A Triptycene-Based Microporous Organic Polymer Bearing Tridentate Ligands and Its Application in Suzuki-Miyaura Cross-Coupling Reaction

2015 ◽  
Vol 36 (4) ◽  
pp. 413-418 ◽  
Author(s):  
Qiang Wen ◽  
Tian-You Zhou ◽  
Qiao-Ling Zhao ◽  
Jie Fu ◽  
Zhi Ma ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Organic Polymer ◽  
Tridentate Ligands ◽  
Cross Coupling Reaction ◽  
Polymer Bearing

scholarly journals Nickel-metalated porous organic polymer for Suzuki–Miyaura cross-coupling reaction

RSC Advances ◽  
2019 ◽  
Vol 9 (35) ◽  
pp. 20266-20272 ◽  
Author(s):  
Ying Dong ◽  
Jing-Jing Jv ◽  
Yue Li ◽  
Wen-Han Li ◽  
Yun-Qi Chen ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Highly Active ◽  
Cross Coupling Reaction

A porous organic polymer with Ni(ii) α-diimine moiety, which can be a highly active reusable heterogeneous catalyst to promote the Suzuki–Miyaura coupling reaction, was reported.

Thiazole-based non-symmetric NNC–palladium pincer complexes as catalytic precursors for the Suzuki–Miyaura C–C coupling

2019 ◽  
Vol 43 (33) ◽  
pp. 12967-12978
Author(s):  
Martín Camacho-Espinoza ◽  
Alberto Reyes-Deloso ◽  
R. Alfredo Toscano ◽  
J. Guillermo Penieres-Carrillo ◽  
José G. López-Cortés ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Pincer Complexes ◽  
Tridentate Ligands ◽  
Aerobic Conditions ◽  
Catalytic Activities ◽  
Cross Coupling Reaction

New non-symmetric pincer palladacycles, containing [N,N,C] tridentate ligands are synthesized and their catalytic activities in the Suzuki–Miyaura cross coupling reaction are tested using water under aerobic conditions and IR irradiation.

Palladium nanoparticles supported on a carbazole functionalized mesoporous organic polymer: synthesis and their application as efficient catalysts for the Suzuki–Miyaura cross coupling reaction

2017 ◽  
Vol 8 (9) ◽  
pp. 1488-1494 ◽  
Author(s):  
Hui Zhou ◽  
Chuanguang Wu ◽  
Qiaolin Wu ◽  
Bixuan Guo ◽  
Wanting Liu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
High Performance ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Pd Nanoparticles ◽  
Polymer Synthesis ◽  
Organic Polymer ◽  
Cross Coupling Reaction ◽  
Good Catalytic Activity

Pd nanoparticles supported on a carbazole functionalized mesoporous organic polymer exhibit high performance in the Suzuki–Miyaura cross coupling reaction with good catalytic activity, substrate adaptability and recyclability.

Ferromagnetic Chain Based on Verdazyl-Nitroxide Diradical

2020 ◽  
Author(s):  
Evgeny Tretyakov ◽  
Svetlana Zhivetyeva ◽  
Pavel Petunin ◽  
Dmitry Gorbunov ◽  
Nina Gritsan ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Ferromagnetic Coupling ◽  
Nitronyl Nitroxide ◽  
Triplet Ground State ◽  
One Dimensional ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed ◽  
Ferromagnetic Chain ◽  
High Yields

<p>Verdazyl-nitroxide diradicals were synthesized using the palladium-catalyzed cross-coupling reaction of the corresponding iodoverdazyls with a nitronyl nitroxide-2-ide gold(I) complex with high yields (up to 82%). The synthesized diradicals were found to be highly thermally stable and have a singlet (D<i>E</i><sub>ST</sub> » -64 cm<sup>–1</sup>) or triplet ground state (D<i>E</i><sub>ST</sub> ³ 25 and 100 cm<sup>–1</sup>), depending on which canonical hydrocarbon diradical type they belong to. Upon crystallization, triplet diradicals form unique one-dimensional (1D) spin <i>S</i> = 1 chains of organic diradicals with intrachain ferromagnetic coupling of <i>J</i>′/<i>k</i><sub>B</sub> from 3 to 6 K.</p>

An Iron-Based Catalyst Enables The Enantioconvergent Synthesis of Chiral 1,1-Diarylalkanes Through a Suzuki-Miyaura Cross-Coupling Reaction

2020 ◽  
Author(s):  
Chet Tyrol ◽  
Nang Yone ◽  
Connor Gallin ◽  
Jeffery Byers
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Radical Intermediates ◽  
Cross Coupling Reactions ◽  
Cross Coupling Reaction ◽  
Boronic Esters ◽  
Carbon Centered Radical ◽  
Iron Based ◽  
High Yields

By using an iron-based catalyst, access to enantioenriched 1,1-diarylakanes was enabled through an enantioselective Suzuki-Miyaura crosscoupling reaction. The combination of a chiral cyanobis(oxazoline) ligand framework and 1,3,5-trimethoxybenzene additive were essential to afford high yields and enantioselectivities in cross-coupling reactions between unactivated aryl boronic esters and a variety of benzylic chlorides, including challenging ortho-substituted benzylic chloride substrates. Mechanistic investigations implicate a stereoconvergent pathway involving carbon-centered radical intermediates.

Ni(0)-Catalyzed α-Allylic Alkylation of Regular Ketones with 1,3-Dienes under pH and Redox-neutral Conditions

2019 ◽  
Author(s):  
Tiantian Chen ◽  
Yang Yang ◽  
Liyu Xie ◽  
Haijian Yang ◽  
Guangbin Dong ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Dual Role ◽  
Allylic Alkylation ◽  
Cross Coupling Reaction ◽  
Neutral Conditions

<p>We report a Ni(0)-catalyzed cross coupling reaction between simple ketones and 1,3-dienes. A variety of a-allylic alkylation products were formed in an 1,2-addition manner with excellent regioselectivity. Water was found to significantly accelerate this transformation. A HO-Ni-H species generated from oxidative addition of Ni(0) to H<sub>2</sub>O is proposed to play a “dual role” in activating both the ketone and the diene substrate.</p>

Immobilizing biogenically synthesized palladium nanoparticles on cellulose support as a green and sustainable dip catalyst for cross-coupling reaction

Cellulose ◽  
2020 ◽  
Vol 27 (6) ◽  
pp. 3335-3357 ◽  
Author(s):  
Manjunatha Kempasiddaiah ◽  
Vishal Kandathil ◽  
Ramesh B. Dateer ◽  
B. S. Sasidhar ◽  
Shivaputra A. Patil ◽  
...  
Keyword(s):  
Palladium Nanoparticles ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Cross Coupling Reaction
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