Volumetric Mass Transfer Coefficient Measurement in a Stirred Tank Reactor

2021 ◽  
Author(s):  
Aysegul Inam ◽  
Ezgi Rojda Taymaz ◽  
Mehmet Emin Uslu ◽  
Baris Binay ◽  
Irem Deniz
Keyword(s):  
Mass Transfer ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Stirred Tank ◽  
Volumetric Mass Transfer Coefficient ◽  
Stirred Tank Reactor ◽  
Tank Reactor ◽  
Coefficient Measurement

scholarly journals In Situ Bio-Methanation Modelling of a Randomly Packed Gas Stirred Tank Reactor (GSTR)

Processes ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 846
Author(s):  
Leone Mazzeo ◽  
Antonella Signorini ◽  
Giuseppe Lembo ◽  
Irene Bavasso ◽  
Luca Di Palma ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Liquid Waste ◽  
Stirred Tank ◽  
Model Parameters ◽  
Stirred Tank Reactor ◽  
Tank Reactor ◽  
Dimensionless Analysis

In situ Bio-Methanation (BM) is a recently developed biogas upgrading technique which finds application also in the Power to Gas (P2G) field. In this study a novel configuration of BM digester, the randomly packed Gas Stirred Tank Reactor (GSTR), was modelled. A 49 L reactor, in thermophilic conditions (55 °C) and at atmospheric pressure, was filled up with random packing on which the microbial populations could adhere. The feedstock used was Second Cheese Whey (SCW), liquid waste of cheese factories, rich in lactose (38 g/L), and its flowrate was chosen to obtain a Hydraulic Retention Time (HRT) of 30 days. The process was analyzed for different hydrogen inlet flowrates of 10 mL/min and 50 mL/min. The produced biogas was also recirculated in the reactor in order to transfer, into the liquid phase, as much hydrogen as possible. The model parameters were estimated by means of stationary state information of the reactor working without hydrogen injection, while a dynamical fitting was necessary to evaluate the value of the hydrogen mass transfer coefficient during BM. The model well described the reactor behavior and, by means of a dimensionless analysis in which the numbers of Stanton (St) and β were defined, it was found out that the mass transfer coefficient is the limiting step of the process.

Research on Mass Transfer Coefficient Measurement Model of External-Loop Airlift Reactor

2012 ◽  
Vol 512-515 ◽  
pp. 2405-2411
Author(s):  
Qian Wu ◽  
Ma Lin Liu ◽  
Tong Wang Zhang
Keyword(s):  
Mathematical Model ◽  
Mass Transfer ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Measurement Model ◽  
Airlift Reactor ◽  
Continuous Stirred Tank Reactor ◽  
Volumetric Mass Transfer Coefficient ◽  
External Loop ◽  
Coefficient Measurement

A mathematical model considering the inter-phase mass transfer both in the down-comer and the riser of an external-loop airlift reactor was established in this paper. The calculated global volumetric mass transfer coefficient based on the assumption of continuous stirred tank reactor (CSTR) was different from the local volumetric mass transfer coefficients by the newly proposed mathematical model and the difference was discussed. The effects of mass transfer in the down-comer, the hydrodynamic pressure and the experimental time on the mass transfer coefficient measurement model have been studied in detail. And it was also proved that only the global volumetric mass transfer coefficient, but not the local volumetric mass coefficient, can be obtained from a time-concentration curve in the external-loop airlift reactor.

scholarly journals Gas–liquid mass transfer characteristics of aviation fuel scrubbing in an aircraft fuel tank

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Li Chaoyue ◽  
Feng Shiyu ◽  
Xu Lei ◽  
Peng Xiaotian ◽  
Yan Yan
Keyword(s):  
Mass Transfer ◽  
Dissolved Oxygen ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Oxygen Concentration ◽  
Gas Holdup ◽  
Aviation Fuel ◽  
Volumetric Mass Transfer Coefficient ◽  
Dissolved Oxygen Concentration ◽  
Liquid Mass Transfer

AbstractDissolved oxygen evolving from aviation fuel leads to an increase in the oxygen concentration in an inert aircraft fuel tank ullage that may increase the flammability of the tank. Aviation fuel scrubbing with nitrogen-enriched air (NEA) can largely reduce the amount of dissolved oxygen and counteract the adverse effect of oxygen evolution. The gas–liquid mass transfer characteristics of aviation fuel scrubbing are investigated using the computational fluid dynamics method, which is verified experimentally. The effects of the NEA bubble diameter, NEA superficial velocity and fuel load on oxygen transfer between NEA and aviation fuel are discussed. Findings from this work indicate that the descent rate of the average dissolved oxygen concentration, gas holdup distribution and volumetric mass transfer coefficient increase with increasing NEA superficial velocity but decrease with increasing bubble diameter and fuel load. When the bubble diameter varies from 1 to 4 mm, the maximum change of descent rate of dissolved oxygen concentration is 18.46%, the gas holdup is 8.73%, the oxygen volumetric mass transfer coefficient is 81.45%. When the NEA superficial velocities varies from 0.04 to 0.10 m/s, the maximum change of descent rate of dissolved oxygen concentration is 146.77%, the gas holdup is 77.14%, the oxygen volumetric mass transfer coefficient is 175.38%. When the fuel load varies from 35 to 80%, the maximum change of descent rate of dissolved oxygen concentration is 21.15%, the gas holdup is 49.54%, the oxygen volumetric mass transfer coefficient is 44.57%. These results provide a better understanding of the gas and liquid mass transfer characteristics of aviation fuel scrubbing in aircraft fuel tanks and can promote the optimal design of fuel scrubbing inerting systems.

Mass Transfer Coefficients during Steel Decarburization in a RH Degasser

2008 ◽  
Vol 273-276 ◽  
pp. 679-684
Author(s):  
Roberto Parreiras Tavares ◽  
André Afonso Nascimento ◽  
Henrique Loures Vale Pujatti
Keyword(s):  
Mass Transfer ◽  
Reynolds Number ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Gas Flow ◽  
Vacuum Chamber ◽  
Volumetric Mass Transfer Coefficient ◽  
Gas Flow Rate ◽  
Rh Process ◽  
Kinetics Of

The RH process is a secondary refining process that can simultaneously attain significant levels of removal of interstitial elements, such as carbon, nitrogen and hydrogen, from liquid steel. In the RH process, the decarburization rate plays a very important role in determining the productivity of the equipment. The kinetics of this reaction is controlled by mass transfer in the liquid phase. In the present work, a physical model of a RH degasser has been built and used in the study of the kinetics of decarburization. The effects of the gas flow rate and of the configurations of the nozzles used in the injection of the gas have been analyzed. The decarburization reaction of liquid steel was simulated using a reaction involving CO2 and caustic solutions. The concentration of CO2 in the solution was evaluated using pH measurements. Based on the experimental results, it was possible to estimate the reaction rate constant. A volumetric mass transfer coefficient was then calculated based on these rate constants and on the circulation rate of the liquid. The logarithm of the mass transfer coefficient showed a linear relationship with the logarithm of the gas flow rate. The slope of the line was found to vary according to the relevance of the reaction at the free surface in the vacuum chamber. A linear relationship between the volumetric mass transfer coefficient and the nozzle Reynolds number was also observed. The slopes of the lines changed according to the relative importance of the two reaction sites, gas-liquid interface in the upleg snorkel and in the vacuum. At higher Reynolds number, the reaction in the vacuum chamber tends to be more significant.

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