An Ultrathin Ferroelectric Perovskite Oxide Layer for High-Performance Hole Transport Material Free Carbon Based Halide Perovskite Solar Cells

2018 ◽  
Vol 29 (1) ◽  
pp. 1806506 ◽  
Author(s):  
Yinglong Yang ◽  
Zhenghao Liu ◽  
Wai Kit Ng ◽  
Lihua Zhang ◽  
Hua Zhang ◽  
...  
2019 ◽  
Vol 55 (2) ◽  
pp. 218-221 ◽  
Author(s):  
Pei Liu ◽  
Youning Gong ◽  
Yuqing Xiao ◽  
Meng Su ◽  
Sen Kong ◽  
...  

Cs containing triple cation HTM-free carbon based PSCs were fabricated out of a glovebox showing the best performance over 15%.


Molecules ◽  
2022 ◽  
Vol 27 (2) ◽  
pp. 481
Author(s):  
Jinyu Wu ◽  
Lei Zhang ◽  
Qiao Kang ◽  
Hongxi Shi ◽  
Long Li ◽  
...  

Carbon-based hole transport material (HTM)-free perovskite solar cells have exhibited a promising commercialization prospect, attributed to their outstanding stability and low manufacturing cost. However, the serious charge recombination at the interface of the carbon counter electrode and titanium dioxide (TiO2) suppresses the improvement in the carbon-based perovskite solar cells’ performance. Here, we propose a modified sequential deposition process in air, which introduces a mixed solvent to improve the morphology of lead iodide (PbI2) film. Combined with ethanol treatment, the preferred crystallization orientation of the PbI2 film is generated. This new deposition strategy can prepare a thick and compact methylammonium lead halide (MAPbI3) film under high-humidity conditions, which acts as a natural active layer that separates the carbon counter electrode and TiO2. Meanwhile, the modified sequential deposition method provides a simple way to facilitate the conversion of the ultrathick PbI2 capping layer to MAPbI3, as the light absorption layer. By adjusting the thickness of the MAPbI3 capping layer, we achieved a power conversation efficiency (PCE) of 12.5% for the carbon-based perovskite solar cells.


Author(s):  
Jing Ren ◽  
Shurong Wang ◽  
Jianxing Xia ◽  
Chengbo Li ◽  
Lisha Xie ◽  
...  

Defects, inevitably produced in the solution-processed halide perovskite films, can act as charge carrier recombination centers to induce severe energy loss in perovskite solar cells (PSCs). Suppressing these trap states...


Sign in / Sign up

Export Citation Format

Share Document