The interplay between the fragility and mechanical properties of styrene–butadiene rubber composites with unmodified and modified sago seed shell powder

2020 ◽  
Vol 137 (39) ◽  
pp. 49180
Author(s):  
Thulissery Velayudhan Jinitha ◽  
Kodakkat Parambil Safna Hussan ◽  
Thayyil Mohamed Shahin ◽  
Etathil Purushothaman
2020 ◽  
Vol 10 (20) ◽  
pp. 7244
Author(s):  
Sung Ho Song

As eco-friendly “green tires” are being developed in the tire industry, conventionally used carbon black is being replaced with silica in rubber compounds. Generally, as a lubricant and dispersing agent, processing aids containing zinc ions have been employed as additives. However, as zinc is a heavy metal, alternative eco-friendly processing aids are required to satisfy worldwide environmental concerns. Furthermore, non-toxic, degradable, and renewable processing aids are required to improve the mechanical properties of the rubber composites. In this study, we evaluated the effects of diverse silica-based processing aids containing hydrocarbon, benzene, and hydroxyl functional groups on the mechanical properties of rubber composites. Among them, rubber composites that used amphiphilic terpene phenol resin (TPR) with hydrophilic silica showed compatibility with the hydrophobic rubber matrix and were revealed to improve the mechanical and fatigue properties. Furthermore, owing to the enhanced dispersion of silica in the rubber matrix, the TPR/styrene butadiene rubber composites exhibited enhanced wet grip and rolling resistance. These results indicated that TPR had multifunctional effects at low levels and has the potential for use as a processing aid in silica-based rubber composites in tire engineering applications.


2018 ◽  
Vol 5 (8) ◽  
pp. 16543-16551 ◽  
Author(s):  
V. Shaniba ◽  
M.P. Sreejith ◽  
K. Balan Aparna ◽  
T.V. Jinitha ◽  
N. Subair ◽  
...  

2011 ◽  
Vol 284-286 ◽  
pp. 401-410
Author(s):  
Qiong Qiong Liu

Mullite (3A12O3·2SiO2) is an aluminosilicate ceramic of great technological importance. We investigated its potential as fillers in rubber. Mullites untreated or treated with 3% γ-mecapto-propyltrimethoxysilane (A-189) were added into styrene-butadiene rubber (SBR) materials on a laboratory-sized two-roll mill. For comparison, commercial precipitated silica was also used. The effect of these fillers on the cure characteristics, processibility and mechanical properties of SBR at various loadings, ranging from 0 to 50 phr was investigated. The results showed that mullite was a semi-reinforcing filler for SBR materials and exhibits better overall cure properties, lower Mooney viscosity, lower tensile set, better resilience as compared to precipitated silica, while it is inferior to precipitated silica especially with regard to tensile strength, tear strength and abrasion resistance. The presence of the silane coupling agent can enhance mechanical properties of filled SBR vulcanizates to some extent.


2017 ◽  
Vol 74 (10) ◽  
pp. 3977-3994 ◽  
Author(s):  
V. Shaniba ◽  
M. P. Sreejith ◽  
K. B Aparna ◽  
T. V. Jinitha ◽  
E. Purushothaman

2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
DongJu Lee ◽  
Sung Ho Song

Epoxidized palm oil (EPO) is environmentally friendly, biodegradable, and a relatively less costly processing aid. In this study, we investigated the suitability of EPO in place of aromatic processing oils in styrene butadiene rubber. The curing properties, mechanical properties, abrasion resistance, and heat buildup properties of rubber composites with EPO were compared with those of the standard with aromatic oils. The rubber composites with EPO showed enhanced mechanical properties including modulus, tensile strength, and elongation at break. This is ascribed to the improved dispersion of fillers in the rubber matrix and interaction between the filler and the polymer. Furthermore, EPO in the rubber matrix showed remarkable abrasion resistance, rebound resilience, and heat buildup at low loadings. EPO in a rubber composite presents feasibility as a renewable raw material that can serve as an alternative to petrochemical oils in various applications.


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