodynamic analyses. The differences in the reaction behavior of titanomagnetite and ilmenite in vanadium-bearing titanomagnetite concentrate, as well as the distribution characteristic of V in the roasted products, are emphatically studied. It is observed that the reaction sequences of titanomagnetite and ilmenite transformations into nitride are as follows: Fe3−xTixO4→Fe2TiO4→FeTiO3→M3O5→(Ti, V)(N, C); FeTiO3→M3O5→Ti(N, C). The reduction of M3O5 to TiN is the rate-limiting step of the entire reaction, and metal iron is an important medium for transferring C for the reduction of M3O5. Titanomagnetite is faster to convert into nitride than ilmenite is, and the reasons for this are discussed in detail. During the entire roasting process, V mainly coexists with Ti and seems to facilitate the conversion of titanium oxides into (Ti, V)(N, C).

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