Polypyrrole vapor phase polymerization on PVDF membrane surface for conductive membrane preparation and fouling mitigation

2017 ◽  
Vol 93 (3) ◽  
pp. 683-689 ◽  
Author(s):  
Jiadong Liu ◽  
Chang Tian ◽  
Jingxue Xiong ◽  
Bo Gao ◽  
Shaonan Dong ◽  
...  
2021 ◽  
Vol 11 (3) ◽  
Author(s):  
Gongpu Wen ◽  
Kun Chen ◽  
Yanhong Zhang ◽  
Yue Zhou ◽  
Jun Pan ◽  
...  

AbstractA novel strategy was proposed to fabricate alkali-resistant PVDF membrane via sodium lauryl sulfate (SDS) attached to the surface of membrane and immobilized by UV-curable polyester acrylate and tri(propylene glycol) diacrylate (TPGDA). The attached anionic surfactant, SDS, on the membrane surface can resist the alkali corrosion by NaOH, and the curing of the resin can immobilize the SDS on the membrane firmly. Due to the unique alkali resistance of SDS and resin formed, the UV-curable resin-modified PVDF membrane showed greatly enhanced alkali-resistant ability. Characterization of SEM and FTIR showed that polyester acrylate and TPGDA were cured successfully under the action of 1-hydroxycyclohexyl phenyl ketone (184) and ultraviolet light. Whiteness, differential scanning calorimeter and X-ray photoelectron spectrometer characterization showed that the modified PVDF membrane had a lower degree of dehydrofluorination than the pristine PVDF membrane after alkali treatment. Results of the detailed alkali-resistant analysis indicated that the F/C ratio of the UV-curable resin-modified PVDF membrane decreased by 2.6% after alkali treatment compared to pristine PVDF membrane decreased by 19.28%. The alkali-resistant performance was mainly attributed to the immobilized SDS. This study provided a facile and scalable method for designing alkali-resistant PVDF membrane, which shows a promising potential in the treatment of alkaline wastewater and alkaline-cleaning PVDF membrane.


2013 ◽  
Vol 1 (20) ◽  
pp. 3353 ◽  
Author(s):  
Robert Brooke ◽  
Drew Evans ◽  
Maik Dienel ◽  
Pejman Hojati-Talemi ◽  
Peter Murphy ◽  
...  

Author(s):  
Yi He ◽  
Ying Li ◽  
Ying Yuan ◽  
Jun Shu ◽  
Xiaoyan Deng ◽  
...  

2004 ◽  
Vol 37 (16) ◽  
pp. 5930-5935 ◽  
Author(s):  
Bjørn Winther-Jensen ◽  
Jun Chen ◽  
Keld West ◽  
Gordon Wallace

2020 ◽  
Vol 3 ◽  
pp. 862-867
Author(s):  
Ying Guan ◽  
Chuang Wang ◽  
Houyong Yu ◽  
Zhuanyong Zou ◽  
Ying Zhou ◽  
...  

2019 ◽  
Vol 570-571 ◽  
pp. 371-379 ◽  
Author(s):  
Kunpeng Wang ◽  
Lili Xu ◽  
Kuiling Li ◽  
Lie Liu ◽  
Yong Zhang ◽  
...  

2018 ◽  
Vol 18 (1) ◽  
pp. 1
Author(s):  
Romaya Sitha Silitonga ◽  
Nurul Widiastuti ◽  
Juhana Jaafar ◽  
Ahmad Fauzi Ismail ◽  
Muhammad Nidzhom Zainol Abidin ◽  
...  

Poly(vinylidene fluoride) (PVDF) has outstanding properties such as high thermal stability, resistance to acid solvents and good mechanical strength. Due to its properties, PVDF is widely used as a membrane matrix. However, PVDF membrane is hydrophobic properties, so as for specific applications, the surface of membrane needs to be modified to become hydrophilic. This research aims to modify PVDF membrane surface with chitosan and glutaraldehyde as a crosslinker agent. The FTIR spectra showed that the modified membrane has a peak at 1655 cm-1, indicating the imine group (–N=C)- that was formed due to the crosslink between amine group from chitosan and aldehyde group from glutaraldehyde. Results showed that the contact angle of the modified membrane decreases to 77.22° indicated that the membrane hydrophilic properties (< 90°) were enhanced. Prior to the modification, the contact angle of the PVDF membrane was 90.24°, which shows hydrophobic properties (> 90°). The results of porosity, Ɛ (%) for unmodified PVDF membrane was 55.39%, while the modified PVDF membrane has a porosity of 81.99%. Similarly, by modifying the PVDF membrane, pure water flux increased from 0.9867 L/m2h to 1.1253 L/m2h. The enhancement of porosity and pure water flux for the modified PVDF membrane was due to the improved surface hydrophilicity of PVDF membrane.


2017 ◽  
Vol 9 (16) ◽  
pp. 2472-2472 ◽  
Author(s):  
Wenjing Wang ◽  
Chao Wang ◽  
Peng Dou ◽  
Lifang Zhang ◽  
Jiao Zheng ◽  
...  

Correction for ‘Self-supported Co3O4 nanoneedle arrays decorated with PPy via chemical vapor phase polymerization for high-performance detection of trace Pb2+’ by Wenjing Wang et al., Anal. Methods, 2017, 9, 1905–1911.


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