In this work, meta-material like behavior of natural Mica are studied. This work makes an attempt to analyze the left-handed Maxwellian (LHM) properties of Mica. The investigations carried out on natural Mica specimen are optical reflectance, optical absorbance and DC current–voltage-characteristics (CVC). Optical reflectance of Mica sheet with plane polarized monochromatic light shows distinct difference with conventional theoretical results. The DC CVC also measured with complete electromagnetic shielding. There exists a clear difference in DC characteristic for presence and absence of stray electromagnetic fields. The X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and ultraviolet-visible spectroscopy (UV-VIS) analysis are also carried out for further analysis. The results obtained from the optical reflectance characteristics using polarized light indicate LHM behavior as may be found in a meta-material. Micro-structural and electrical analysis shows that it is a nano-structured layered material.