In this article, low-density polyethylene (LDPE) was used as a matrix polymer, the Micro-ZnO and Nano-ZnO particles were used as the inorganic filler. With the melt blending method, the Nano-ZnO/LDPE(Nano-ZnO particles doping into LDPE), Micro-ZnO/LDPE(Micro-ZnO particles doping into LDPE) and Micro-Nano-ZnO/LDPE (Nano-ZnO and Micro-ZnO particles doping into LDPE in the same time) composites were prepared. Then, the inorganic filler and the composites were dealt with structural characterizations and analysis by Fourier transform infrared (FTIR), Polarization microscope (PLM), and Differential scanning calorimeter (DSC). Besides, these samples were dealt with (alternating current) AC breakdown performance test. The micro-experimental results showed that the Micro-ZnO and Nano-ZnO particles doping reduced the crystal size and increased the crystallization rate. With the change of cell structure, the crystallinity of composites increased. The crystallinity order of different samples was as follows: LDPE < Micro-ZnO/LDPE < Nano-ZnO/LDPE < Micro-Nano-ZnO/LDPE. From the breakdown of the experimental result, with the same mass fraction of the different inorganic doping of particles, the breakdown strength of these composites was different. The Nano-ZnO particle doping could improve the breakdown strength of composites effectively. Among them, the breakdown strength of Nano-ZnO/LDPE and Micro-Nano-ZnO/LDPE were 11% higher and 1.3% lower than that of pure LDPE, respectively. Meanwhile, the breakdown strength of Micro-composite was the lowest but its Weibull shape coefficient was the highest. Therefore, the Micro-ZnO doping was helpful for the Nano-ZnO dispersing in the matrix, which produced the Micro-Nano-synergy effects better.
The Research of Crystalline Morphology and Breakdown Characteristics of Polymer/Micro-Nano-Composites