The Mesomeric Effect of Thiazolium on non-Kekulé Diradicals in Pichia stipitis Transketolase

2018 ◽  
Vol 57 (7) ◽  
pp. 1802-1807 ◽  
Author(s):  
Ning-Shian Hsu ◽  
Yung-Lin Wang ◽  
Kuan-Hung Lin ◽  
Chi-Fon Chang ◽  
Syue-Yi Lyu ◽  
...  
2018 ◽  
Vol 130 (7) ◽  
pp. 1820-1825 ◽  
Author(s):  
Ning-Shian Hsu ◽  
Yung-Lin Wang ◽  
Kuan-Hung Lin ◽  
Chi-Fon Chang ◽  
Syue-Yi Lyu ◽  
...  

2021 ◽  
Author(s):  
Chan Jing Ru ◽  
Fu Qinqin ◽  
Li Jianwei ◽  
Chen Ying ◽  
Satoru Machida ◽  
...  

2010 ◽  
Vol 171-172 ◽  
pp. 261-265
Author(s):  
Zhuang Zuo ◽  
Xiu Shan Yang

Corn stover was pretreated using different soaking conditions at mild temperature. Among the tested conditions, the best was 1% NaOH+8% NH4OH,50°C,48 h, Solid-to-liquid ratio 1:10. The results showed that soaking pretreatment achieved 63.6% delignification, retained the xylan and glucan. After enzymatic hydrolysis, conversion rates of xylan and glucan were 70.9% and 78.5%, respectively. The pretreated filtration re-soaking cause 52.7% xylan and 65.0% glucan conversion. NaOH+NH4OH treatment can be performed under mild conditions, gives a good buffering effect, low carbohydates degradation and extensive removal of lignin. Additionally, simultaneous saccharification and fermentation was conducted with pretreated corn stover to assess the ethanol production. For the whole process, 0.15g ethanol /g corn stover was achieved using Saccharomyces cerevisiae Y5, and 0.19g ethanol /g corn stover when using Pichia stipitis.


1979 ◽  
Vol 57 (22) ◽  
pp. 2967-2970 ◽  
Author(s):  
Gabriel Llabrès ◽  
Marcel Baiwir ◽  
Léon Christiaens ◽  
Jean-Louis Piette

The 1Hmr study of the title compounds has revealed a screw conformation, with defined interconversion processes, in good agreement with crystal structure determinations and theoretical calculations. The mesomeric effect of the heteroatom is smaller than in the anisole series, due to steric inhibitions.The 13Cmr enhances, to some extent, these conclusions. In the case of Te compounds, a heavy atom effect adds to the classical mesomeric and inductive effects to account for the experimental observations.


2011 ◽  
Vol 102 (2) ◽  
pp. 1709-1714 ◽  
Author(s):  
Anuj K. Chandel ◽  
Om V. Singh ◽  
L. Venkateswar Rao ◽  
G. Chandrasekhar ◽  
M. Lakshmi Narasu

1999 ◽  
Vol 77 (1-3) ◽  
pp. 211-222 ◽  
Author(s):  
Hassan K. Sreenath ◽  
Thomas W. Jeffries

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