Thermal oxidative stability and effect of water on gas transport and mechanical properties in PA6-EVOH films

Underwater wet welding (UWW) combined with the shielded metal arc welding (SMAW) method has proven to be an effective way of permanently joining metals that can be performed in water. This research was conducted to determine the effect of water flow rate on the physical and mechanical properties (tensile, hardness, toughness, and bending effect) of underwater welded bead on A36 steel plate. The control variables used were a welding speed of 4 mm/s, a current of 120 A, electrode E7018 with a diameter of 4 mm, and freshwater. The results show that variations in water flow affected defects, microstructure, and mechanical properties of underwater welds. These defects include spatter, porosity, and undercut, which occur in all underwater welding results. The presence of flow and an increased flow rate causes differences in the microstructure, increased porosity on the weld metal, and undercut on the UWW specimen. An increase in water flow rate causes the acicular ferrite microstructure to appear greater, and the heat-affected zone (HAZ) will form finer grains. The best mechanical properties are achieved by welding with the highest flow rate, with a tensile strength of 534.1 MPa, 3.6% elongation, a Vickers microhardness in the HAZ area of 424 HV, and an impact strength of 1.47 J/mm2.

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Effect of Water Ingress on the Mechanical and Chemical Properties of Polybutylene Terephthalate Reinforced with Glass Fibers

Materials ◽

10.3390/ma14051261 ◽

2021 ◽

Vol 14 (5) ◽

pp. 1261

Author(s):

Catarina S. P. Borges ◽

Alireza Akhavan-Safar ◽

Eduardo A. S. Marques ◽

Ricardo J. C. Carbas ◽

Christoph Ueffing ◽

...

Keyword(s):

Mechanical Properties ◽

Water Absorption ◽

Water Uptake ◽

Significant Influence ◽

Water Immersion ◽

Water Diffusion ◽

Polybutylene Terephthalate ◽

Chemical Changes ◽

Water Ingress ◽

Effect Of Water

Short fiber reinforced polymers are widely used in the construction of electronic housings, where they are often exposed to harsh environmental conditions. The main purpose of this work is the in-depth study and characterization of the water uptake behavior of PBT-GF30 (polybutylene terephthalate with 30% of short glass fiber)as well as its consequent effect on the mechanical properties of the material. Further analysis was conducted to determine at which temperature range PBT-GF30 starts experiencing chemical changes. The influence of testing procedures and conditions on the evaluation of these effects was analyzed, also drawing comparisons with previous studies. The water absorption behavior was studied through gravimetric tests at 35, 70, and 130 °C. Fiber-free PBT was also studied at 35 °C for comparison purposes. The effect of water and temperature on the mechanical properties was analyzed through bulk tensile tests. The material was tested for the three temperatures in the as-supplied state (without drying or aging). Afterwards, PBT-GF30 was tested at room temperature following water immersion at the three temperatures. Chemical changes in the material were also analyzed through Fourier-transform infrared spectroscopy (FTIR). It was concluded that the water diffusion behavior is Fickian and that PBT absorbs more water than PBT-GF30 but at a slightly higher rate. However, temperature was found to have a more significant influence on the rate of water diffusion of PBT-GF30 than fiber content did. Temperature has a significant influence on the mechanical properties of the material. Humidity contributes to a slight drop in stiffness and strength, not showing a clear dependence on water uptake. This decrease in mechanical properties occurs due to the relaxation of the polymeric chain promoted by water ingress. Between 80 and 85 °C, after water immersion, the FTIR profile of the material changes, which suggests chemical changes in the PBT. The water absorption was simulated through heat transfer analogy with good results. From the developed numerical simulation, the minimum plate size to maintain the water ingress unidirectional was 30 mm, which was validated experimentally.

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Evaluation of the thermal oxidative stability of polyimides via TGA techniques

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/(sici)1099-0518(19991101)37:21<3943::aid-pola10>3.0.co;2-5 ◽

1999 ◽

Vol 37 (21) ◽

pp. 3943-3956 ◽

Cited By ~ 42

Author(s):

Mary Jo Turk ◽

Asif S. Ansari ◽

William B. Alston ◽

Gloria S. Gahn ◽

Aryeh A. Frimer ◽

...

Keyword(s):

Oxidative Stability ◽

Thermal Oxidative Stability

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Polyimide Copolymers Containing Various Levels Of The 6F Moiety For High Temperature And Microelectronic Applications

MRS Proceedings ◽

10.1557/proc-227-35 ◽

1991 ◽

Vol 227 ◽

Cited By ~ 9

Author(s):

M. Haider ◽

E. Chenevey ◽

R. H. Vora ◽

W. Cooper ◽

M. Glick ◽

...

Keyword(s):

Mechanical Properties ◽

High Temperature ◽

Electrical Properties ◽

Oxidative Stability ◽

Trifluoromethyl Group ◽

Thermal And Mechanical Properties

ABSTRACTTrifluoromethyl group-containing polyimides not only show extraordinary electrical properties, but they also exhibit excellent long-term thermo-oxidative stability. Among the most thermomechanically stable structural polyimides are those from 6F dianhydride (6FDA) and 6F diamines. The effects of substituting non-fluorine containing monomers such as BTDA, mPDA and 4,4′-DADPS for the hexafluoroisopropylidene monomers on the dielectric, thermo-oxidative, thermal and mechanical properties of the copolymers were studied.

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