Atmospheric observations of line intensity and half-width in the rotation and ν2 vibration-rotation bands of water vapour

1961 ◽  
Vol 87 (374) ◽  
pp. 578-587 ◽  
Author(s):  
F. Saiedy
1956 ◽  
Vol 34 (11) ◽  
pp. 1119-1125 ◽  
Author(s):  
Robert Herman ◽  
Robert J. Rubin

The magnitude of the effect of the vibration–rotation interaction on the intensities of pure rotation lines of diatomic molecules has been calculated for two different molecular models, the anharmonic oscillator and the rotating Morse or Pekeris oscillator. The intensity correction for the anharmonic oscillator has been obtained by adapting the contact transformation formalism for calculating second-order corrections to the energy to the calculation of first-order corrections to the matrix elements of the electric moment as suggested by H. H. Nielsen. The correction to the line intensity for vibrationless transitions of the anharmonic oscillator is found to be[Formula: see text]The results obtained here are also in complete agreement, to first order, with the results obtained earlier by Herman and Wallis for the 1–0 and 2–0 vibration–rotation line intensities. In the case of the Pekeris or rotating Morse oscillator the correction to the pure rotation line intensity is of the same form as above, namely,[Formula: see text]but exhibits minor differences which can be explained in terms of the difference in the vibrational potential energy function in the two cases.


1968 ◽  
Vol 46 (15) ◽  
pp. 1697-1703 ◽  
Author(s):  
Philippe Arcas ◽  
Lucette Hochard-Demolliere

The intensity and half-width of the 12CO2 3ν3 band lines are determined, the instrumental effects being corrected by numerical calculations. The square of the vibrational moment (R03)2 is found to be equal to 0.233 × 10−42 e.s.u. With a quadrupolar momentum Q = 5.2 × 10−26 e.s.u., the line-width variation curve versus J can be approximately interpreted by Anderson's theory.


1999 ◽  
Vol 96 (6) ◽  
pp. 941-954 ◽  
Author(s):  
LAURENT H. COUDERT

2019 ◽  
Author(s):  
Jonathan Elsey ◽  
Marc D. Coleman ◽  
Tom D. Gardiner ◽  
Kaah P. Menang ◽  
Keith P. Shine

Abstract. Water vapour continuum absorption is potentially important for both closure of the Earth’s energy budget and remote sensing applications. Currently, there are significant uncertainties in its characteristics in the near-infrared atmospheric windows at 2.1 and 1.6 μm. There have been several attempts to measure the continuum in the laboratory; not only are there significant differences amongst these measurements but there are also difficulties in extrapolating the laboratory data taken at room temperature or higher to atmospheric temperatures. Validation is therefore required using field observations of the real atmosphere. There are currently few published observations in atmospheric conditions with enough water vapour to detect a continuum signal within these windows, or where the self-continuum component is significant. We present observations of the near-infrared water vapour continuum from Camborne, UK at sea level using a sun-pointing, radiometrically-calibrated Fourier transform spectrometer in the window regions between 2000–10000 cm−1. Analysis of this data is challenging, particularly because of the need to remove aerosol extinction, and the large uncertainties associated with such field measurements. Nevertheless, we present data that is consistent with recent laboratory datasets in the 4 and 2.1 μm windows (when extrapolated to atmospheric temperatures). These results indicate that the most recent revision (3.2) of the MT_CKD foreign continuum, versions of which are widely used in atmospheric radiation models, requires strengthening by a factor of ~ 5 in the centre of the 2.1 µm window. In the higher-wavenumber window at 1.6 µm, our estimated self and foreign continua are significantly stronger than MT_CKD. The possible contribution of the self and foreign continua to our derived total continuum optical depth is estimated by using laboratory or MT_CKD values of one, to estimate the other. The obtained self-continuum shows some consistency with temperature-extrapolated laboratory data in the centres of the 4 and 2.1 µm windows. The 1.6 μm region is more sensitive to atmospheric aerosol and continuum retrievals and therefore more uncertain than the more robust results at 2.1 and 4 μm. We highlight the difficulties in observing the atmospheric continuum and make the case for additional measurements from both the laboratory and field, with discussion of the requirements for any new field campaign.


2020 ◽  
Vol 13 (5) ◽  
pp. 2335-2361
Author(s):  
Jonathan Elsey ◽  
Marc D. Coleman ◽  
Tom D. Gardiner ◽  
Kaah P. Menang ◽  
Keith P. Shine

Abstract. Water vapour continuum absorption is potentially important for both closure of the Earth's energy budget and remote sensing applications. Currently, there are significant uncertainties in its characteristics in the near-infrared atmospheric windows at 2.1 and 1.6 µm. There have been several attempts to measure the continuum in the laboratory; not only are there significant differences amongst these measurements, but there are also difficulties in extrapolating the laboratory data taken at room temperature and above to temperatures more widely relevant to the atmosphere. Validation is therefore required using field observations of the real atmosphere. There are currently no published observations in atmospheric conditions with enough water vapour to detect a continuum signal within these windows or where the self-continuum component is significant. We present observations of the near-infrared water vapour continuum from Camborne, UK, at sea level using a Sun-pointing, radiometrically calibrated Fourier transform spectrometer in the window regions between 2000 and 10 000 cm−1. Analysis of these data is challenging, particularly because of the need to remove aerosol extinction and the large uncertainties associated with such field measurements. Nevertheless, we present data that are consistent with recent laboratory datasets in the 4 and 2.1 µm windows (when extrapolated to atmospheric temperatures). These results indicate that the most recent revision (3.2) of the MT_CKD foreign continuum, versions of which are widely used in atmospheric radiation models, requires strengthening by a factor of ∼5 in the centre of the 2.1 µm window. In the higher-wavenumber window at 1.6 µm, our estimated self- and foreign-continua are significantly stronger than MT_CKD. The possible contribution of the self- and foreign-continua to our derived total continuum optical depth is estimated by using laboratory or MT_CKD values of one, to estimate the other. The obtained self-continuum shows some consistency with temperature-extrapolated laboratory data in the centres of the 4 and 2.1 µm windows. The 1.6 µm region is more sensitive to atmospheric aerosol and continuum retrievals and therefore more uncertain than the more robust results at 2.1 and 4 µm. We highlight the difficulties in observing the atmospheric continuum and make the case for additional measurements in both the laboratory and field and discuss the requirements for any future field campaign.


2013 ◽  
Vol 8 (S300) ◽  
pp. 52-55
Author(s):  
M. Zapiór ◽  
P. Heinzel ◽  
R. Oliver ◽  
J. L. Ballester ◽  
P. Kotrč

AbstractProminence oscillations have been mostly detected using Doppler velocity, although there are also claimed detections by means of the periodic variations of half-width or line intensity. Our main aim here is to explore the relationship between spectral indicators such as Doppler shift, line intensity and line half-width and the linear perturbations excited in a simple prominence model.


2004 ◽  
Vol 22 (5) ◽  
pp. 1549-1561 ◽  
Author(s):  
F. Phillips ◽  
G. B. Burns ◽  
W. J. R. French ◽  
P. F. B. Williams ◽  
A. R. Klekociuk ◽  
...  

Abstract. Rotational temperatures derived from the OH(8–3) band may vary by ~18K depending on the choice of transition probabilities. This is of concern when absolute temperatures or trends determined in combination with measurements of other hydroxyl bands are important. In this paper, measurements of the OH(8–3) temperature-insensitive Q/P and R/P line intensity ratios are used to select the most appropriate transition probabilities for use with this band. Aurora, airglow and solar and telluric absorption in the OH(8–3) band are also investigated. Water vapour absorption of P1(4), airglow or auroral contamination of P1(2) and solar absorption in the vicinity of P1(5) are concerns to be considered when deriving rotational temperatures from this band. A comparison is made of temperatures derived from OH(6–2) and OH(8–3) spectra collected alternately at Davis (69° S, 78° E) in 1990. An average difference of ~4K is found, with OH(8–3) temperatures being warmer, but a difference of this magnitude is within the two sigma uncertainty limit of the measurements. Key words. Atmospheric composition and structure airglow and aurora; pressure, density, and temperature)


1996 ◽  
Vol 51 (1-2) ◽  
pp. 36-40
Author(s):  
K.M.T. Yamada ◽  
A. Moravec ◽  
M. Niedenhoff ◽  
G. Winnewisser

Abstract The relative intensities and Lorentz half-widths of rovibrational transitions observed for the 2ν5 overtone band of cyanoacetylene, HCCCN, have been determined. The line widths and the intensities were obtained by fitting the observed line profiles with Voigt functions. The Lorentz half-width shows a clear J dependence and vanishes at J ~ 100. In the intensity calculation, we took into account the effects of the accidental resonances between the ν5 = 2 state and the (ν4 = 1, ν7 = 2) state as well as those of the generic l-type resonance. Peak intensities have been found not to be the appropriate presentation of the line intensity because of the strong J dependence of the half-width.


2020 ◽  
Author(s):  
Jon Elsey ◽  
Marc Coleman ◽  
Tom Gardiner ◽  
Kaah Menang ◽  
Keith Shine

<div> <div> </div> </div><div> <div>The water vapour continuum is an important additional component to the total absorption of atmospheric radiation by water vapour. However, while it has been studied extensively in the far and mid-infrared, there are significant uncertainties in its absorption strength in the near-infrared, since the relatively few laboratory measurements in this region disagree by a factor of ~50. Compounding this uncertainty is the lack of observations in atmospheric conditions; measurements are typically made at room-temperature or above, but the continuum has significant (and uncertain) temperature dependence. We aim to reduce this uncertainty by presenting observations of the near-infrared water vapour continuum from Camborne, UK at sea level using a sun-pointing, radiometrically-calibrated Fourier transform spectrometer in the window regions between 2000–10000 cm<sup>−1</sup>. When extrapolated to atmospheric temperatures, we show good agreement with various laboratory studies in the 4 µm window.  Our results show that the widely-used MT_CKD continuum is too weak by a factor of ~5 in the in the centre of the 2.1 µm window in line with laboratory analyses, with implications for energy balance studies and remote sensing. Our results at 1.6 µm show significantly stronger absorption than MT_CKD. This may be in part due to the influence of atmospheric aerosol, which forms a rather significant part of the uncertainty in our measurements at higher wavenumbers. We demonstrate the difficulties in making such field observations, and highlight the need for future observations both from the laboratory and the field, with the aim of including the water vapour continuum in the HITRAN spectroscopic database.</div> </div>


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