Nano-sized Metal Fluorides: A New Synthetic Approach towards High Surface Area Materials

2004 ◽  
Vol 630 (11) ◽  
pp. 1696-1696 ◽  
Author(s):  
Erhard Kemnitz ◽  
Stephan Ruediger ◽  
Udo Gross
ChemTexts ◽  
2020 ◽  
Vol 6 (3) ◽  
Author(s):  
Erhard Kemnitz ◽  
Stefan Mahn ◽  
Thoralf Krahl

Abstract The recently developed fluorolytic sol–gel route to metal fluorides opens a very broad range of both scientific and technical applications of the accessible high surface area metal fluorides, many of which have already been applied or tested. Specific chemical properties such as high Lewis acidity and physical properties such as high surface area, mesoporosity and nanosize as well as the possibility to apply metal fluorides on surfaces via a non-aqueous sol make the fluorolytic synthesis route a very versatile one. The scope of its scientific and technical use and the state of the art are presented.


2008 ◽  
Vol 8 (11) ◽  
pp. 5733-5738 ◽  
Author(s):  
Xicoténcatl López ◽  
Victor M. Castaño

Cr ion-polluted industrial water was treated with commercial activated carbon and with either mercaptane- and amine-functionallized silica nanoparticles, revealing that the use of relatively low surface area materials can advantageously compete with high surface area materials, traditionally utilized for removing hazardous metal ions, provided a proper surface functionalization of the nanoparticles is in place. FTIR and SEM characterization of the different materials and stages of the experiments are provided, as well.


Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4226
Author(s):  
Ghedini ◽  
Menegazzo ◽  
Manzoli ◽  
Di Michele ◽  
Puglia ◽  
...  

This work deals with the formulation of environmentally friendly, cheap, and readily-available materials for green building applications, providing the function of air purificator by improving the safety and the comfort of an indoor environment. High surface area TiO2–SiO2 samples, prepared by a simple, cost effective, and scalable synthetic approach, proved to be effective in maximizing the properties of each component, i.e., the photocatalytic properties of titania and the high surface area of silica. TiO2 was introduced onto an ordered mesoporous silica Santa Barbara Amorphous-15 (SBA-15), that is featured by interesting insulating features, by using an incipient wetness impregnation method. The photocatalytic activity was evaluated in gas phase oxidation of ethylbenzene, which was selected as model volatile organic compound (VOC) molecule. The morphological, textural and structural features along with the electronic properties, the hydrophilicity and heat capacity of the materials were investigated in depth by scanning electron microscopy, powder X-ray diffraction, N2 physisorption, diffuse reflectance UV-Vis, FT-IR spectroscopies, and modulated DSC (MDSC) dynamic scan. Outstanding performances in the ethylbenzene abatement results are promising for further application in the green building sector.


2014 ◽  
Vol 353 ◽  
pp. 244-247
Author(s):  
Eun Jin Jung ◽  
Yoon Joo Lee ◽  
Woo Teck Kwon ◽  
Y. Kim ◽  
Dong Geun Shin ◽  
...  

Since mesoporous silica such as MCM-41 and SBA-15 was developed, the study of the properties of high-surface area materials was accelerated. Moreover, the mesoporous silica is used as a template to produce high-surface materials by nanocasting technology. The purpose of this paper is the synthesis of a high surface silicon carbide sphere by the nanocasting technology. In this study, KCC-1 silica sphere was used as a template, and polycarbosilane and poly (phenyl carbosilane) were selected for precursor of silicon carbide. Carbosilane polymer gives advantage of synthesis silicon carbide under low temperature, and hollow spheres were produced. In this study, the polycarbosilane was more effective for the synthesis of SiC hollow spheres by inversion of template structure showing a fibrous morphology on the sphere wall. And it was confirmed that the sphere was composed of nanosized SiC crystals, and has high surface area using TEM, XRD and BET analysis.


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