Organic compound gas detector based on polylactic acid/poly (styrene‐co‐acrylonitrile)/multi‐walled carbon nanotube blend composite with co‐continuous microstructure

Author(s):  
Payam Molla‐Abbasi
Micromachines ◽  
2020 ◽  
Vol 11 (12) ◽  
pp. 1132
Author(s):  
Xiaoqiang Li ◽  
Guangming Zhang ◽  
Wenhai Li ◽  
Zun Yu ◽  
Kun Yang ◽  
...  

Existing 3D printing techniques are still facing the challenge of low resolution for fabricating polymer matrix composites, inhibiting the wide engineering applications for the biomedical engineering (biomimetic scaffolds), micro fuel cells, and micro-electronics. In order to achieve high resolution fabrication of polylactic acid (PLA)/multi-walled carbon nanotube (MWCNT) composites, this paper presents an electric-field-driven (EFD) fusion jetting 3D printing method by combining the mixing effect and material feeding of the micro-screw and the necking effect of Taylor cone by the EFD. The effects of main process parameters (the carbon loading, the voltage, the screw speed, and the printing speed) on the line width and the printing quality were studied and optimized. To demonstrate the printing capability of this proposed method, meshes with line width of 30 µm to 100 μm and 1 wt.% to 5 wt.% MWCNT for the application of conductive biomimetic scaffold and the anisotropic flexible meshes were prepared. The electrical properties were investigated to present the frequency dependence of the alternating current conductivity and the dielectric loss (tanδ), and the microstructures of printed structures demonstrated the uniformly dispersed MWCNT in PLA matrix. Therefore, it provides a new solution to fabricate micro-scale structures of composite materials, especially the 3D conductive biomimetic scaffolds.


2020 ◽  
Vol 15 ◽  
pp. 155892502096881
Author(s):  
Lisha Pan ◽  
Qiaoqiang Lv ◽  
Nai Xu

In this study, antistatic biodegradable polylactic acid (PLA)/multi-walled carbon nanotube (PLA/MWCNT) composites were prepared by the melt-blending of MWCNT with PLA. The conductive, mechanical, thermal properties and microstructure of the PLA/MWCNT composites were investigated. Results revealed that with the loading of 1.0 to 1.5 wt% of MWCNT, the tensile strength, elongation at break, and crystallinity of the composites slightly increase, followed by a downward trend with the further increase in the loading amount of MWCNT. With the increase in the MWCNT loading amount to 3.0%, the volume resistivity and surface resistivity of the composites were reduced by nine orders of magnitude. According to the internal microstructure of PLA/MWCNT, by the loading of 1.5 wt% of MWCNT, the MWCNT formed a conductive network in the composite matrix, reaching the percolation threshold. The new composties can be applicated in medical protective clothing for protecting the electronic instrument.


Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 832
Author(s):  
Edna X. Figueroa-Rosales ◽  
Javier Martínez-Juárez ◽  
Esmeralda García-Díaz ◽  
Daniel Hernández-Cruz ◽  
Sergio A. Sabinas-Hernández ◽  
...  

Hydroxyapatite (HAp) and hydroxyapatite/multi-walled carbon nanotube (MWCNT) composites were obtained by the co-precipitation method, followed by ultrasound-assisted and microwave radiation and thermal treatment at 250 °C. X-ray diffraction (XRD) confirmed the presence of a hexagonal phase in all the samples, while Fourier-transform infrared (FTIR) spectroscopy elucidated the interaction between HAp and MWCNTs. The photoluminescent technique revealed that HAp and the composite with non-functionalized MWCNTs present a blue luminescence, while the composite with functionalized MWCNTs, under UV-vis radiation shows an intense white emission. These findings allowed presentation of a proposal for the use of HAp and HAp with functionalized MWCNTs as potential materials for optoelectronic and medical applications.


2021 ◽  
Vol 49 (6) ◽  
pp. 861-872
Author(s):  
Wei LIU ◽  
Zhuang LI ◽  
Shao-peng ZHANG ◽  
Wei-wei JIAN ◽  
Dan-zhu MA

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