Coulomb Coupling and Virtual Phonon Exchange in Spatially Separated 2D Electron Systems

1993 ◽  
pp. 81-95
Author(s):  
P. Vasilopoulos ◽  
H. C. Tso
Keyword(s):  
Electron Systems ◽  
Coulomb Coupling

Pathway Complexity in the Stacking of Imine-linked Macrocycles Related to Two-Dimensional Covalent Organic Frameworks

2019 ◽  
Author(s):  
Shiwei Wang ◽  
Anton Chavez ◽  
Simil Thomas ◽  
Hong Li ◽  
Nathan C. Flanders ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Structural Similarity ◽  
Discrete Models ◽  
Side Chains ◽  
Two Dimensional ◽  
Assembly Process ◽  
Covalent Organic Frameworks ◽  
Electron Systems ◽  
Monomer Structure ◽  
Kinetic Traps

This work reports on the assembly of imine-linked macrocycles that serve as models of two-dimensional covalent organic frameworks (2D COFs). Interlayer interactions play an important role in the formation of 2D COFs, yet the effect of monomer structure on COF formation, crystallinity, and susceptibility to exfoliation are not well understood. For example, monomers with both electron-rich and electron-poor π-electron systems have been proposed to strengthen interlayer inter-actions and improve crystallinity. Here we probe these effects by studying the stacking behavior of imine-linked macrocycles that represent discrete models of 2D COFs. <div><br></div><div>Specifically, macrocycles based on terephthaldehyde (PDA) or 2,5-dimethoxyterephthaldehyde (DMPDA) stack upon cooling molecularly dissolved solutions. Both macrocycles assemble cooperatively with similar ΔHe values of -97 kJ/mol and -101 kJ/mol, respectively, although the DMPDA macrocycle assembly process showed a more straightforward temperature dependence. Circular dichroism spectroscopy performed on macrocycles bearing chiral side chains revealed a helix reversion process for the PDA macrocycles that was not observed for the DMPDA macrocycles. <br></div><div><br></div><div>Given the structural similarity of these monomers, these findings demonstrate that the stacking processes associated with nanotubes derived from these macrocycles, as well as for the corresponding COFs, are complex and susceptible to kinetic traps, casting doubt on the relevance of thermodynamic arguments for improving materials quality. <br></div>

A Theoretical Study of Influence of Lattice Structure on Multi Pole of f-electron Systems

2018 ◽  
Vol 8 (10) ◽  
pp. 181-186
Author(s):  
Ravi Kumar ◽  
Uday Narain Singh ◽  
L. K. Mishra
Keyword(s):  
Theoretical Study ◽  
Lattice Structure ◽  
Electron Systems

Effect of external magnetic field on lane formation in driven pair-ion plasmas

2021 ◽  
Vol 87 (2) ◽  
Author(s):  
Swati Baruah ◽  
U. Sarma ◽  
R. Ganesh
Keyword(s):  
Magnetic Field ◽  
External Magnetic Field ◽  
Field Strength ◽  
Electric Field ◽  
Electric Field Strength ◽  
Coupling Parameter ◽  
Critical Parameters ◽  
Coulomb Coupling ◽  
Lane Formation ◽  
Parameter Values

Lane formation dynamics in externally driven pair-ion plasma (PIP) particles is studied in the presence of external magnetic field using Langevin dynamics (LD) simulation. The phase diagram obtained distinguishing the no-lane and lane states is systematically determined from a study of various Coulomb coupling parameter values. A peculiar lane formation-disintegration parameter space is identified; lane formation area extended to a wide range of Coulomb coupling parameter values is observed before disappearing to a mixed phase. The different phases are identified by calculating the order parameter. This and the critical parameters are calculated directly from LD simulation. The critical electric field strength value above which the lanes are formed distinctly is obtained, and it is observed that in the presence of the external magnetic field, the PIP system requires a higher value of the electric field strength to enter into the lane formation state than that in the absence of the magnetic field. We further find out the critical value of electric field frequency beyond which the system exhibits a transition back to the disordered state and this critical frequency is found as an increasing function of the electric field strength in the presence of an external magnetic field. The movement of the lanes is also observed in a direction perpendicular to that of the applied electric and magnetic field directions, which reveals the existence of the electric field drift in the system under study. We also use an oblique force field as the external driving force, both in the presence and absence of the external magnetic field. The application of this oblique force changes the orientation of the lane structures for different applied oblique angle values.

Systematic calculations of energy levels and transitions rates in Mo XXVIII

2020 ◽  
Vol 75 (8) ◽  
pp. 739-747
Author(s):  
Feng Hu ◽  
Yan Sun ◽  
Maofei Mei
Keyword(s):  
Energy Levels ◽  
Oscillator Strengths ◽  
Atomic Data ◽  
Data Sets ◽  
Electron Systems ◽  
Excitation Energies ◽  
Experimental Values ◽  
Qed Effects ◽  
Hyperfine Structures ◽  
Good Agreement

AbstractComplete and consistent atomic data, including excitation energies, lifetimes, wavelengths, hyperfine structures, Landé gJ-factors and E1, E2, M1, and M2 line strengths, oscillator strengths, transitions rates are reported for the low-lying 41 levels of Mo XXVIII, belonging to the n = 3 states (1s22s22p6)3s23p3, 3s3p4, and 3s23p23d. High-accuracy calculations have been performed as benchmarks in the request for accurate treatments of relativity, electron correlation, and quantum electrodynamic (QED) effects in multi-valence-electron systems. Comparisons are made between the present two data sets, as well as with the experimental results and the experimentally compiled energy values of the National Institute for Standards and Technology wherever available. The calculated values including core-valence correction are found to be in a good agreement with other theoretical and experimental values. The present results are accurate enough for identification and deblending of emission lines involving the n = 3 levels, and are also useful for modeling and diagnosing plasmas.

Two-dimensional electron systems and interfacial coupling in LaCrO3/KTaO3 heterostructures

2021 ◽  
Vol 118 (19) ◽  
pp. 192905
Author(s):  
Athby H. Al-Tawhid ◽  
Divine P. Kumah ◽  
Kaveh Ahadi
Keyword(s):  
Two Dimensional ◽  
Electron Systems ◽  
Dimensional Electron ◽  
Interfacial Coupling ◽  
Two Dimensional Electron Systems

Boron-Doped Polycyclic π-Electron Systems with an Antiaromatic Borole Substructure That Forms Photoresponsive B–P Lewis Adducts

2021 ◽  
Author(s):  
Naoki Ando ◽  
Takuya Yamada ◽  
Hiroki Narita ◽  
Niels N. Oehlmann ◽  
Matthias Wagner ◽  
...  
Keyword(s):  
Electron Systems ◽  
Boron Doped
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