Polyethylene/Ethylene Vinyl Acetate and Ethylene Octene Copolymer/Clay Nanocomposite Films: Different Processing Conditions and Their Effect on Properties

2019 ◽  
Vol 59 (12) ◽  
pp. 2514-2521
Author(s):  
Merinska Dagmar ◽  
Tesarikova Alice ◽  
Kalendova Alena
2020 ◽  
Vol 40 (9) ◽  
pp. 763-770 ◽  
Author(s):  
Molin Guo ◽  
Hao Chen ◽  
João M. Maia

AbstractSurface roughness and sharkskin of extruded polymers, including blends are affected by the morphology and processing conditions. In this study, different effects on the roughness of the polymer blend extrudates were investigated. Co-continuous poly(ethylene) oxide/ethylene-vinyl acetate (PEO/EVA) blends with three different molecular weight (Mw) PEOs were compounded successfully. It was found that the better co-continuity of the structure and smoother surface were achieved for lower Mw PEO/EVA blend because of more effective stress transfer in the PEO phase. The effect of processing temperature was also studied with decreasing processing temperature reducing the surface roughness of the high Mw PEO/EVA blend, which was also achieved as a result of improved co-continuous morphology by adjusting the viscosity and elasticity ratio with shifting temperatures.


2020 ◽  
Vol 29 (8) ◽  
pp. 723-733
Author(s):  
Miguel A. García-Muñoz ◽  
Mario Valera-Zaragoza ◽  
Alejandro Aparicio-Saguilán ◽  
Miguel A. Peña-Rico ◽  
Erick A. Juarez-Arellano ◽  
...  

2021 ◽  
Vol 33 (7) ◽  
pp. 1656-1662
Author(s):  
N. Gopal ◽  
A. Saxena ◽  
B. Kumar ◽  
R. Sahney

Soft and conductive interfaces are valuable in wearable electronics as they are capable for integration of diverse classes of electronic and sensor technologies directly with living body which can be used as health monitoring systems. In present work, we explore the development of multi-walled carbon nanotube-ethylene vinyl acetate nanocomposite (MWCNT-EVA) film and their properties. Oxidation of MWCNT is known to improve their dispersion properties and increase the electrical conductivity of MWCNT-polymer nanocomposites. Thus, pristine MWCNTs (p-MWCNTs) and functionalized MWCNTs (f-MWCNTs) were further used as conductive filler to construct p-MWCNT-EVA and f-MWCNT-EVA nanocomposite films. The films were characterized by Fourier-transform infrared spectroscopy, scanning electron microscopy, energy dispersive X-ray analysis and electrochemical technique. The results indicated that the chemical oxidation of p-MWCNT generates carboxylic function at the p-MWCNT surface important for sensor fabrication. The concentration of carboxylic functional group in f-MWCNT higher than in nanocomposites. The f-MWCNT-EVA nanocomposite film electrode surface show much higher conductivitythan p-MWCNT-EVAnanocomposite film. Thus, the soft and flexible f-MWCNT-EVA nanocomposite films are effective for the development of electrochemical platform for biosensor fabrication in wearable applications.


2016 ◽  
Vol 30 (1) ◽  
pp. 121-140 ◽  
Author(s):  
Gibin George ◽  
M Selvakumar ◽  
Arunjunairaj Mahendran ◽  
S Anandhan

Poly(ethylene- co-vinyl acetate- co-carbon monoxide) (EVACO)/halloysite nanotube (HNT) nanocomposite films were solution cast. Dispersion of HNTs in the matrix was analyzed by elemental mapping and the role of HNTs on crystallizability, flammability and thermal, mechanical, and electrical properties of the polymer was evaluated. The nature of interaction between the EVACO matrix and HNTs was studied using Fourier transform infrared spectroscopy. The highest tensile strength was observed for the composite with 1% filler loading, whereas the highest crystallinity was observed for that with 3% filler loading. The decay in the tensile properties at higher filler loading was due to agglomeration of HNTs and debonding of polymer–filler interface. The electrical volume resistivity of the composites decreased with HNT loading because of the ionic charge transfer. The direct current electrical resistivity study of the composites proves that the addition of HNT can improve the antistatic properties of the polymer.


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