scholarly journals Electroweak Baryogenesis with Topological Defects

1994 ◽  
pp. 161-170
Author(s):  
A. C. Davis ◽  
R. H. Brandenberger ◽  
M. Trodden
Keyword(s):  
Topological Defects

A Pseudo Five-Fold Symmetrical Ligand Drives Geometric Frustration in Porous Metal-Organic and Hydrogen Bonded Frameworks

2020 ◽  
Author(s):  
Frederik Haase ◽  
Gavin Craig ◽  
Mickaele Bonneau ◽  
kunihisa sugimoto ◽  
Shuhei Furukawa
Keyword(s):  
Topological Defects ◽  
Porous Metal ◽  
Building Blocks ◽  
Structural Features ◽  
Equilibrium Structure ◽  
Sorption Behavior ◽  
Building Unit ◽  
Geometric Frustration ◽  
Secondary Building Units ◽  
Hydrogen Bonded

Reticular framework materials thrive on designability, but unexpected reaction outcomes are crucial in exploring new structures and functionalities. By combining “incompatible” building blocks, we employed geometric frustration in reticular materials leading to emergent structural features. The combination of a pseudo C<sub>5</sub> symmetrical organic building unit based on a pyrrole core, with a C<sub>4</sub> symmetrical copper paddlewheel synthon led to three distinct frameworks by tuning the synthetic conditions. The frameworks show structural features typical for geometric frustration: self-limiting assembly, internally stressed equilibrium structures and topological defects in the equilibrium structure, which manifested in the formation of a hydrogen bonded framework, distorted and broken secondary building units and dangling functional groups, respectively. The influence of geometric frustration on the CO<sub>2</sub> sorption behavior and the discovery of a new secondary building unit shows geometric frustration can serve as a strategy to obtain highly complex porous frameworks.

A Pseudo Five-Fold Symmetrical Ligand Drives Geometric Frustration in Porous Metal-Organic and Hydrogen Bonded Frameworks

2020 ◽  
Author(s):  
Frederik Haase ◽  
Gavin Craig ◽  
Mickaele Bonneau ◽  
kunihisa sugimoto ◽  
Shuhei Furukawa
Keyword(s):  
Topological Defects ◽  
Porous Metal ◽  
Building Blocks ◽  
Structural Features ◽  
Equilibrium Structure ◽  
Sorption Behavior ◽  
Building Unit ◽  
Geometric Frustration ◽  
Secondary Building Units ◽  
Hydrogen Bonded

Reticular framework materials thrive on designability, but unexpected reaction outcomes are crucial in exploring new structures and functionalities. By combining “incompatible” building blocks, we employed geometric frustration in reticular materials leading to emergent structural features. The combination of a pseudo C<sub>5</sub> symmetrical organic building unit based on a pyrrole core, with a C<sub>4</sub> symmetrical copper paddlewheel synthon led to three distinct frameworks by tuning the synthetic conditions. The frameworks show structural features typical for geometric frustration: self-limiting assembly, internally stressed equilibrium structures and topological defects in the equilibrium structure, which manifested in the formation of a hydrogen bonded framework, distorted and broken secondary building units and dangling functional groups, respectively. The influence of geometric frustration on the CO<sub>2</sub> sorption behavior and the discovery of a new secondary building unit shows geometric frustration can serve as a strategy to obtain highly complex porous frameworks.

scholarly journals Defects and perturbation

2021 ◽  
Vol 2021 (4) ◽  
Author(s):  
Enrico M. Brehm
Keyword(s):  
Entanglement Entropy ◽  
Topological Defects ◽  
Field Theories ◽  
Two Dimensional ◽  
Conformal Field Theories ◽  
Minimal Models ◽  
Conformal Field

Abstract We investigate perturbatively tractable deformations of topological defects in two-dimensional conformal field theories. We perturbatively compute the change in the g-factor, the reflectivity, and the entanglement entropy of the conformal defect at the end of these short RG flows. We also give instances of such flows in the diagonal Virasoro and Super-Virasoro Minimal Models.

scholarly journals Properties of twisted topological defects in 2D nematic liquid crystals

Soft Matter ◽  
2021 ◽  
Author(s):  
Daniel Pearce ◽  
Karsten Kruse
Keyword(s):  
Liquid Crystals ◽  
Nematic Liquid Crystals ◽  
Topological Defects ◽  
Two Dimensional

Topological defects are one of the most conspicuous features of liquid crystals. In two dimensional nematics, they have been shown to behave effectively as particles with both, charge and orientation,...

Topological defects involving Fe/N co-doped mesoporous carbon nanosheets as novel electrocatalysts for the oxygen reduction reaction and Zn–air batteries

Nanoscale ◽  
2021 ◽  
Author(s):  
Junjie Ding ◽  
Dongchuang Wu ◽  
Senhe Huang ◽  
Chenbao Lu ◽  
Yu Chen ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Topological Defects ◽  
Reduction Reaction ◽  
Defect Engineering ◽  
Carbon Nanosheets ◽  
Renewable Energy Technologies ◽  
Central Focus ◽  
Energy Technologies ◽  
Co Doped

Developing effective electrocatalysts for oxygen reduction reaction is of great significance for clean and renewable energy technologies, such as metal–air batteries and fuel cells. Defect engineering is the central focus...

scholarly journals Wavefront dislocations reveal the topology of quasi-1D photonic insulators

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Clément Dutreix ◽  
Matthieu Bellec ◽  
Pierre Delplace ◽  
Fabrice Mortessagne
Keyword(s):  
Local Density ◽  
Topological Defects ◽  
Wave Functions ◽  
Topological Classification ◽  
Local Density Of States ◽  
Topological Phase Transition ◽  
Interference Fringes ◽  
Classical Wave ◽  
Phase Singularities

AbstractPhase singularities appear ubiquitously in wavefields, regardless of the wave equation. Such topological defects can lead to wavefront dislocations, as observed in a humongous number of classical wave experiments. Phase singularities of wave functions are also at the heart of the topological classification of the gapped phases of matter. Despite identical singular features, topological insulators and topological defects in waves remain two distinct fields. Realising 1D microwave insulators, we experimentally observe a wavefront dislocation – a 2D phase singularity – in the local density of states when the systems undergo a topological phase transition. We show theoretically that the change in the number of interference fringes at the transition reveals the topological index that characterises the band topology in the insulator.

scholarly journals Ionically Charged Topological Defects in Nematic Fluids

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jeffrey C. Everts ◽  
Miha Ravnik
Keyword(s):  
Topological Defects

scholarly journals A Thermal Transport Study of Branched Carbon Nanotubes with Cross and T-Junctions

2021 ◽  
Vol 11 (13) ◽  
pp. 5933
Author(s):  
Wei-Jen Chen ◽  
I-Ling Chang
Keyword(s):  
Heat Transfer ◽  
Carbon Nanotubes ◽  
Thermal Management ◽  
Thermal Transport ◽  
Topological Defects ◽  
Branch Length ◽  
Phonon Transport ◽  
Heat Current ◽  
Transport Mechanisms ◽  
Non Equilibrium Molecular Dynamics

This study investigated the thermal transport behaviors of branched carbon nanotubes (CNTs) with cross and T-junctions through non-equilibrium molecular dynamics (NEMD) simulations. A hot region was created at the end of one branch, whereas cold regions were created at the ends of all other branches. The effects on thermal flow due to branch length, topological defects at junctions, and temperature were studied. The NEMD simulations at room temperature indicated that heat transfer tended to move sideways rather than straight in branched CNTs with cross-junctions, despite all branches being identical in chirality and length. However, straight heat transfer was preferred in branched CNTs with T-junctions, irrespective of the atomic configuration of the junction. As branches became longer, the heat current inside approached the values obtained through conventional prediction based on diffusive thermal transport. Moreover, directional thermal transport behaviors became prominent at a low temperature (50 K), which implied that ballistic phonon transport contributed greatly to directional thermal transport. Finally, the collective atomic velocity cross-correlation spectra between branches were used to analyze phonon transport mechanisms for different junctions. Our findings deeply elucidate the thermal transport mechanisms of branched CNTs, which aid in thermal management applications.

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