scholarly journals Integrated process development of a reactive extraction concept for itaconic acid and application to a real fermentation broth

2017 ◽  
Vol 17 (7) ◽  
pp. 809-816 ◽  
Author(s):  
Jannick Gorden ◽  
Elena Geiser ◽  
Nick Wierckx ◽  
Lars M. Blank ◽  
Tim Zeiner ◽  
...  
Keyword(s):  
Itaconic Acid ◽  
Process Development ◽  
Fermentation Broth ◽  
Reactive Extraction ◽  
Integrated Process

Assessment of the Efficiency of Aliquat 336+Rice Bran Oil for Separation of Acrylic Acid from Aqueous Solution Using Reactive Extraction

2018 ◽  
Vol 16 (9) ◽  
Author(s):  
Himangshu Mondal ◽  
Kanti Kumar Athankar ◽  
Kailas L. Wasewar
Keyword(s):  
Acrylic Acid ◽  
Rice Bran ◽  
Renewable Resources ◽  
Extraction Efficiency ◽  
Process Development ◽  
Rice Bran Oil ◽  
Reactive Extraction ◽  
Aliquat 336 ◽  
Proposed Model ◽  
Predicted Values

Abstract Biomass is an attractive target in process development for the emerging renewable resources based bio-refinery industry. Due to the ample range of application of acrylic acid, its production through bio-route received more awareness in scientific fraternity. In this view, an attempted was made to study the reactive extraction of acrylic acid with aliquat 336 in rice bran oil. Moreover, Box-Behnken matrix was employed to corroborate the effects of process variables viz. concentration of acrylic acid [CAA]aq, concentration of aliquat 336 [CR4N+Cl], and temperature on the extraction efficiency (η%). In physical extraction, average extraction efficiency was found in the order as: 43.55 > 35.36 > 29.14 at 303 K, 323 K, and 343 K respectively in rice bran oil. The correlation coefficient, R2 = 0.988 % indicates the appropriateness of proposed model to predict the extraction efficiency in terms of independent variables, and the predicted values were found in close agreement with that of experimental results. Further, R2(Pred) = 0.806 is in reasonable agreement with the R2(Adj) = 0.972. The optimum conditions for extraction of acrylic acid using aliquat 336 as an extractant in rice bran oil are [CAA]aq = 0.0.5 (mol/kg); [CR4N+Cl] = 1.98 (mol/kg); temperature = 323 K and the model predicted extraction efficiency 77.5 % was found to be an excellent fit with the experimental value 75 %. Further, number of theoretical stages was found to be 3 and S/F ratio 0.247.

Study on the Biocompatible Solvent Systems for the Reactive Extraction of Itaconic Acid

2019 ◽  
Vol 64 (10) ◽  
pp. 4280-4285 ◽  
Author(s):  
Dipaloy Datta ◽  
Neha Chomal ◽  
Hasan Uslu ◽  
Sushil Kumar
Keyword(s):  
Itaconic Acid ◽  
Reactive Extraction ◽  
Solvent Systems

scholarly journals Reactive Extraction of Lactic Acid, Formic Acid and Acetic Acid from Aqueous Solutions with Tri-n-octylamine/1-Octanol/n-Undecane

2019 ◽  
Vol 3 (2) ◽  
pp. 43 ◽  
Author(s):  
Nuttakul Mungma ◽  
Marlene Kienberger ◽  
Matthäus Siebenhofer
Keyword(s):  
Mass Transfer ◽  
Acetic Acid ◽  
Lactic Acid ◽  
Formic Acid ◽  
Fermentation Broth ◽  
Lactic Acid Production ◽  
Mass Action ◽  
Reactive Extraction ◽  
Technical Application ◽  
Pka Value

The present work develops the basics for the isolation of lactic acid, acetic acid and formic acid from a single as well as a mixed feed stream, as is present, for example, in fermentation broth for lactic acid production. Modelling of the phase equilibria data is performed using the law of mass action and shows that the acids are extracted according to their pka value, where formic acid is preferably extracted in comparison to lactic and acetic acid. Back-extraction was performed by 1 M NaHCO3 solution and shows the same tendency regarding the pka value. Based on lactic acid, the solvent phase composition, consisting of tri-n-octylamine/1-octanol/n-undecane, was optimized in terms of the distribution coefficient. The data clearly indicate that, compared to physical extraction, mass transfer can be massively enhanced by reactive extraction. With increasing tri-n-octylamine and 1-octanol concentration, the equilibrium constant increases. However, even when mass transfer increases, tri-n-octylamine concentrations above 40 wt%, lead to third phase formation, which needs to be prevented for technical application. The presented data are the basis for the transfer to liquid membrane permeation, which enables the handling of emulsion tending systems.

Development of reactive extraction systems for itaconic acid: a step towards in situ product recovery for itaconic acid fermentation

RSC Advances ◽  
2014 ◽  
Vol 4 (85) ◽  
pp. 45029-45039 ◽  
Author(s):  
Guneet Kaur ◽  
Kathy Elst
Keyword(s):  
Process Optimization ◽  
Itaconic Acid ◽  
Acid Production ◽  
Product Recovery ◽  
Reactive Extraction ◽  
Acid Fermentation ◽  
In Situ Product Recovery ◽  
Product Separation ◽  
Important Means

Process optimization by integration of bioconversion with product separation and recovery i.e. in situ product recovery (ISPR) is an important means to develop a sustainable and petrochemical-competitive biotechnological method for itaconic acid production.

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