scholarly journals Spin‐Crossover Molecules on Surfaces: From Isolated Molecules to Ultrathin Films

2021 ◽  
pp. 2008141
Author(s):  
Lalminthang Kipgen ◽  
Matthias Bernien ◽  
Felix Tuczek ◽  
Wolfgang Kuch
Keyword(s):  
Ultrathin Films ◽  
Spin Crossover ◽  
Isolated Molecules

scholarly journals Spin‐Crossover Molecules on Surfaces: From Isolated Molecules to Ultrathin Films

2021 ◽  
Vol 33 (45) ◽  
pp. 2105663
Author(s):  
Lalminthang Kipgen ◽  
Matthias Bernien ◽  
Felix Tuczek ◽  
Wolfgang Kuch
Keyword(s):  
Ultrathin Films ◽  
Spin Crossover ◽  
Isolated Molecules

scholarly journals Correction: Effect of nanostructuration on the spin crossover transition in crystalline ultrathin films

2019 ◽  
Vol 10 (18) ◽  
pp. 4930-4930
Author(s):  
Víctor Rubio-Giménez ◽  
Carlos Bartual-Murgui ◽  
Marta Galbiati ◽  
Alejandro Núñez-López ◽  
Javier Castells-Gil ◽  
...  
Keyword(s):  
Ultrathin Films ◽  
Spin Crossover ◽  
Correction Effect ◽  
Crossover Transition

Correction for ‘Effect of nanostructuration on the spin crossover transition in crystalline ultrathin films’ by Víctor Rubio-Giménez et al., Chem. Sci., 2019, DOI: 10.1039/c8sc04935a.

Modification of Molecular Spin Crossover in Ultrathin Films

Nano Letters ◽  
2013 ◽  
Vol 13 (4) ◽  
pp. 1429-1434 ◽  
Author(s):  
Alex Pronschinske ◽  
Yifeng Chen ◽  
Geoffrey F. Lewis ◽  
David A. Shultz ◽  
Arrigo Calzolari ◽  
...  
Keyword(s):  
Ultrathin Films ◽  
Spin Crossover ◽  
Molecular Spin

Thermal and light-induced spin transition in a nanometric film of a new high-vacuum processable spin crossover complex

2018 ◽  
Vol 6 (33) ◽  
pp. 8885-8889 ◽  
Author(s):  
Matteo Atzori ◽  
Lorenzo Poggini ◽  
Lorenzo Squillantini ◽  
Brunetto Cortigiani ◽  
Mathieu Gonidec ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Ultrathin Films ◽  
Spin Crossover ◽  
Spin Transition ◽  
High Vacuum ◽  
Nanometric Film

Herein, we report the identification of a novel high-vacuum processable spin-crossover complex which can be efficiently used to prepare continuous ultrathin films with retention of switchable magnetic properties.

scholarly journals Effect of nanostructuration on the spin crossover transition in crystalline ultrathin films

2019 ◽  
Vol 10 (14) ◽  
pp. 4038-4047 ◽  
Author(s):  
Víctor Rubio-Giménez ◽  
Carlos Bartual-Murgui ◽  
Marta Galbiati ◽  
Alejandro Núñez-López ◽  
Javier Castells-Gil ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Film Thickness ◽  
Ultrathin Films ◽  
Spin Crossover ◽  
Crossover Transition

Film thickness and microstructure critically affect the spin crossover transition of a 2D coordination polymer.

Spin state of spin-crossover complexes: From single molecules to ultrathin films

2014 ◽  
Vol 89 (19) ◽  
Author(s):  
Manuel Gruber ◽  
Vincent Davesne ◽  
Martin Bowen ◽  
Samy Boukari ◽  
Eric Beaurepaire ◽  
...  
Keyword(s):  
Spin State ◽  
Ultrathin Films ◽  
Spin Crossover ◽  
Single Molecules ◽  
Spin Crossover Complexes

Surface morphology-induced spin-crossover-inactive high-spin state in a coordination framework

2021 ◽  
Author(s):  
Shun Sakaida ◽  
Kazuya Otsubo ◽  
Ken-ichi Otake ◽  
Shogo Kawaguchi ◽  
Mitsuhiko Maesato ◽  
...  
Keyword(s):  
Surface Morphology ◽  
High Spin ◽  
Spin State ◽  
Ultrathin Films ◽  
Spin Crossover ◽  
High Spin State ◽  
Surface Microstructure ◽  
State Control ◽  
Coordination Framework

Here we report a surface morphology-induced spin state control in ultrathin films of a spin-crossover (SCO) material. The surface microstructure of film domains exhibited selectivity, to stabilize the SCO-active high-spin...

Epitaxial growth manner and structure of superconducting oxide films

1990 ◽  
Vol 48 (4) ◽  
pp. 2-3
Author(s):  
Yoshichika Bando ◽  
Takahito Terashima ◽  
Kenji Iijima ◽  
Kazunuki Yamamoto ◽  
Kazuto Hirata ◽  
...  
Keyword(s):  
Ultrathin Films ◽  
Film Surface ◽  
High Energy ◽  
Epitaxial Films ◽  
Layer By Layer ◽  
Initial Growth ◽  
In Situ Growth ◽  
High Quality ◽  
Activated Reactive Evaporation

The high quality thin films of high-Tc superconducting oxide are necessary for elucidating the superconducting mechanism and for device application. The recent trend in the preparation of high-Tc films has been toward “in-situ” growth of the superconducting phase at relatively low temperatures. The purpose of “in-situ” growth is to attain surface smoothness suitable for fabricating film devices but also to obtain high quality film. We present the investigation on the initial growth manner of YBCO by in-situ reflective high energy electron diffraction (RHEED) technique and on the structural and superconducting properties of the resulting ultrathin films below 100Å. The epitaxial films have been grown on (100) plane of MgO and SrTiO, heated below 650°C by activated reactive evaporation. The in-situ RHEED observation and the intensity measurement was carried out during deposition of YBCO on the substrate at 650°C. The deposition rate was 0.8Å/s. Fig. 1 shows the RHEED patterns at every stage of deposition of YBCO on MgO(100). All the patterns exhibit the sharp streaks, indicating that the film surface is atomically smooth and the growth manner is layer-by-layer.

Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis

2021 ◽  
Author(s):  
Cyril Rajnák ◽  
Romana Mičová ◽  
Ján Moncoľ ◽  
Ľubor Dlháň ◽  
Christoph Krüger ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Mononuclear Complex ◽  
Hysteresis Width ◽  
Thermally Induced

A pentadentate Schiff-base ligand 3,5Cl-L2− and NCSe− form a iron(iii) mononuclear complex [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).

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